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ingap/ingaas/ge triple-junction solar cell with micro-nano anti-reflection structure and manufacturing method

A solar cell and inverse structure technology, applied in circuits, electrical components, photovoltaic power generation, etc., can solve the problems of restricting sufficient absorption of incident light, restricting photoelectric conversion efficiency, etc., to increase incident optical path, increase optical path and effective light absorption. , the effect of high anti-reflection characteristics

Active Publication Date: 2019-12-31
西安纳智光研科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the thickness of the effective light-absorbing layer is too thin, it will limit the sufficient absorption of incident light, which seriously restricts the improvement of photoelectric conversion efficiency.

Method used

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  • ingap/ingaas/ge triple-junction solar cell with micro-nano anti-reflection structure and manufacturing method
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  • ingap/ingaas/ge triple-junction solar cell with micro-nano anti-reflection structure and manufacturing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] 1)选择p型Ge衬底,抛光,清洗,在Ge表面淀积P原子,Ge衬底加热到700℃,形成n-Ge层。

[0068] 2)在Ge表面继续引入含In元素和Ga元素的气体与含P元素气体一起生长InGaP第一异质层;

[0069] 3)采用MOVPE的方法生长n-InGaAs缓冲层;

[0070] 4)采用纳米软压印法,在n-InGaAs缓冲层表面制备条栅结构;

[0071]5) The p-GaAs / n-GaAs tunnel junction, p-InGaP BSF layer, p-InGaAs base, n-InGaAs emitter and n-InGaP window are sequentially grown by MOVPE method;

[0072] 6) Prepare a grid structure on the surface of the n-InGaP window by using the nano soft imprint method;

[0073] 7) Using MOVPE method to grow p-AlGaAs / n-InGaP tunnel junction, p-AlInP BSF layer, p-InGaP base, n-InGaP emitter, n-AlInP window and GaAs layer sequentially;

[0074] 8) Prepare a composite micro-nano structure on the surface of GaAs by using nano-soft imprinting method;

[0075] The process flow for preparing the composite micro-nano structure is as follows:

[0076] 8a) The SU-8 gel was spun at 500rpm for 30s, then at 3000rpm for 5min; then baked at 65°C for 10min, then at 95°C for 20min; UV light curing for 30...

Embodiment 2

[0082] 1) Select a p-type Ge substrate, polish, clean, deposit P atoms on the Ge surface, and heat the Ge substrate to 750°C to form an n-Ge layer.

[0083] 2) Continue to introduce the gas containing In element and Ga element on the Ge surface to grow the first heterogeneous layer of InGaP together with the gas containing P element;

[0084] 3) growing n-InGaAs buffer layer by MOVPE method;

[0085] 4) Prepare a bar grid structure on the surface of the n-InGaAs buffer layer by using nano soft imprinting method;

[0086] 5) The p-GaAs / n-GaAs tunnel junction, p-InGaP BSF layer, p-InGaAs base, n-InGaAs emitter and n-InGaP window are sequentially grown by MOVPE method;

[0087] 6) Prepare a grid structure on the surface of the n-InGaP window by using the nano soft imprint method;

[0088] 7) Using MOVPE method to grow p-AlGaAs / n-InGaP tunnel junction, p-AlInP BSF layer, p-InGaP base, n-InGaP emitter, n-AlInP window and GaAs layer sequentially;

[0089] 8) Prepare a composite m...

Embodiment 3

[0097] 1) Select a p-type Ge substrate, polish, clean, deposit P atoms on the Ge surface, and heat the Ge substrate to 580°C to form an n-Ge layer.

[0098] 2) Continue to introduce the gas containing In element and Ga element on the Ge surface to grow the first heterogeneous layer of InGaP together with the gas containing P element;

[0099] 3) growing n-InGaAs buffer layer by MOVPE method;

[0100] 4) Prepare a bar grid structure on the surface of the n-InGaAs buffer layer by using nano soft imprinting method;

[0101] 5) The p-GaAs / n-GaAs tunnel junction, p-InGaP BSF layer, p-InGaAs base, n-InGaAs emitter and n-InGaP window are sequentially grown by MOVPE method;

[0102] 6) Prepare a grid structure on the surface of the n-InGaP window by using the nano soft imprint method;

[0103] 7) Using MOVPE method to grow p-AlGaAs / n-InGaP tunnel junction, p-AlInP BSF layer, p-InGaP base, n-InGaP emitter, n-AlInP window and GaAs layer sequentially;

[0104] 8) Prepare a composite m...

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Abstract

The invention discloses an InGaP / InGaAs / Ge three-junction solar cell with micro-nano anti-reflection structure and a manufacturing method thereof, including InGaP / InGaAs / Ge three-junction cell and micro-nano structure on the top surface, the surface is a hexagonal periodically arranged composite micro-nano anti-reflection structure. The invention mainly utilizes nano soft imprint technology to prepare InGaP / InGaAs / Ge three-junction solar cell device with the micro-nano anti-reflection structure, including a micro-nano strip grid structure and a composite micro-nano bump (depression) structure.The structure has very low surface reflectance, by adjusting the height and filling factor of the composite micro-nano structure, when light enters the solar cell from the air, the refractive index of the medium changes slowly. The equivalent refractive index slow-changing structure slows down the violent degree of the refractive index change at the surface and the interface of the traditional solar cell, greatly reduces the reflectance, increases the optical path and improves the effective light absorption, thereby realizing the high conversion efficiency of the solar cell.

Description

technical field [0001] The invention belongs to the field of semiconductor photovoltaic devices, and relates to an InGaP / InGaAs / Ge triple-junction solar cell with a micro-nano anti-reflection structure. Using nano soft imprinting technology, InGaP / InGaAs / Ge triple-junction solar cell devices with micro-nano anti-reflection structure were prepared, including micro-nano bar grid structure and composite micro-nano protrusion (depression) structure, to achieve high surface anti-reflection characteristics , increase light absorption power, improve photocurrent and conversion efficiency. Background technique [0002] With the rapid development of the global economy, human beings are facing the current situation of resource shortage and ecological environment deterioration. Therefore, changing the existing energy structure and developing sustainable green energy have become a topic of great concern to countries all over the world. As an "inexhaustible and inexhaustible" clean ener...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/0725H01L31/074H01L31/054H01L31/18
CPCH01L31/02327H01L31/0725H01L31/074H01L31/18Y02E10/52Y02P70/50
Inventor 毕臻苏爱雪张春福陈大正张进成张金凤许晟瑞郝跃
Owner 西安纳智光研科技有限公司