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A special conductive fiber material with permanent antistatic and melt direct spinning

A conductive fiber, antistatic technology, applied in fiber processing, conductive/antistatic filament manufacturing, textile and papermaking, etc., can solve the problem of inability to directly add antistatic agent

Active Publication Date: 2021-05-18
ZHEJIANG SUHZ TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be seen that when the surface resistance is required to be low, it is impossible to directly add an antistatic agent, and an antistatic synergist must be added at the same time to solve the processing problem, and the permanent antistatic nylon elastomer material can only be added as an additive to In the fiber masterbatch, it cannot be melted and spun directly

Method used

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  • A special conductive fiber material with permanent antistatic and melt direct spinning
  • A special conductive fiber material with permanent antistatic and melt direct spinning

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] Preparation of conductive fiber special material:

[0071] 100g of nylon 6 / 66 prepolymer with a molecular weight of 1500-2500,

[0072] Dibasic acid-terminated polyether polyol 85g,

[0073] Ethoxylauramide 2g,

[0074] Sodium dodecylbenzenesulfonate 2.6g,

[0075] Lithium bisoxalate borate 0.5g,

[0076] 15g of deionized water.

[0077] Put the above materials into the reaction kettle and react for 20 hours at 270°C with a stirring speed of 50 rpm to prepare the special material for cable sheathing.

[0078] Among them, the preparation method of lithium bisoxalate borate is as follows: using water as the medium, mixing lithium hydroxide with oxalic acid and boric acid, reacting at 60°C, evaporating and crystallizing.

[0079] The multi-component nylon prepolymer comprises the following raw materials by mass percentage:

[0080] Nylon 66 salt 10%, nylon 610 salt 20%,

[0081] Dodecanoic Acid 15%,

[0082] Dodecyl diamine 15%,

[0083] Antioxidant 0.2%,

[0084...

Embodiment 2

[0094] Preparation of conductive fiber special material:

[0095] 100g of nylon 6 / 66 prepolymer with a molecular weight of 1500-2500,

[0096] Dibasic acid-terminated polyester polyol 85g,

[0097] Ethoxylauramide 2g,

[0098] Sodium octadecylbenzenesulfonate 2.6g,

[0099] Lithium bisoxalate borate 0.5g,

[0100] 15g of deionized water.

[0101] Among them, the preparation method of lithium bisoxalate borate is: using water as the medium, mixing lithium hydroxide with oxalic acid and boric acid, reacting at 40°C, evaporating and crystallizing.

[0102] Multi-component nylon prepolymer includes the following raw materials by mass percentage:

[0103] Nylon 66 salt 10%, Nylon 610 salt 25%,

[0104] p-toluic acid 20%,

[0105] p-Phenylenediamine 20%,

[0106] Antioxidant 0.5%,

[0107] Orthophosphate 0.05%,

[0108] water balance.

[0109] The preparation method of multi-component nylon prepolymer is as follows: add the raw materials into the reaction kettle according...

Embodiment 3

[0117] Preparation of conductive fiber special material:

[0118] 110g of nylon 6 / 66 prepolymer with a molecular weight of 1500-2500,

[0119] Dibasic acid-terminated polyether polyol 80g,

[0120] Ethoxylauramide 2g,

[0121] Sodium octadecylbenzenesulfonate 2.6g,

[0122] Lithium bisoxalate borate 0.5g,

[0123] 15g of deionized water.

[0124] Among them, the preparation method of lithium bisoxalate borate is as follows: using water as the medium, mixing lithium hydroxide with oxalic acid and boric acid, reacting at 80°C, evaporating and crystallizing.

[0125] The multi-component nylon prepolymer comprises the following raw materials by mass percentage:

[0126] Nylon 66 salt 20%, Nylon 610 salt 10%,

[0127] Adipic acid 5%, suberic acid 5%,

[0128] Hexamethylenediamine 5%, octanediamine 5%,

[0129] Antioxidant 0.1%,

[0130] Orthophosphate 0.02%,

[0131] water balance.

[0132] The preparation method of the multi-component nylon prepolymer is as follows: add...

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PUM

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Abstract

The invention relates to the field of macromolecular materials, and discloses a special conductive fiber material with permanent antistatic properties and melt direct spinning, including: 50-75% of multi-component nylon prepolymer with a molecular weight of 1500-2500, dibasic acid-terminated Polyester polyol or dibasic acid-terminated polyether polyol 35‑50%, the molecular weight of the polyester polyol and polyether polyol is 200‑3000, ethoxylated lauramide 1‑5%, ionic surface Active agent 1‑3%, lithium bisoxalate borate, 0.3‑0.5%, water 3‑5%. The material of the invention is polyester, polyether, amide block polymer, which can be directly melted and spun into conductive fibers, and can also be added to nylon or PET co-spinning as antistatic masterbatch to prepare antistatic fibers. It is characterized by permanent antistatic ability and no need to add antistatic synergist.

Description

technical field [0001] The invention relates to the field of macromolecule materials, in particular to a special conductive fiber material with permanent antistatic properties and capable of melt direct spinning. Background technique [0002] At present, most of the antistatic fibers are made of nylon or PET, which are modified by adding an antistatic agent and then spun. [0003] The patent application number CN03141992.5 discloses an antistatic polypropylene fiber, which is composed of a composite antistatic agent and polypropylene, and its components and weight percentages are: composite antistatic agent 0.2-0.8%, polypropylene 99.2-99.8% . The compound antistatic agent is composed of antistatic agent A, antistatic agent B and antistatic agent C. [0004] The patent with application number CN201610418708.8 discloses a flame-retardant antistatic polyester fiber, including: a polyester fiber body, and a flame retardant and an antistatic agent added to the polyester fiber ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F1/09D01F8/12D01F8/14D01F8/16D01D5/34
CPCD01D5/34D01F1/09D01F8/12D01F8/14D01F8/16
Inventor 吴中心
Owner ZHEJIANG SUHZ TECH CO LTD
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