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Material for organic electroluminescence device

A technology of electronic devices and groups, applied in the field of materials for organic electroluminescent devices, can solve problems such as expensive and complicated processes

Pending Publication Date: 2018-10-19
MERCK PATENT GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Processes based on vapor deposition yield good results, but such processes are complex and expensive

Method used

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  • Material for organic electroluminescence device
  • Material for organic electroluminescence device
  • Material for organic electroluminescence device

Examples

Experimental program
Comparison scheme
Effect test

Synthetic example

[0137] The scheme of synthetic embodiment compound 1

[0138]

[0139] Synthesis of ArL group

[0140] Synthesis of compound Int1.1

[0141]

[0142] 30g (97.5mmol) of 2-bromo-7-chloro-9,9-dimethyl-9H-fluorene (see JP 2003277305 A), 25.5g (107.3mmol) of (9,9-dimethylfluorene-2- Base) boronic acid 90g (390mmol), 0.9g (4mmol) palladium (II) acetate and 3.6g (11.7mmol) tri (o-tolyl) phosphine in 1L toluene, di Mix in alkane and water (1:1:1) and stir at reflux overnight. After cooling to room temperature, 200 mL of toluene was added, the organic phase was separated and washed with water (2 x 200 mL), and the combined organic phases were concentrated under reduced pressure. The residue was purified by recrystallization from toluene / heptane.

[0143] Yield: 39.1 g (93 mmol; 96%).

[0144] The following compounds can be synthesized in a similar manner:

[0145]

[0146] Synthesis of ArL1

[0147]

[0148] 40g (95mmol) Int1.1, 38.6g (152mmol) bis-(pinacolate) dibo...

Embodiment V1

[0196] The substrate pretreatment of embodiment V1, E1 to E8:

[0197] A glass plate with structured ITO (50nm, indium tin oxide) was coated with 20nm PEDOT:PSS (poly(3,4-ethylenedioxythiophene), poly(styrene-sulfonate, CLEVIOS TM P VP AI 4083, from Heraeus Precious Metals GmbH, Germany, was spin-coated from a water-based solution) as a buffer layer to form the substrate on which the OLED device was fabricated.

[0198] The OLED device basically has the following layer structure:

[0199] - base,

[0200] -ITO (50nm),

[0201] - buffer layer (20nm),

[0202] - a hole transport layer (HTL),

[0203] - optional interlayer (IL),

[0204] - emissive layer (EML),

[0205] - optional hole blocking layer (HBL),

[0206] - Electron Transport Layer (ETL),

[0207] - electron injection layer (EIL),

[0208] -cathode.

[0209] The cathode was formed from an aluminum layer with a thickness of 100 nm. The detailed stack sequence is shown in Table A. Table C shows the materials ...

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Abstract

The invention relates to a material for an organic electroluminescence device. Specifically, the invention relates to a formula (1) compound suitable for an electronic device, particularly an organicelectroluminescence device, and an electronic device containing the compounds.

Description

technical field [0001] The invention relates to a material for organic electroluminescent devices. In particular, the present invention relates to compounds of formula (1), their use in electronic devices and electronic devices comprising compounds of formula (1). The invention also relates to processes for the preparation of compounds of formula (1) and formulations comprising one or more compounds of formula (1). Background technique [0002] The development of functional compounds for use in electronic devices is the subject of intense current research. The aim is in particular to develop compounds with which improvements in the properties of electronic devices can be achieved at one or more relevant points, for example in the power efficiency and lifetime of the devices and in the color coordinates of the emitted light. [0003] According to the present invention, the term electronic device is considered to mean, inter alia, organic integrated circuits (OICs), organic ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D307/93C07D307/94C09K11/06H01L51/50H01L51/54H10K99/00
CPCC07D307/93C07D307/94C09K11/06C09K2211/1022C09K2211/1014C09K2211/1011C09K2211/1007C09K2211/1088H10K85/636H10K85/6574H10K50/00C07D493/04H05B33/14H05B33/20Y02E10/549H10K85/615H10K50/11C07D407/12
Inventor 鲁文·林格塞巴斯汀·迈耶拉拉-伊莎贝尔·罗德里格斯
Owner MERCK PATENT GMBH