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Method for recovering ethylene and vinyl-based comonomer

A comonomer and vinyl technology, which is applied in the field of recycling ethylene and vinyl-based comonomers, can solve the problems of high cost, consumption, and insufficient recycling, and achieve the effect of cost minimization

Active Publication Date: 2018-06-08
LG CHEM LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, there is also a limitation that unreacted monomers cannot be recovered sufficiently from the final product
There is also a limitation in terms of process efficiency, i.e. a significant cost is consumed in the compression process used to feed the depressurized unreacted monomer to the high pressure reactor

Method used

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  • Method for recovering ethylene and vinyl-based comonomer
  • Method for recovering ethylene and vinyl-based comonomer
  • Method for recovering ethylene and vinyl-based comonomer

Examples

Experimental program
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Embodiment 1 to 7

[0056]

[0057] refer to figure 1 , Vinyl acetate monomer from vessel 1 and ethylene monomer from vessel 2 were respectively fed into reactor 3 at a temperature of about 150° C. to 250° C. and a pressure of 2000 bar for radical polymerization. After the reaction is complete, the mixture of ethylene-vinyl acetate polymer and unreacted monomers in the reactor 3 is transferred to the first separator 4 at a temperature of about 200°C to 250°C and a pressure of 250 bar.

[0058] In the first separator 4, the mixture of unreacted monomers is separated in a gaseous state in the upper part of the first separator 4, and the mixture of ethylene-vinyl acetate polymer and some unreacted monomers is separated in the lower part of the first separator 4 Separated in liquid phase. The mixture of unreacted monomers separated in the upper part of the first separator 4 was compressed to a pressure of 2000 bar by the first compressor 7 having a pressure of 250 bar, and then polymerized in the...

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Abstract

The present invention relates to a method for recovering ethylene and a vinyl-based comonomer, the method improving the recovery rate of unreacted monomers remaining after the polymerization reactionof ethylene and a vinyl-based comonomer, and enabling process efficiency to increase through a cost reduction. Specifically, the method for recovering ethylene and a vinyl-based comonomer can comprisethe steps of: polymerizing ethylene and a vinyl-based comonomer at a pressure of 1,500 bar or higher; reducing, to 0.1-5 bar, the pressure of the product of the polymerization step, comprising an ethylene-vinyl-based comonomer copolymer, ethylene, and a vinyl-based comonomer; adding ethylene to the product of the polymerization step under the pressure of 0.1-5 bar; and separating ethylene and a vinyl-based copolymer from the product of the polymerization step in which the ethylene is added.

Description

technical field [0001] Cross References to Related Applications [0002] This application claims the benefit of priority from Korean Patent Application No. 10-2016-0119375 filed with the Korean Intellectual Property Office on Sep. 19, 2016, the entire contents of which are incorporated herein by reference. [0003] The present invention relates to a process for the recovery of ethylene and vinyl-based comonomers. More specifically, the present invention relates to a method for recovering ethylene and vinyl-based comonomers, which improves the recovery of unreacted monomers remaining after polymerization of ethylene and vinyl-based comonomers, and by Reduce costs to increase process efficiency. Background technique [0004] The ethylene copolymer is a material in which various vinyl-based comonomers have been introduced into the existing properties of LDPE (low density polyethylene), and it has been developed for various uses and widely commercialized. [0005] Ethylene c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F6/00C08F210/02C08F2/00C08J11/02
CPCC08F6/001C08L101/00C08L23/0815C08L23/0853C08F210/02C08F2/00C08J11/02C08F6/005
Inventor 申大荣周垠廷申俊浩许畅会张诚根
Owner LG CHEM LTD
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