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Mineral processing method of antimony sulfide ore

A technology of antimony sulfide ore and beneficiation method, which is applied in flotation, solid separation, etc. It can solve the problems of operational safety impact, low lead content of antimony concentrate, and large dosage of chemicals, so as to reduce production cost and have strong collection capacity , the effect of easy operation

Active Publication Date: 2017-05-31
锡矿山闪星锑业有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN101623673A discloses a kind of beneficiation method of antimony ore, adopts H 2 SO 4 As a pH adjuster for pulp, and then use Al 2 (SO 4 ) 3 As an antimony mineral activator, the resulting antimony concentrate contains low lead, but the antimony recovery rate is only 90.34%, the recovery rate is low, and the H 2 SO 4 The addition of it has a corrosive effect on the equipment and has a certain impact on the safety of the operation
However, by flotation recovery of carbon-containing lead-zinc-antimony ore, the highest grade of antimony in the obtained lead-antimony concentrate is only 12.55%, and the highest antimony recovery rate is only 70.23%. high problem

Method used

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  • Mineral processing method of antimony sulfide ore

Examples

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Comparison scheme
Effect test

Embodiment 1

[0026] Crush the raw antimony sulfide ore until the particle size is less than 14mm, grind the ore until the particle size is 200 mesh, and the mass percentage of the sieve is 72.50%. and three times of beneficiation to obtain antimony concentrate; among them, in the rough selection, 70g lead nitrate / t antimony ore is used as the activator, and 120gMA-3 / t antimony ore and 95g ethyl disulfide / t antimony ore are used as the combination Collector, with 130g new pinol oil / t antimony sulfide as foaming agent; in the first sweep and second sweep, both with 40g lead nitrate / t antimony sulfide as activator, both with 60gMA -3 / t antimony sulfide ore is used as collector; in the third sweeping and beneficiation, no chemicals are added.

Embodiment 2

[0028] Crush the raw antimony sulfide ore until the particle size is less than 14mm, grind the ore until the particle size is 200 mesh, and the mass percentage of the sieve is 70.00%. and three times of beneficiation to obtain antimony concentrate; among them, in the rough selection, 80g lead nitrate / t antimony ore is used as the activator, and 130gMA-3 / t antimony ore and 110g ethyl disulfide / t antimony ore are used as the combination Collector, with 150g new pinol oil / t antimony sulfide as foaming agent; in the first sweep and second sweep, both with 50g lead nitrate / t antimony sulfide as activator, both with 65gMA -3 / t antimony sulfide ore is used as collector; in the third sweeping and beneficiation, no chemicals are added.

Embodiment 3

[0030]Crush the raw antimony sulfide ore until the particle size is less than 14mm, grind the ore until the particle size is 200 mesh, and the mass percentage of the sieve is 74.00%, add water and stir to make the slurry until the mass concentration of the slurry is 33.0%. and three times of beneficiation to obtain antimony concentrate; among them, in the rough selection, 65g lead nitrate / t antimony ore is used as the activator, and 110gMA-3 / t antimony ore and 90g ethyl disulfide / t antimony ore are used as the combination As a collector, 120g pine alcohol oil / t antimony ore is used as a foaming agent; in the first sweep and the second sweep, 35g lead nitrate / t antimony ore is used as an activator, both with 55gMA -3 / t antimony sulfide ore is used as collector; in the third sweeping and beneficiation, no chemicals are added.

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Abstract

The invention relates to a mineral processing method of antimony sulfide ore. The mineral processing method comprises the following steps: crushing raw antimony sulfide ore, carrying out ore grinding, adding water, stirring, carrying out size mixing, recycling antimony sulfide minerals by adopting a flotation method, and carrying out roughing once, scavenging for three times and concentration for three times to obtain antimony concentrate, wherein lead nitrate is taken as an activating agent, xanthogenate mixture and B sulfur nitrogen are taken as a combined collecting agent and new coniferyl oil is taken as a foaming agent during the roughing, and the lead nitrate is taken as the activating agent and the xanthogenate mixture is taken as a collecting agent during primary scavenging and secondary scavenging. The method provided by the invention has the advantages that floatation collecting capability on the antimony sulfide minerals is strong, recycling effect is good, antimony recovery rate is more than or equal to 93.2% and is increased by 0.98% compared with the prior art, lead-antimony ratio in the antimony concentrate is reduced by more than or equal to 26.8%, and antimony concentrate grade is more than or equal to 50.0%; reaction conditions of the method provided by the invention are neutral, corrosive effect on mineral processing equipment is alleviated, operation safety is improved, and production cost is reduced; and the method provided by the invention is easy to operate, efficient and environmentally friendly.

Description

technical field [0001] The invention relates to a beneficiation method, in particular to a beneficiation method of antimony sulfide ore. Background technique [0002] Antimony and its compounds are widely used as important raw materials in industrial production and people's life. With the continuous mining of antimony metal mines, antimony resources are decreasing, and the grade of ore is getting lower and lower. Traditional conventional flotation reagents are used to And methods have been difficult to improve the mineral processing recovery. [0003] In order to improve the recovery rate of antimony in the process of antimony flotation, lead nitrate is used as antimony flotation activator, but some lead ions will enter the antimony concentrate, and lead is a harmful impurity in antimony concentrate, and antimony concentrate contains lead High will affect the grade of antimony concentrate, so as to affect the sales price. In addition, the antimony concentrate contains high...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/012B03D1/008B03D103/02B03D101/02B03D101/04
CPCB03D1/008B03D1/012B03D2201/02B03D2201/04B03D2203/02
Inventor 蒋康生尹华功李国康汪卫红康卧飞曾艳平刘华丽陈诚
Owner 锡矿山闪星锑业有限责任公司
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