Remediation agent for heavy metal contaminated soil as well as preparation method and using method of remediation agent

A technology for polluted soil and remediation agent, applied in the field of contaminated soil remediation, can solve the problems of single type of remediation agent, difficult expansion and optimization of remediation time dimension, single remediation mechanism, etc. The effect of stable repair ability and simple preparation method

Active Publication Date: 2018-12-21
北京润鸣环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. The restorative material itself has the problem of secondary pollution by heavy metals;
[0007] 2. The component type of the restoration agent is too single, or chemical reagents, or environmentally friendly ingredients;
[0008] 3. The synergistic repair effect between repair agent components needs to be improved;
[0009] 4. There are obvious differences in the application effect of restoration agent materials to contaminated soil from different sources;
[0010] 5. The repair mechanism is single, and the applicable environmental conditions are harsh;
[0011] 6. The repair efficiency is not enough to meet the treatment needs of higher pollution concentrations;
[0012] 7. It is difficult to further expand and optimize the repair time dimension

Method used

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  • Remediation agent for heavy metal contaminated soil as well as preparation method and using method of remediation agent
  • Remediation agent for heavy metal contaminated soil as well as preparation method and using method of remediation agent
  • Remediation agent for heavy metal contaminated soil as well as preparation method and using method of remediation agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] This embodiment provides a heavy metal soil remediation agent and a preparation method thereof. The soil remediation agent mainly includes the following components in parts by weight: 45 parts of organically modified montmorillonite, 15 parts of wheat bran, and 20 parts of ferric chloride 10 parts of acid-modified biochar and 10 parts of calcium oxide; wherein, the montmorillonite is calcium-based montmorillonite with a mesh size of 200 mesh; the biochar is corn stalk charcoal.

[0056] The preparation method is as follows: mixing organically modified montmorillonite, wheat bran, ferric chloride, acid-modified biochar and calcium oxide in a prescribed amount, grinding, and passing through a 2mm sieve to obtain a specific heavy metal soil repair agent.

[0057] The heavy metal polluted soil remediation agent prepared in Example 1 was used to remediate arsenic, mercury, zinc and lead compound polluted soil in an industrial site in Guangzhou. Take a 50g soil sample, add 2....

Embodiment 2

[0060] This embodiment provides a heavy metal soil remediation agent and a preparation method thereof. The soil remediation agent mainly includes the following components in parts by weight: 45 parts of organically modified montmorillonite, 10 parts of heat-activated modified cow dung, chlorine 10 parts of iron oxide, 25 parts of activated sepiolite and 10 parts of magnesium oxide; wherein, the montmorillonite is calcium-based montmorillonite with a mesh size of 200 mesh.

[0061] The preparation method is as follows: mix organically modified montmorillonite, heat-activated modified cow dung, ferric chloride, activated sepiolite and magnesium oxide in a formula amount, grind, and pass through a 2mm sieve to obtain a specific heavy metal soil repair agent .

[0062] The heavy metal contaminated soil remediation agent prepared in Example 2 was used to remediate arsenic, zinc, lead and copper composite contaminated soil in an industrial site in Guangzhou. Take a 50g soil sample,...

Embodiment 3

[0065] This embodiment provides a heavy metal soil remediation agent and a preparation method thereof. The soil remediation agent mainly includes the following components in parts by weight: 40 parts of synthetic hydrotalcite, 15 parts of heat-activated modified cow dung, calcium hypochlorite 25 parts, 15 parts of acid-modified biochar and 5 parts of iron sulfate; wherein, the biochar is corn stalk charcoal.

[0066] The preparation method is as follows: mixing synthetic hydrotalcite, heat-activated modified cow dung, calcium hypochlorite, acid-modified biochar and ferric sulfate, grinding, and passing through a 2mm sieve to obtain a specific heavy metal soil restoration agent .

[0067] The heavy metal contaminated soil remediation agent prepared in Example 3 was used to remediate cadmium and arsenic compound contaminated soil in an industrial site in Shandong. Take a 50g soil sample, add 3.0% mass ratio of heavy metal contaminated soil remediation agent, adjust the moisture...

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Abstract

The invention provides a remediation agent for heavy metal contaminated soil as well as a preparation method and a using method of the remediation agent. The remediation agent is prepared from the following components in parts by weight: 20-80 parts of a mineral material, 10-70 parts of a biomass material, 5-40 parts of a redox agent, 5-50 parts of an adsorbent and 0-30 parts of a pH regulator. The preparation method comprises the following steps: mixing the five components according to a formula ratio, grinding, and screening to obtain the remediation agent for the heavy metal contaminated soil. The using method comprises the following steps: mixing the remediation agent for heavy metal contaminated soil with compound contaminated soil, adjusting the water content of the compound contaminated soil, and carrying out soil conservation and remediation. The remediation agent for the heavy metal contaminated soil can reduce the migration and bioavailability of the soil by reducing the heavy metal leaching concentration of the soil, thereby realizing the stabilization of the soil for the various heavy metals; the remediation agent for the heavy metal contaminated soil has the advantagesof being low in cost, short in repair period, good in repair effect, wide in application range and free from secondary pollution, and the like.

Description

technical field [0001] The invention belongs to the technical field of contaminated soil remediation, and relates to a heavy metal contaminated soil remediation agent and a preparation method and an application method thereof. Background technique [0002] The heavy metal stabilization technology is well used in the field of soil remediation, and the soil remediation agents involved are in various forms, but the mechanism of action is similar. The characteristics of contaminated soil determine the selection of remediation agents to a certain extent. However, at present, there is no fixed remediation plan in the pharmaceutical industry for remediation of heavy metal-contaminated soil. "Adjusting measures to local conditions" and "prescribing the right medicine" have become important principles in the field of soil remediation. [0003] The development of soil remediation agents started earlier in foreign countries, and today, the research and development of related materials...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40B09C1/08C09K109/00
CPCB09C1/08C09K17/40C09K2109/00
Inventor 毕学张琢王志新
Owner 北京润鸣环境科技有限公司
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