Collector layer structure

Abstract

The present invention provides a collector layer structure, which includes a conductive substrate and a plurality of insulating regions, the conductive substrate has a plurality of holes, each hole has two openings, the insulating region is formed at least covering the periphery of the opening, and At least part of the surface of the conductive substrate remains bare. When lithium ions undergo electrochemical reactions inside the battery, since the insulating region formed at the periphery of the opening has the characteristics of electronic insulation, it can avoid concentrated deposition of lithium ions near the opening of the conductive substrate, thereby reducing the formation of lithium synapses on the conductive substrate. probability on the surface, or even the possibility of continuing to grow along the hole and towards the direction of the isolation layer, the current collector layer structure disclosed in the present invention can effectively control the position and growth amount of lithium synapse formation, and improve the overall safety of the battery sex.

Description

technical field [0001] The present invention relates to a collector layer and an applied electrode plate thereof, in particular to a collector layer with an insulating region, and generally used as a collector layer structure of a negative electrode layer. Background technique [0002] For existing lithium batteries, the most difficult problem to solve is that during the electrochemical reaction inside the battery, because the collector layer (usually copper foil) of the negative electrode plate is approaching the state of lithium relative potential 0 volts Under the condition, the deposition and deposition reaction of lithium ions will continue on the surface of the collector layer, resulting in the formation of a large number of lithium synapses. The formation of lithium synapses not only consumes the amount of lithium ions inside the battery, but also makes the capacity cycle It gradually decreases after use, and because of the dendrite structure of the lithium synapse, i...

AI Technical Summary

Problems solved by technology

[0002] For existing lithium batteries, the most difficult problem to solve is that during the electrochemical reaction inside the battery, because the collector layer (usually copper foil) of the negative electrode plate is approaching the state of lithium relative potential 0 volts Under the condition, the deposition and deposition reaction of lithium ions will continue on the surface of the collector layer, resulting in the formation of a large number of lithium synapses. The formation of lithium synapses not only consumes the amount of lithium ions inside the battery, but also makes the capacity cycle It gradually decreases after use, and because of the dendrite structure of the lithium synapse, it is easy to cause its sharp end to pierce the isolation layer. Once the structure of the isolation layer is damaged, it will cause an internal short circuit or even an explosion of the battery. situation

[0003] For the above bottleneck, one of the more common solutions is to use additives in the electrolyte, according to different additives, to reduce the probability of lithium ion deposition reaction, for example: reduce the activation energy of lithium ion formation passive layer (SEIlayer) reaction Make more lithium ions tend to form a passive layer without deposition reaction, or provide specific functional groups to generate lithium intermediates, so as to interfere with the deposition reaction of lithium ions. In addition, by using specific negative active materials, For example: Lithium Titanium Oxide (LTO), in order to prevent the negative electrode active material from being in the state of lithium relative potential 0 volts during the charging process, it can prevent lithium ions from depositing on the negative electrode plate. However, the above methods will Causes some obstacles to the deposition reaction of lithium ions, but the degree of influence is still limited, and in terms of the method of adding additives to the electrolyte, because the use of additives is usually accompanied by some side reactions, so although the deposition reaction is reduced Lithium ions, but some side reactions will reduce the efficiency of the electrochemical reaction inside the battery. In addition, when the active material of the negative plate is changed to lithium titanium oxide, because the potential of lithium titanium oxide is about 1.5 volts higher than that of lithium , when using the existing positive electrode material, the battery discharge voltage will be reduced to about 2.4V. Under the premise that the theoretical capacitance of lithium titanium oxide is equivalent to that of graphite, the energy density provided by the battery using lithium titanium oxide will be reduced. sacrifice

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