Bismaleimide resin/silicone rubber ablation-resistant thermal insulation composite material and preparation method thereof

A technology of Shuangma resin and composite materials, which is applied in the field of thermal protection of the afterburner chamber of the integral solid-impact engine, can solve the problems of poor oxidation resistance, easy cracks, poor elasticity, etc., and achieve high temperature resistance and flame retardancy. Improved ablation resistance and ease of handling

Inactive Publication Date: 2017-04-26
湖北三江航天江北机械工程有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented new type of thermally insulated materials have several technical benefits compared to previous designs such as those made from silicon carbide or graphite. These improvements include improved durability against damage caused by burning fuels at higher temperatures without losing their ability to maintain its properties over time (hot protection), better fireproofness for longer periods while still being effective even when exposed to harsh environments like these conditions). Additionally, they are easier to manufacture due to having fewer steps involved than traditional methods making them more efficient.

Problems solved by technology

This patented technology describes two different ways how integrated solid-pulsive (IS) internal combustions can perform better than traditional gasoline engines when flying over altitude quickly without losing power because they lack certain features like fuel injection systems that require frequent maintenance. However, current methods involve adding ceramics layers on top of the rear igniter before burning out during flight. These techniques may cause cracks if exposed to air containing sulfur dioxide which could damage them more easily. Additionally, existing solutions such as epoxy resin coatings cannot protect against erosion caused by sand grains hitting these surfaces.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Use silane coupling agent to carry out surface treatment to fumed white carbon black, zirconium boride and chopped carbon fiber, stand-by; Add 35 parts of methyl vinyl silicone rubber and 65 parts of methyl vinyl phenyl silicone rubber to the mixer Mixing at 80°C to a transparent state; add 2 parts of hydroxyl silicone oil, 25 parts of surface-treated fumed silica, 10 parts of surface-treated micron zirconium boride powder, and 15 parts of surface-treated average length of 9mm chopped carbon fiber continue to mix until evenly mixed; add 20 parts of double horse resin and 2 parts of dicumyl peroxide, continue to mix until evenly mixed; after mixing, take it out and let it stand for 25 hours; then according to the required thickness And size, sheet; two-stage vulcanization: one-stage vulcanization, pressure vulcanization, pressure is 12MPa, vulcanization temperature is 160°C, vulcanization time is 15min; two-stage vulcanization: normal pressure vulcanization, temperature i...

Embodiment 2

[0030] Use silane coupling agent to carry out surface treatment to fumed silica, zirconium boride and chopped carbon fiber, stand-by; add 30 parts of methyl vinyl silicone rubber and 70 parts of methyl vinyl phenyl silicone rubber to the mixer Mixing at 90°C to a transparent state; add 3 parts of hydroxyl silicone oil, 20 parts of surface-treated fumed silica, 15 parts of pretreated micron zirconium boride powder, and 10 parts of surface-treated average length of 10mm chopped carbon fiber continue to mix until evenly mixed; add 25 parts of Shuangma resin and 3 parts of dicumyl peroxide, continue to mix until evenly mixed; after mixing, take it out and let it stand for 28 hours; then according to the required thickness and size, sheet output; two-stage vulcanization: one-stage vulcanization, pressure vulcanization, pressure 15MPa, vulcanization temperature 180°C, vulcanization time 20min; two-stage vulcanization: normal pressure vulcanization, temperature 220°C, time 4h.

[003...

Embodiment 3

[0033] Use silane coupling agent to carry out surface treatment to fumed silica, zirconium boride and chopped carbon fiber, stand-by; add 20 parts of methyl vinyl silicone rubber and 80 parts of methyl vinyl phenyl silicone rubber to the mixer Mixing at 70°C to a transparent state; add 1 part of hydroxyl silicone oil, 15 parts of surface-treated fumed silica, 20 parts of pretreated micron zirconium boride powder, and 6 parts of surface-treated average length of 8mm chopped carbon fiber continue to mix until evenly mixed; add 5 parts of Shuangma resin and 1 part of dicumyl peroxide, continue to mix until evenly mixed; after mixing, take it out and let it stand for 15 hours; then according to the required thickness And size, sheet; two-stage vulcanization: one-stage vulcanization, pressure vulcanization, pressure 10MPa, vulcanization temperature 200°C, vulcanization time 25min; two-stage vulcanization: normal pressure vulcanization, temperature 200°C, time 2h.

[0034] The prepa...

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PUM

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Abstract

The invention discloses a bismaleimide resin/silicone rubber ablation-resistant thermal insulation composite material and a preparation method thereof. The composite material is prepared from the following components in parts by mass: 20-80 parts of methylvinylsilicone rubber, 20-80 parts of methyl vinyl phenyl polysiloxane rubber, 1-5 parts of dicumyl peroxide, 15-40 parts of white carbon black, 5-15 parts of chopped fibers, 5-40 parts of bismaleimide, 1-5 parts of hydroxyl silicone oil and 1-20 parts of zirconium boride. The bismaleimide resin/silicone rubber ablation-resistant thermal insulation composite material has high vulcanization molding quality, and a dense hard carbon layer can be formed on the surface of an ablation layer of the thermal insulation composite material in the ablation process to play a role of preventing the thermal insulation composite material from further ablation, thereby improving the ablation resistance and antioxygenic property of the thermal insulation composite material, enabling the thermal insulation composite material to meet the requirements of operating environments with oxygen enrichment, high temperature, high-speed gas flow and particle erosion, and solving the problem that the thermal insulation material is easy to flaw and be burnt out under the working environments with high temperature, high pressure, oxygen enrichment and particle erosion.

Description

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Claims

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Application Information

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Owner 湖北三江航天江北机械工程有限公司
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