A kind of three-dimensional flower-shaped bismuth ferrite powder and preparation method thereof
A three-dimensional flower-like, bismuth ferrite technology, applied in the field of material science, can solve problems such as performance limitation and small specific surface area, and achieve the effects of good crystallinity, increased specific surface area, and uniform grain dispersion.
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[0031] A three-dimensional flower-like Bi 2 Fe 4 o 9 and preparation method thereof, comprising the following steps:
[0032] 1) According to Bi 2 Fe 4 o 9 The molar ratio in the weighed Bi(NO 3 ) 3 ·5H 2 O, Fe(NO 3 ) 3 9H 2 0, measure 10~15mL water and 1~2mL concentrated nitric acid (65wt.%), magnetically stir after mixing, make it fully dissolve and obtain mixed solution A; In the aqueous solution, the amount of bismuth ions and iron ions is carried out in the whole solution with the original ratio for the next reaction.
[0033] 2) Add 45-50 mL of 10-12 mol / L NaOH solution dropwise at a rate of two drops per second to the mixed solution A to precipitate Bi 3+ and Fe 3+, after obtaining the reddish-brown suspension B, continue stirring; when the NaOH concentration is in the range of 10-12 mol / L, the flaky bismuth ferrite with higher purity and uniform distribution can be obtained.
[0034] 3) Pour the suspension B into a polytetrafluoroethylene reactor, place i...
Embodiment 1
[0043] A three-dimensional flower-like Bi 2 Fe 4 o 9 and preparation method thereof, comprising the following steps:
[0044] (1) According to Bi 2 Fe 4 o 9 In the molar ratio, respectively weigh the Bi(NO 3 ) 3 ·5H 2 O, 2mmol of Fe(NO 3 ) 3 9H 2 O, 10mL of water and 1mL of concentrated nitric acid (65wt.%), magnetically stirred after mixing, fully dissolved to obtain mixed solution A;
[0045] (2) Slowly add 45mL 10mol / L NaOH solution dropwise to the mixed solution A to obtain the reddish-brown suspension B, then continue to stir;
[0046] (3) Pour the suspension B into a polytetrafluoroethylene reactor for a homogeneous hydrothermal reaction at a reaction temperature of 180°C for 6 hours;
[0047] (4) After the reaction kettle was cooled to room temperature, the precipitate obtained after the reaction was washed with deionized water and absolute ethanol, and then dried in an oven at 60° C. for 12 hours to obtain bismuth ferrite powder;
[0048] (5) Mix 3 mg of b...
Embodiment 2
[0054] Change the reaction time of the corrosion process in step (7) to 30min, 40min, 50min, 60min, 90min in sequence, and other conditions are the same as in Example 1.
[0055] After testing, when the reaction time of the corrosion process is 30 minutes, it can be observed that the complete flower-shaped bismuth ferrite cannot be obtained, and a small amount of thick flake bismuth ferrite can still be observed, but it is still a pure phase of bismuth ferrite; When the reaction time of the process is 60min and 90min, the complete flower-shaped bismuth ferrite can be obtained and the nanosheets are thinner, but Bi 25 FeO 40 and Bi 2 o 3 and other miscellaneous phases, so they do not meet the requirements. When the reaction time of the corrosion process is 40min and 50min, the XRD and SEM results meet the requirements; when the reaction time of the corrosion process is 40min, the phase is still bismuth ferrite, and the thick flaky bismuth ferrite disappears completely. The ...
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