37results about How to "Achieve white light emission" patented technology

The invention discloses barcode-structure fluorescent ceramic for white LED devices. The barcode-structure fluorescent ceramic is composed of two or more ceramic units. The ceramic units emit light of different colors after being excited by the same LED lamp, and the light is synthesized into full-spectrum white light and then emitted out. The ceramic units are arranged alternately and closely in the horizontal plane to form an integrated structure similar to a barcode. After being excited by an LED chip arranged above or below the ceramic, the fluorescent ceramic of a barcode structure emits white light. The fluorescent ceramic has the characteristics of flexible spectrum adjustment, high light conversion efficiency and color rendering index, long service life, and good thermal stability. For a white LED device using the fluorescent ceramic, efficient utilization of energy is realized, and a small and compact lighting system is ensured. Therefore, the barcode-structure fluorescent ceramic can make up for the deficiency of the prior art and meet the requirement of market commercialization.

The invention discloses an organic porous polymer which is shown as the following general molecular formula and constructed by taking pyrene and 9,9-dioctylfluorene as monomers: (the general molecularformula is shown in the specification). The organic porous polymer can be used as an organic electroluminescence material for preparing a white light-emitting organic electroluminescence material bybeing doped with other micromolecular organic electroluminescence materials with complementary emitting colors. The doped other micromolecular organic electroluminescence materials can enter holes ofthe organic porous polymer, so as to keep the single-phase property of the polymer, avoid the phase separation and interface degradation phenomena caused by doping, and keep the emitting color stable.

The invention discloses a green light luminescent material which comprises the material with the following chemical formula: a CaO. B Al2O3, c SiO2: x Tb, wherein the a is larger than and equal to 0.4 and is less than and equal to 2.5, the b is larger than or equal to 0.2 and is less than or equal to 1.5, the c=1.0, and the x is larger than or equal to 0.001 and is less than or equal to 0.8. The green light luminescent material has high luminous efficiency, good stability and high luminous intensity, can be used in 'UV-LED+red, green and blue three-base color fluorescent powder', and replacesthe LED chip and is matched with the cerium-activated tombarthite garnet yellow fluorescent powder to send the white light. The preparation method of the green light luminescent material comprises the following steps of: adopting at least one oxide, carbonate and oxalate of Ca, Al2O3, SiO2 and Tb4O7 as raw materials, calcinating at high temperature under the reducing atmosphere, cooling to room temperature, and grinding to obtain the green light luminescent material. The preparation method of the green light luminescent material is simple in technology step, easy to control the technical conditions, easy to operate and low in cost.

The invention discloses a preparation method of a beta-Ca3(PO4)2 type phosphate luminescent material with adjustable luminescent color and a luminescent material prepared by the method, and belongs tothe technical field of luminescent materials. The preparation method which adopts two steps of a sol-gel method comprises the following steps: preparing a CMNP precursor by a first step of the sol-gel method, and preparing Ca9EuNa(PO4)7 wet sol by a second step of the sol-gel method; and calcining Ca9MnNa(PO4)7 xerogel at low temperature to obtain the CMNP precursor, dispersing the CMNP precursorin the Ca9EuNa(PO4)7 wet sol to obtain a uniform mixture, then heating the uniform mixture to form mixed xerogel, and finally, calcining the mixed xerogel to obtain the phosphate luminescent material. From the aspect of synthesis, the luminescent property of the CMNP material is regulated and controlled by a two-step sol-gel synthesis strategy, and thus, regulation and control of the material from red light to yellow light to white light to green light are realized. The method is simple and easy to operate, and the obtained material has favorable properties.

