Aqueous plastic-plastic compounding glue water for soft packaging and preparation method thereof

A water-based, flexible packaging technology, applied in the direction of adhesive types, ester copolymer adhesives, etc., can solve the problems of limited adaptability of the substrate, inability to meet the comprehensive requirements of the composite process, and high equipment procurement costs, so as to reduce costs. Effect

Inactive Publication Date: 2016-12-14
广东佰合新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the difficulties of soft packaging companies are that the lamination industry currently lacks water-based lamination adhesives with reliable performance to replace traditional solvent-based lamination adhesives. Solvent-free lamination is also in the exploratory stage. The economic loss caused by the production made many packaging companies stop; the original water-based composite glue (including various domestic manufacturers and international famous brands) has very limited adaptability to the substrate and cannot meet the overall requirements of the composite process. , it is easy to draw a conclusion from the current actual market share of water-based glue;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A water-based plastic-plastic composite glue for flexible packaging. The components of the composite glue and the weight of each component are: 188g butyl acrylate, 20g ethyl acrylate, 17g lauryl acrylate, 15g methyl methacrylate, hydroxymethacrylate Propyl ester 15g, styrene 95g, acrylonitrile 35g, acrylic acid 12g, N-hydroxyacrylamide 12g, itaconic acid 6g, OP-10 3g, DNS-86 1g, COPS-1 0.8g, sodium persulfate 3.2g, carbonic acid Sodium hydrogen 1g, ammonia water 4g, wetting agent DC01 4g, dispersant 8g, defoamer 1g, deionized water 600g.

[0023] The method includes the following steps:

[0024] Step 1: monomer pre-emulsification: put 380g deionized water, emulsifier OP-10 3g and DNS-86 1g into the emulsification tank, start the mixer to stir, adjust the speed of the mixer to 80 rpm, and then gradually add : N-hydroxyacrylamide 12g, butyl acrylate 188g, ethyl acrylate 20g, lauryl acrylate 17g, methyl methacrylate 15g, hydroxypropyl methacrylate 15g, styrene 95g, acryl...

Embodiment 2

[0029] A water-based plastic-plastic composite glue for flexible packaging. The components of the composite glue and the weight of each component are: 170g of butyl acrylate, 40g of ethyl acrylate, 15g of lauryl acrylate, 20g of butyl methacrylate, hydroxymethacrylate 10g of ethyl ester, 105g of styrene, 25g of acrylonitrile, 13g of methacrylic acid, 10g of N-hydroxyacrylamide, 6g of ethylene glycol dimethacrylate, 3g of NP-10, 1g of CO-436, 1g of COPS-1, Sodium sulfate 3.2g, sodium bicarbonate 1g, ammonia water 4.5g, wetting agent OT-75 4g, dispersant 8g, defoamer 1g, deionized water 600g.

[0030] The method includes the following steps:

[0031]Step 1: Monomer pre-emulsification: put 380g of deionized water, 3g of emulsifier NP-10 and 1g of CO-436 into the emulsification tank, start stirring, the speed is 80 rpm, and then gradually add: 10g of N-hydroxyacrylamide , 170 g of butyl acrylate, 40 g of isooctyl acrylate, 15 g of lauryl acrylate, 20 g of butyl methacrylate, 10 g...

Embodiment 3

[0036] A water-based plastic-plastic composite glue for flexible packaging, the components of the composite glue and the weight of each component are: 190 g of butyl acrylate, 30 g of isooctyl acrylate, 20 g of lauryl acrylate, 20 g of butyl methacrylate, methacrylic acid 15 g of hydroxyethyl ester, 125 g of styrene, 10 g of acrylonitrile, 12 g of methacrylic acid, 8 g of diacetone acrylamide, 4 g of adipate diacyl base, 6 g of diallyl maleate, 3 g of NP-10, 1 g of ES-50 , COPS-1 1g, sodium persulfate 3.2g, sodium bicarbonate 1g, ammonia 4.5g, wetting agent 440 4g, dispersant 8g, defoamer 1g, deionized water 600g.

[0037] The method includes the following steps:

[0038] Step 1: Monomer pre-emulsification: Put 380g of deionized water, 3g of emulsifier NP-10 and 1g of ES-50 into the emulsification tank, start stirring, and rotate at 80 rpm, and then gradually add: 8g of diacetone acrylamide, 190 g of butyl acrylate, 30 g of isooctyl acrylate, 20 g of lauryl acrylate, 20 g of ...

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PUM

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Abstract

The invention provides aqueous plastic-plastic compounding glue water for soft packaging, and relates to compounding glue water. The compounding glue water is prepared from the following ingredients in parts by weight: 20 to 30 parts of acrylic ester monomers, 1 to 5 parts of acrylic acid or methacrylic acid, 2 to 4 parts of alkyl methacrylate esters, 10 to 20 parts of styrene or acrylonitrile, 1 to 2 parts of acrylic acid hydroxyl esters, 0.2 to 1 part of N-Methylol acrylamide or diacetone-acryloamide, 1 to 5 parts of adipic dihydrazide, 0.4 to 0.8 part of itaconic acid, ethylene dimethacrylate or diallyl maleate, 0.3 to 1 part of emulsifying agents, 0.2 to 0.8 part of initiating agents, 0.1 to 0.3 part of buffering agents and 0.3 to 1 part of wetting agents. According to the material structure matching, the dry glue coating quantity per square meter can be controlled to be 0.5 to 2g, and the requirements can be met, for example, thin BOPP / CPP only needs 0.5 kg of dry glue, and the transparency and the firmness degree can reach the requirements; the cost of glue water used in per square meter is as low as 0.02 Yuan RMB; the product can be used on an original dry type compounding machine; the addition of equipment investment is not needed.

Description

Technical field: [0001] The invention relates to composite glue, in particular to a water-based plastic-plastic composite glue for flexible packaging and a preparation method thereof. Background technique: [0002] At present, about 90% of the adhesives used in the composite process of flexible packaging are solvent-based two-component polyurethane adhesives, 7-8% are solvent-free two-component polyurethane adhesives, and 2-3% are water-based adhesives. The composite process of the soft packaging industry consumes and directly discharges about 2 million tons of unburned solvents (ethyl acetate, toluene, industrial alcohols) into the atmosphere every year. The energy loss is quite serious, and at the same time it causes huge pollution hazards to the environment. In October 2015, the country formally passed the VOC Treatment Act, which fully collects pollution treatment fees for industrial solvent emissions. [0003] However, the difficulties of soft packaging companies are t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C08F220/18C08F220/14C08F220/28C08F212/10C08F220/46C08F220/06C08F220/58C08F222/02C08F222/14
CPCC09J133/08C08F220/18C08F220/1804C08F222/02C08F212/10C08F220/1812C08F220/14C08F220/281C08F220/46C08F220/06C08F220/58C08F222/14C08F220/1802C08F220/1808
Inventor 李星明袭登凰
Owner 广东佰合新材料科技股份有限公司
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