High-molecular special anticorrosive coating
An anti-corrosion coating and polymer technology, applied in anti-corrosion coatings, coatings, etc., can solve the problems of poor wear resistance, weather resistance, and insufficient toughness.
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[0096] The preparation method of the castor oil modified vinyl polymer is as follows: add 20 parts by weight of castor oil to a 200mL three-necked flask equipped with a condenser tube, then add 5 parts by weight of vinylthiophene and 10 parts by weight of vinylimidazole, stir evenly, and then Add 0.05 parts by weight of cyclohexanone peroxide, raise the temperature to 168° C. within 1 hour, stir at constant temperature for 15 hours, filter after cooling, wash with acetone, and dry in vacuum for 12 hours to obtain the product.
[0097] Each component of the present invention can produce synergistic effect, introduce castor oil in vinyl polymer, can improve the toughness of anticorrosion coating, the sulfur between mercaptosilane coupling agent, aminosilane coupling agent and vinylthiophene, vinylimidazole The action of sulfur and hydrogen bond can form multiple cross-linking points in the system, improving the wear resistance and weather resistance of the coating.
[0098] The ...
Embodiment 1
[0101] Polymer special anti-corrosion coating, in parts by weight, the preparation raw materials include: 40 parts of castor oil modified vinyl polymer, 5 parts of plasticizer, 0.8 part of silane coupling agent, 0.08 part of stabilizer, 2 parts of pigment, 50 parts of filler share. The preparation method of the castor oil modified vinyl polymer is as follows: add 20 parts by weight of castor oil to a 200mL three-necked flask equipped with a condenser tube, then add 5 parts by weight of vinylthiophene and 10 parts by weight of vinylimidazole, stir evenly, and then Add 0.05 parts by weight of cyclohexanone peroxide, raise the temperature to 168° C. within 1 hour, stir at constant temperature for 15 hours, filter after cooling, wash with acetone, and dry in vacuum for 12 hours to obtain the product. The plasticizer is dioctyl glutarate, and the silane coupling agent is N-(6-aminohexyl)aminomethyltriethoxysilane and diethoxy(3-mercaptopropyl)methylsilane in weight ratio 1:1 mixtu...
Embodiment 2
[0103] Polymer special anti-corrosion coating, in parts by weight, the preparation raw materials include: 40 parts of castor oil modified vinyl polymer, 5 parts of plasticizer, 0.8 part of silane coupling agent, 0.08 part of stabilizer, 2 parts of pigment, 50 parts of filler share. The preparation method of castor oil-modified vinyl polymer is as follows: add 20 parts by weight of castor oil to a 200mL three-necked flask equipped with a condenser, then add 15 parts by weight of vinylimidazole, stir evenly, and then add 0.05 parts by weight of peroxide For cyclohexanone, heat up to 168°C within 1 hour, stir at constant temperature for 15 hours, filter after cooling, wash with acetone, and dry in vacuum for 12 hours to obtain the product. The plasticizer is dioctyl glutarate, and the silane coupling agent is N-(6-aminohexyl)aminomethyltriethoxysilane and diethoxy(3-mercaptopropyl)methylsilane in weight ratio 1:1 mixture, the stabilizer is zinc laurate, the pigment is Dupont R-7...
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