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Synthetic method of 2,5-furan dimethanol and etherified product of 2,5-furan dimethanol

A technology of furan dimethanol and its synthesis method, which is applied in the field of synthesis of 2,5-furan dimethanol and its etherification products, can solve the problems of difficult acquisition of raw materials, high cost of catalysts, etc., and achieve good reusability and reaction system Simple and cost-effective

Active Publication Date: 2017-07-14
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The catalyst cost of this method is relatively high, and the raw materials are difficult to obtain and expensive

Method used

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  • Synthetic method of 2,5-furan dimethanol and etherified product of 2,5-furan dimethanol
  • Synthetic method of 2,5-furan dimethanol and etherified product of 2,5-furan dimethanol
  • Synthetic method of 2,5-furan dimethanol and etherified product of 2,5-furan dimethanol

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1～5

[0025] Add 0.4g 5-hydroxymethylfurfural and 19.6g isopropanol (2wt%) in the autoclave of 50mL, then add 0.2gZrO 2 / MCM-41, ZrO 2 / Beta1401, ZrO 2 / USY, ZrO 2 / SBA-15(ZrO 2 The loading capacity is 40%) as a catalyst, seal the reactor, stir vigorously (500rpm), heat to 150°C and keep for 2.5h, finish the reaction and cool to room temperature and take samples, use GC-MS (Shimadzu) and GC (Agilent) Qualitative and quantitative tests were carried out, and the test results are listed in Table 1, numbered 1-5.

Embodiment 6

[0027] Add 0.4g 5-hydroxymethylfurfural and 19.6g isopropanol (2wt%) in the autoclave of 50mL, then add 0.2gZrO 2 / SBA-15(ZrO 2 The loading amount is 40wt%) as a catalyst, seal the reactor, vigorously stir (500rpm), heat to 150 ° C and keep for 4h, finish the reaction and cool to room temperature and take samples, use GC-MS (Shimadzu) and GC (Agilent) to carry out Qualitative and quantitative detection, the detection results are listed in Table 1, the serial number is 6.

Embodiment 7～10

[0029] Add 0.4g 5-hydroxymethylfurfural and 19.6g methanol (2wt%) in the 50mL autoclave, then add 0.2gMgO-ZrO 2 / SBA-15,K 2 O-ZrO 2 / SBA-15, CaO-ZrO 2 / SBA-15, BaO-ZrO 2 / SBA-15 (the load of metal oxide is 40wt%, the mixing ratio of the two metal oxides is 1:1) as a catalyst, seal the reactor, stir vigorously (500rpm), heat to 100°C and keep it for 2.5h, After finishing the reaction, cool down to room temperature and take samples. GC-MS (Shimadzu) and GC (Agilent) are used for qualitative and quantitative detection. The detection results of different catalysts are listed in Table 1, numbered 7-10.

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PUM

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Abstract

The invention discloses a synthetic method of 2,5-furan dimethanol and an etherified product of 2,5-furan dimethanol and relates to 2,5-furan dimethanol. The synthetic method comprises the following steps of: adding organic alcohol into a reaction substrate; putting the obtained mixture as a raw material in a high pressure reaction kettle; adding a certain amount of a molecular sieve supported catalyst; and performing a heating reaction to obtain 2,5-furan dimethanol and the etherified product of 2,5-furan dimethanol. By using alcohol as a hydrogen donor and a reaction substrate, no external hydrogen source does not needed. By adjusting the acid-base property of a catalyst through an active metal component, 2,5-furan dimethanol can be obtained by selectively catalyzing transfer hydrogenation of 5-hydroxymethylfurfural or 2,5-dialkoxyl methyl furan is obtained by further etherification. The catalyst is cheap and easily available and good in repeatability, no excessively hydrogenated product exists, and the whole reaction is hydrogenated in a hydrogen environment, and the synthetic method has relatively strong operating safety of industrial production and very good industrial application potential.

Description

technical field [0001] The present invention relates to 2,5-furandimethanol, in particular to a method for synthesizing 2,5-furandimethanol and its etherified product using two-component active metal-supported molecular sieves to catalyze the transfer hydrogenation of 5-hydroxymethylfurfural . Background technique [0002] As a biomass-based furan derivative compound, 2,5-furandimethanol has a very wide application potential, and has attracted more and more attention from academia and industry in recent years. 2,5-furandimethanol can be used as a raw material to synthesize pharmaceutical intermediates, nucleoside derivatives, crown ethers and furans, and can also be used as solvents, softeners, wetting agents, binders, surfactants, synthetic plasticizers, etc. Second, it can be used as a monomer to synthesize polyester, polyurethane and other polymeric materials, reduce the content of volatile organic compounds in clothing coatings, and is expected to completely or partiall...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D307/46
Inventor 唐兴魏珺楠孙勇曾宪海林鹿雷廷宙
Owner XIAMEN UNIV
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