The invention relates to a preparation method of a nitride-boride fluorescent powder material. The preparation method is characterized in that common metal salt or oxide is used as the raw material, a high-temperature solid-phase method is used for preparation, the preparation process of nitride fluorescent powder is simplified, and production cost is lowered. The expression of the nitride-boride fluorescent powder material is AM4-4x(BN2):xD, wherein A is one or more of Li, Na, K, Rb and Cs; M is one or more of Mg, Ca, Sr and Ba, and D is one or more of Mn<2+>, Ce<3+>, Pr<3+>, Nd<3+>, Pm<3+>, Sm<3+>, Sm<2+>, Eu<3+>, Eu<2+>, Tb<3+>, Dy<3+>, Ho<3+>, Er<3+>, Tm<3+>, Yb<3+> and Yb<2+>. The preparation method specifically includes: weighing the raw materials of A, M and D and boric acid according to stoichiometric ratio, adding appropriate amount of acetone into the raw materials, and sufficiently grinding to obtain a mixture; performing heat preservation on the mixture for 1-5 hours in an environment of 400-650 DEG C and under reduction atmosphere; grinding and evenly mixing obtained preliminary-combustion substance, and performing heat preservation on the mixture for 1-8 hours in an environment of 700-900 DEG C to obtain the nitride-boride fluorescent powder material. The preparation method has the advantages that the method using a solid-phase synthesizing method is low in synthesizing temperature, simple in preparation process, low in cost, safe, reliable, short in production cycle and suitable for large-scale industrial production, and the prepared fluorescent powder is excellent in light-emitting efficiency.

The invention relates to rare earth-doped halide glass ceramics and a preparation method thereof. The glass ceramics are prepared through microcrystallization heat treatment, and the composition of the glass ceramics is: (100-x)(ZrF4-BaF2-YF3-AlF3)-xBaCl2:Re<3+>, wherein the value range of x is 0-33; Re<3+> is codoping of Pr<3+> and Ho<3+>, and the concentration proportional range of the Pr<3+> tothe Ho<3+> is 0.25-3. The glass ceramics involved in the invention have the characteristics of high fluorescence intensity and low cost, enhance the fluorescence intensity of the rare earth ions Pr<3+> and Ho<3+> under excitation of 445 nm blue light and X rays, and can be applied to the fields of white light emitting diode, scintillating materials and the like.

The invention discloses barcode-structure fluorescent ceramic for white LED devices. The barcode-structure fluorescent ceramic is composed of two or more ceramic units. The ceramic units emit light of different colors after being excited by the same LED lamp, and the light is synthesized into full-spectrum white light and then emitted out. The ceramic units are arranged alternately and closely in the horizontal plane to form an integrated structure similar to a barcode. After being excited by an LED chip arranged above or below the ceramic, the fluorescent ceramic of a barcode structure emits white light. The fluorescent ceramic has the characteristics of flexible spectrum adjustment, high light conversion efficiency and color rendering index, long service life, and good thermal stability. For a white LED device using the fluorescent ceramic, efficient utilization of energy is realized, and a small and compact lighting system is ensured. Therefore, the barcode-structure fluorescent ceramic can make up for the deficiency of the prior art and meet the requirement of market commercialization.

The invention discloses a pyridine-type anthracene derivative platinum coordination compound and its synthesis and application. The pyridine-type anthracene derivative platinum coordination compound is centered on the pyridine derivative platinum complex and anthracene group is added to reduce The triplet state of the entire molecule realizes near-infrared emission; and through the arrangement of the anthracene group on the molecule, the metal-to-ligand charge-transfer state and the metal-to-metal-to-ligand charge-transfer state are realized to achieve dual phosphorescent emission. The pyridine anthracene derivative platinum coordination compound can be used for temperature detection and as an electroluminescent material, and is a new temperature detection, single-molecule white light and near-infrared luminescent material. The present invention improves the key chemical structure and preparation process of the pyridine anthracene derivative platinum coordination compound, and obtains a new type of temperature detection, single-molecule white light and near-infrared based on the pyridine anthracene derivative platinum coordination compound. luminescent material, and the preparation method in the present invention is simple and feasible.

