Pyridine anthracene derivative platinum coordination compound as well as synthesis and application thereof
A coordination compound, pyridine-like anthracene technology, applied in the field of pyridine-like anthracene derivative platinum coordination compound and its synthesis and application, can solve the problems of unstable light color and low efficiency
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Embodiment 1
[0088] The structural formula of the pyridine anthracene derivative platinum coordination compound in this example is shown in formula 1, and the main chemical reactions in its preparation method are as follows:
[0089]
[0090] (1) Suzuki coupling reaction: under nitrogen protection, 3-bis(4,4,5,5-tetramethyl-1,3,2-boronic acid pinacol ester) benzene (2.5g, 7.58mmol) , 5-bromo-2-iodopyridine (5.2g, 18.2mmol), tetrakis(triphenylphosphine) palladium (105mg, 0.09mmol), toluene (300mL) and potassium carbonate aqueous solution (150mL 2M) were put into 1000ml three-port round bottom Stirring in the flask, the mixture was heated to 90° C. for 12 hours under the protection of nitrogen flow. Naturally cool to room temperature after completion of the reaction, the crude product is washed by using dichloromethane (400ml) and deionized water (4 / 300mL), separates the organic layer, filters after drying with magnesium sulfate, and obtains the crude product by distillation under reduced...
Embodiment 2
[0098] The structural formula of the pyridine anthracene derivative platinum coordination compound in this example is shown in Formula 2, and the main chemical reactions in its preparation method are as follows:
[0099]
[0100]
[0101] (1) Suzuki coupling reaction: under the protection of nitrogen, 2,2'-(5-fluoro-1,3-benzene)bis(4,4,5,5-tetramethyl-1,3,2- Pinacol borate) (1.74g, 5mmol), 5-bromo-2-iodopyridine (2.55g, 9mmol), tetrakis(triphenylphosphine)palladium (208mg, 0.18mmol), toluene (40mL) and potassium carbonate The aqueous solution (20mL, 2M) was put into a 250ml three-necked round-bottomed flask and stirred, and the mixture was heated to 90°C under the protection of nitrogen flow for 12 hours. Naturally cool to room temperature after completion of the reaction, the crude product is washed with dichloromethane (40ml) and deionized water (4 / 30mL), separates the organic layer, filters after drying with magnesium sulfate, and distills under reduced pressure to ob...
Embodiment 3
[0109] The structural formula of the pyridine anthracene derivative platinum coordination compound in this example is shown in formula 9, and the main chemical reactions in its preparation method are as follows:
[0110]
[0111]
[0112] (1) Suzuki coupling reaction: under nitrogen protection, 1,3-bis[2-(5-bromopyridine)]-benzene (200mg, 0.512mmol), [10-(1-naphthalene) 9-anthracene] Boric acid (428mg, 1.23mmol), tetrakis (triphenylphosphine) palladium (29.6mg, 0.026mmol), toluene (80mL) and aqueous potassium carbonate (40mL, 2M) were put into a 250ml three-necked round-bottomed flask and stirred, and the mixture was Heated to 90° C. under the protection of nitrogen flow for 12 hours. Naturally cool to room temperature after completion of the reaction, the crude product is washed with dichloromethane (40ml) and deionized water (4 / 30mL), separates the organic layer, filters after drying with magnesium sulfate, and distills under reduced pressure to obtain the crude produc...
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