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A kind of mesoporous cobalt oxide/manganese oxide/carbon composite nanomaterial, preparation method and application thereof

A nanomaterial and composite material technology, which is applied in the field of mesoporous cobalt oxide/manganese oxide/carbon composite nanomaterials and preparation, can solve the problem that few people have made mesoporous bimetallic cobalt and manganese, and the specific surface area of ​​the material is not very high. It is too easy to control and other problems to achieve the effect of being suitable for large-scale production, significant technological progress, and low production cost

Inactive Publication Date: 2018-03-20
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] At present, cobalt oxide, or a composite of cobalt oxide and other materials has been prepared by various methods, but few people have made a composite material of mesoporous bimetallic cobalt and manganese, and then applied it in electrochemical examples
At the same time, the process of preparing cobalt oxide is relatively cumbersome. For example, the requirements for equipment through mechanical grinding are relatively high. The preparation process through hydrolysis is not easy to control, and the specific surface area of ​​the synthesized materials is relatively not very high.

Method used

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  • A kind of mesoporous cobalt oxide/manganese oxide/carbon composite nanomaterial, preparation method and application thereof
  • A kind of mesoporous cobalt oxide/manganese oxide/carbon composite nanomaterial, preparation method and application thereof
  • A kind of mesoporous cobalt oxide/manganese oxide/carbon composite nanomaterial, preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0039] A preparation method of mesoporous cobalt oxide / manganese oxide / carbon composite nanomaterial, specifically comprising the following steps:

[0040] (1) At 40°C, dissolve 0.6g of nonionic surfactant in 12.0g of organic solvent, then add 0.9g of inorganic cobalt source, 0.9g of inorganic manganese source and 0.6g of organic silicon source in sequence, and dissolve completely for 10 minutes Finally, add 2.4g of organic high molecular polymer, fully stir in a water bath at 40°C to form a homogeneous solution, then pour it into a watch glass, place it in a 40°C oven for 24 hours, and then place it in a 100°C oven for 24 hours for cross-linking, thereby Obtain a transparent film;

[0041] The amount of the nonionic surfactant, solvent, inorganic cobalt source, inorganic manganese source, organic silicon source, and organic polymer used above is calculated by mass ratio. Nonionic surfactant: solvent: inorganic cobalt source: inorganic manganese Source: organosilicon source: ...

Embodiment 2

[0057] A preparation method of mesoporous cobalt oxide / manganese oxide / carbon composite nanomaterial, specifically comprising the following steps:

[0058] (1) At 40°C, dissolve 0.6g of nonionic surfactant in 6.0g of solvent, then add 0.6g of inorganic cobalt source, 0.3g of inorganic manganese source and 0.12g of organic silicon source in sequence, and dissolve completely after 10 minutes Add 1.2g of organic high molecular polymer, fully stir in a 40°C water bath to form a homogeneous solution, then pour it into a watch glass, place it in a 40°C oven for 24h, and then place it in a 100°C oven for 24h for crosslinking, thus obtaining transparent film;

[0059] The amount of the nonionic surfactant, solvent, inorganic cobalt source, inorganic manganese source, organic silicon source, and organic polymer used above is calculated by mass ratio. Nonionic surfactant: solvent: inorganic cobalt source: inorganic manganese Source: Silicone source: 20% ethanol solution of phenolic res...

Embodiment 3

[0074] A preparation method of mesoporous cobalt oxide / manganese oxide / carbon composite nanomaterial, specifically comprising the following steps:

[0075] (1) Dissolve 0.6g of nonionic surfactant in 24.0g of solvent at 40°C, then add 3g of inorganic cobalt source, 9g of inorganic manganese source and 1.2g of organic silicon source in sequence, and add 3.6 g organic high molecular polymer, fully stirred in a water bath at 40°C to form a homogeneous solution, then poured into a watch glass, placed in an oven at 40°C for 24 hours, and then placed in an oven at 100°C for 24 hours for cross-linking to obtain a transparent membranous matter;

[0076]The amount of the nonionic surfactant, solvent, inorganic cobalt source, inorganic manganese source, organic silicon source, and organic polymer used above is calculated by mass ratio. Nonionic surfactant: solvent: inorganic cobalt source: inorganic manganese Source: Silicone source: phenolic resin ethanol solution with a concentration...

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Abstract

The invention discloses a mesoporous cobalt oxide / manganese oxide / carbon composite nanometer material, a preparation method and an application thereof. The preparation method comprises the steps of firstly mixing a surface active agent, a cobalt source, a manganese source, a silicon source, an organic macromolecule polymer and a solvent to form a homogeneous solution, then pouring the homogeneous solution into a reaction vessel, and performing cross-linking in a drying oven; then roasting an acquired transparent membranous substance to acquire a compound of cobalt oxide, manganese oxide, silicon oxide and carbon; and finally removing the silicon oxide through alkali washing, and acquiring a mesoporous cobalt oxide / manganese oxide / carbon composite nanometer material after filtering, washing and drying. The preparation method is simple and suitable for large-scale production. The specific surface area of the acquired composite material is 105-298m<2> / g, the pore volume is 0.2-0.65cm<3> / g, and the pore diameter is 2.2-4.6nm. The composite nanometer material can act as an electrode material used for manufacturing a supercapacitor.

Description

technical field [0001] The invention belongs to the technical field of inorganic nanomaterials, and specifically relates to a mesoporous cobalt oxide / manganese oxide / carbon composite nanomaterial, a preparation method and an application thereof. Background technique [0002] In the 21st century, human beings are facing two important problems of energy crisis and environmental pollution, so the development and research of clean energy has far-reaching significance. Among them, all kinds of vehicles account for about 40% of oil consumption, and 42% of global air pollution comes from the emissions of traffic vehicles. The country has issued many policies to encourage everyone to buy new energy vehicles. Countries around the world attach great importance to the development of electric vehicles. my country's 863 plan also lists the development of electric vehicles as an important development direction. The research on the power battery as vehicle power has become the main bottle...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G11/26H01G11/36H01G11/46H01G11/38H01G11/86
CPCY02E60/13
Inventor 马立梦沈绍典王根礼毛东森卢冠忠
Owner SHANGHAI INST OF TECH
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