The invention relates to a white light-emitting aluminum nitride material injected with a rare earth element as well as a preparation method and an application of the white light-emitting aluminum nitride material. The preparation method comprises the steps of putting an aluminum nitride film material with the thickness of 50-100nm in an ion injecting device, and carrying out Pr, Er and Tm rare earth ion injecting and annealing treatments respectively, wherein the injecting energy range is 200-400KeV, the injecting angle is 0-10 degrees, the injecting doses of ions are equal and are 10<14>-10<16> per square centimeters respectively. The aluminum nitride material has the function of white light emission, can be used as a core function material and is applied to the fields of light-emitting diodes, panel display and the like.

The invention discloses an ESIPT luminescent material with delayed fluorescence properties, a preparation method and application thereof. Based on the special properties of ESIPT, the invention designs and synthesizes a luminescent material with delayed fluorescence characteristics and large Stokes shift. At the same time, the ESIPT luminescent material of the present invention has suitable molecular energy levels, high luminous efficiency, and good film-forming properties, and can be used as a yellow light doping material to prepare a non-energy transfer luminescent film. In the finished organic electroluminescent device, the ESIPT light-emitting material of the present invention does not undergo energy transfer with the host material, and the ratio control of the host-guest luminescence peak can be realized by adjusting the doping ratio, thereby successfully preparing a repeatable chromaticity Tunable multi-color light-emitting OLED.

The invention provides a d-p heteronuclear bimetallic organic framework material capable of white light emission and a preparation method thereof; the molecular formula of the d-p heteronuclear bimetallic organic framework material is: {[Pb 2 Zn(L) 2 (H 2 O) 2 ]·NMP·H 2 O} n ; The present invention also relates to the preparation method of material. The invention is synthesized under hydrothermal conditions, has simple process, low cost and good repeatability. The Pb-Zn-based HMOF material prepared by the present invention can realize white light emission under the irradiation of an ultraviolet lamp, and has good chemical stability and thermal stability, and is an excellent new high-efficiency luminescent crystal material. The Pb-Zn-based HMOF material prepared by the present invention can realize white light emission under the irradiation of an ultraviolet lamp, and can be applied to light-emitting diodes, fluorescent immunoassays, optical fiber communications, photochemical sensing, and the like.

The invention discloses a single-substrate white-light fluorescent powder for white-light LEDs (light-emitting diodes) and a preparation method thereof, belonging to the technical field of preparation of LED fluorescent powder. The composition expression of the white-light fluorescent powder is NaLaMgWO6:xTm<3+>,yDy<3+>,zEu<3+>, wherein x=0.07-0.2, y=0.01-0.07, and z=0.01-0.07. The preparation method comprises the following steps: 1) mixing Na2CO3, La2O3, Mg(NO3)2.6H2O, WO3, Tm2O3, Dy2O3 and Eu2O3 in a mole ratio of (0.5-2):(0.5-2):(0.5-2):1:x / 2:y / 2:z / 2, and grinding uniformly to obtain a powder mixture; and 2) carrying out solid-phase sintering on the powder mixture in a weakly reducing atmosphere to obtain the white-light fluorescent powder. The method is simple to operate, has the advantages of low facility request and environment friendliness, and is suitable for industrialized large-scale production.

The invention discloses a green light luminescent material which comprises the material with the following chemical formula: a CaO. B Al2O3, c SiO2: x Tb, wherein the a is larger than and equal to 0.4 and is less than and equal to 2.5, the b is larger than or equal to 0.2 and is less than or equal to 1.5, the c=1.0, and the x is larger than or equal to 0.001 and is less than or equal to 0.8. The green light luminescent material has high luminous efficiency, good stability and high luminous intensity, can be used in 'UV-LED+red, green and blue three-base color fluorescent powder', and replaces the LED chip and is matched with the cerium-activated tombarthite garnet yellow fluorescent powder to send the white light. The preparation method of the green light luminescent material comprises the following steps of: adopting at least one oxide, carbonate and oxalate of Ca, Al2O3, SiO2 and Tb4O7 as raw materials, calcinating at high temperature under the reducing atmosphere, cooling to room temperature, and grinding to obtain the green light luminescent material. The preparation method of the green light luminescent material is simple in technology step, easy to control the technical conditions, easy to operate and low in cost.

