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Modified phosphogypsum and phosphogypsum rigid waterproof mortar and preparation method thereof

A rigid waterproof and phosphogypsum technology, which is used in the field of building waterproofing to achieve the effects of improving compatibility, good compatibility and moderate setting time.

Active Publication Date: 2020-07-17
WUHAN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a phosphogypsum rigid waterproof mortar and its preparation method to solve the problem of solid waste phosphogypsum in the production of phosphoric acid and open up a new way for the utilization of phosphogypsum in view of the existing technical defects

Method used

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Effect test

preparation example Construction

[0036] A third aspect of the present invention provides a method for preparing the phosphogypsum rigid waterproof mortar, the method comprising:

[0037] Mix cement, nano-magnesia, fly ash and fine sand to obtain mixed powder;

[0038] Mix the mixed powder with water, then add modified phosphogypsum, and stir to obtain the mixed material;

[0039] The mixed material is poured, vibrated and maintained to obtain the phosphogypsum rigid waterproof mortar.

[0040] As a preferred version, mixing is carried out by a mixer, the mixing time of the mixed powder is 50-80s; the mixing time of the mixed powder and water is 50-80s; the modified phosphogypsum is added, and the mixed material is obtained by stirring. Stirring time is 60-120s; curing time is 28d.

[0041] All raw materials used to prepare the phosphogypsum rigid waterproof mortar of the present invention can be obtained commercially.

Embodiment 1

[0045] This embodiment provides a phosphogypsum rigid waterproof mortar, the preparation method of which is as follows: in parts by mass, pour 200 parts of cement, 5 parts of nano-magnesia, 5 parts of fly ash and 350 parts of fine sand into the mixer , stirred for 50 to 80 seconds; then poured in 100 parts of water weighed and stirred for 50 to 80 seconds; finally poured the modified phosphogypsum with an amount of 1wt% of the amount of cement, stirred for 60 to 120 seconds, and then poured and vibrated , cured for 28 days under standard curing conditions to obtain phosphogypsum rigid waterproof mortar;

[0046] Wherein, the modified phosphogypsum is prepared according to the following method:

[0047] (1) mixing phosphogypsum with quicklime, aging for 24 hours to obtain the initial material, in parts by mass, relative to 100 parts of the phosphogypsum, 10 parts of the quicklime;

[0048] (2) Pour the initial material and water into a mixer and mix evenly, then adjust the pH ...

Embodiment 2

[0052]This embodiment provides a phosphogypsum rigid waterproof mortar, the preparation method of which is as follows: in parts by mass, pour 220 parts of cement, 5 parts of nano-magnesia, 10 parts of fly ash and 400 parts of fine sand into the mixer , stirred for 50 to 80 seconds; then poured 80 parts of weighed water and stirred for 50 to 80 seconds; finally poured the modified phosphogypsum with an amount of 3wt% of the amount of cement, stirred for 60 to 120 seconds, and then poured and vibrated , cured for 28 days under standard curing conditions to obtain phosphogypsum rigid waterproof mortar;

[0053] Wherein, the preparation method and parameters of the modified phosphogypsum in this embodiment and the dosage of each material are the same as those in Embodiment 1.

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Abstract

The invention discloses a modified phosphogypsum and phosphogypsum rigid waterproof mortar and a preparation method thereof. The modified phosphogypsum is prepared according to the following method: (1) mixing the phosphogypsum with quicklime and aging to obtain an initial material; (2) ) uniformly mix the initial material with water, then adjust the pH value to 6-8, filter and dry to obtain the treated phosphogypsum; (3) mix the treated phosphogypsum with the reaction solution A to form a mixed solution B, The reaction solution A is an ethanol solution of a modifying agent; (4) adjust the pH value of the mixed solution B to 6-8, heat and dry, and grind to obtain modified phosphogypsum; the present invention can make full use of the waste phosphogypsum It solves the problem of phosphogypsum treatment and lays the foundation for broadening the application of phosphogypsum.

Description

technical field [0001] The invention belongs to the field of building waterproofing, and more specifically relates to a modified phosphogypsum and phosphogypsum rigid waterproof mortar and a preparation method thereof. Background technique [0002] The main cause of damage to cement-based structures is the corrosion of cement-based materials by external environmental factors. Among them, water is an important factor causing durability problems of cement-based structures. As we all know, ordinary concrete or mortar is essentially a heterogeneous, porous composite material. The main measure to reduce the permeability of concrete (mortar) is to reduce its hardened porosity, thereby improving its impermeability and waterproof performance. The use of waterproof materials is the main measure commonly used to improve the impermeability and waterproof performance of concrete (mortar). Among them, rigid waterproof material is a category of waterproof material, which refers to the m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B22/14C04B20/02C04B28/00C04B111/34
CPCC04B20/023C04B22/144C04B28/00C04B2111/343C04B22/066C04B18/08C04B14/06C04B22/002
Inventor 刘杰胜龚晓强李发平张荣堂董莪何翔涂妮郑方方
Owner WUHAN POLYTECHNIC UNIVERSITY