The invention discloses a single-layer exciter complex and a single-molecular excicomplex white light polymer, a preparation method thereof and an application in an organic light-emitting diode. A device based on the blending of two blue light polymers can realize binary white light emission, and the invention provides a single-layer exciplex capable of emitting white light, which has high application value. And through molecular design, suitable electron donors and acceptors are respectively introduced into the polymer chain to form intramolecular exciplexes and realize exciplex-type single-molecule white light emission. The preparation method of the single-layer exciplex type complementary white light device is simple and easy, is suitable for solution processing such as solution spin coating and inkjet printing, and has good practicability in the application of white light organic light emitting diodes.

The invention discloses a β-Ca with adjustable emission color 3 (PO 4 ) 2 The invention discloses a method for preparing a type phosphate luminescent material and the luminescent material prepared by the method, belonging to the technical field of luminescent materials. The present invention adopts two-step sol-gel method, the first step sol-gel method prepares CMNP precursor, the second step sol-gel method prepares Ca 9 EuNa(PO 4 ) 7 Wet sol; the Ca 9 MnNa(PO 4 ) 7 The CMNP precursor obtained after the xerogel was calcined at low temperature was dispersed in Ca 9 EuNa(PO 4 ) 7 In the wet sol, after obtaining a homogeneous mixture, it is heated to form a mixed xerogel, and is finally calcined to obtain a phosphate luminescent material. From the perspective of synthesis, the present invention adopts a two-step sol-gel synthesis strategy to regulate the luminescent properties of CMNP materials, and realizes the regulation of materials from red light to yellow light to white light to green light. The method is simple and easy to operate, and the obtained materials have good properties.

Disclosed in the invention is a quantum-dot white-light light-emitting diode comprising a substrate, an N-GaN layer, an active layer, a P-GaN layer, an N electrode, a P electrode and a transparent electric contact layer. The N-GaN layer, the active layer, the P-GaN layer, and the transparent electric contact layer are arranged on the substrate successively; the N-GaN layer and the P-GaN layer are connected with the N electrode and the P electrode. Conductive particles and red-light, yellow-light and green-light quantum dots are arranged in the transparent electric contact layer. According to the invention, the transparent electric contact layer having the conductive particles and red-light, yellow-light and green-light quantum dots is arranged on the P type layer, thereby forming the transparent electric contact layer generating multi-wavelength fluorescent light. After the transparent electric contact layer is stimulated by blue light emitted by a gallium-nitride-based light-emitting diode, white light emitting of a single chip is realized.

The invention relates to the field of a semiconductor, and discloses an LED epitaxial structure. The LED epitaxial structure comprises a substrate, a nucleating layer, a non-doped GaN layer, an n type GaN layer and a porous SiN<x> layer on the n type GaN layer, and also comprises an n type GaN hexagonal-pyramid array formed in the holes of the porous SiN<x> layer, and quantum dots on the peak of the hexagonal pyramid, quantum lines on the six ridges and a multi-quantum-well layer on six semi-polar (10-11) crystal surfaces, and a p type GaN filling layer at the tail part; and the GaN hexagonal pyramid and the quantum dots / lines / well layer at different positions thereon form the three-dimensional core-shell structure. The structure is large in light emitting area and high in light extracting efficiency; in addition, due to influences of different In contents and polarization effects and other factors, the light emitting wavelengths of the quantum dots / lines / well structures are also different; through reasonable control, white light emission can be realized; in the preparation method of the GaN hexagonal pyramid array, substrate patterning is not needed, so that the technological process is simple; and meanwhile, the grown GaN crystals are high in quality, so that the luminous efficiency of the LED can be improved effectively.