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A heavy metal contaminated soil remediation agent and its preparation method and use method

A technology of contaminated soil and remediation agent, which is applied in the field of contaminated soil remediation, can solve the problems of single type of remediation agent, difficult expansion and optimization of repair time dimension, single repair mechanism, etc., to achieve structural stability and acid-base balance, long-term sustainable The effect of stable repair ability and simple preparation method

Active Publication Date: 2021-06-18
北京润鸣环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. The restorative material itself has the problem of secondary pollution by heavy metals;
[0007] 2. The component type of the restoration agent is too single, or chemical reagents, or environmentally friendly ingredients;
[0008] 3. The synergistic repair effect between repair agent components needs to be improved;
[0009] 4. There are obvious differences in the application effect of restoration agent materials to contaminated soil from different sources;
[0010] 5. The repair mechanism is single, and the applicable environmental conditions are harsh;
[0011] 6. The repair efficiency is not enough to meet the treatment needs of higher pollution concentrations;
[0012] 7. It is difficult to further expand and optimize the repair time dimension

Method used

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  • A heavy metal contaminated soil remediation agent and its preparation method and use method
  • A heavy metal contaminated soil remediation agent and its preparation method and use method
  • A heavy metal contaminated soil remediation agent and its preparation method and use method

Examples

Experimental program
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Effect test

Embodiment 1

[0055] This embodiment provides a heavy metal soil repair agent and a preparation method thereof, and the soil repair agent mainly includes the following components: 45 parts of organic modified montmorillonmine, 15 wheat bran, 20 copies of ferric chloride , 10 parts of acid-modified biocompatient and 10 copies of calcium oxide; wherein the montmorillonite is calcium-homing, and the number of mesh is 200 mesh; bioaccha is corn straw charcoal.

[0056] The preparation method is: the formulation amount of organically modified montmorillonite, wheat bran, ferric chloride, acid modified bio-carbon and calcium oxide mix, ground, over 2mm sieve, to obtain a specific heavy metal soil repair agent.

[0057] The heavy metal contaminated soil repair agents made in Example 1 were used to repair arsenic, mercury, zinc and lead composite contaminated soil in a industrial site in Guangzhou. Take 50 g of the soil sample, add 2.0% mass than heavy metal contamination soil repair agent, adjust the ...

Embodiment 2

[0060] This embodiment provides a heavy metal soil repair agent and a preparation method thereof, which mainly comprises 45 parts of the organic modified montmorillonite, 10 parts of thermally activated modified cow dung, chlorine 10 copies of iron, 25 parts of seafubbles and 10 magnesium oxide; wherein the Monte soil is calcium-sized, and the number of mesh is 200 mesh.

[0061] The preparation method is: the formulation of organic modified montmorillonite, thermally activated cattle, ferrous chloride, activated seafubi and magnesium oxide, ground, over 2mm sieve, to obtain a specific heavy metal soil repair agent .

[0062] The heavy metal contaminated soil repair agents produced in Example 2 were used to repair arsenic, zinc, lead and copper composite contaminated soil in a certain industrial site in Guangzhou. Take 50g soil sample, add 2.5% mass than heavy metal contamination soil repair agents to adjust the water content to 20% ~ 35%, mix, 7 days; for repair soil, "solid wast...

Embodiment 3

[0065] This embodiment provides a heavy metal soil repair agent and a preparation method thereof, which mainly comprises 40 parts by weight of the synthesis of water talc, 15 parts of heat activated cow dung, calcium hypochlorite 25 copies of acid-modified biocompans and 5 sulfate; wherein bioaccha is corn straw charcoal.

[0066] The preparation method is: mixing the formulation of synthetic water talc, thermally activated cow dung, hypochlorite, acid-modified bio and iron sulfate, ground, over 2mm sieve to obtain a specific heavy metal soil repair agent .

[0067] The heavy metal contaminated soil repair agents made in Example 3 were used to repair cadmium and arsenic composite contaminated soil in a industrial site in Shandong. Take 50 g soil, add 3.0% mass than heavy metal pollution soil repair agents, regulate water content to 20% ~ 35%, mix, 7 days; for repair soil, "solid waste leaching toxic leaching method horizontal oscillation method "(Hj557-2007) leaching.

[0068] The...

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Abstract

The invention provides a heavy metal polluted soil remediation agent, a preparation method and an application method thereof. The restoration agent includes the following components in parts by weight: 20-80 parts of mineral materials, 10-70 parts of biomass materials, 5-40 parts of redox agents, 5-50 parts of adsorbents, and pH regulators 0 to 30 copies. The preparation method comprises: mixing the above-mentioned five components in the formulated amount, grinding and sieving to obtain the heavy metal polluted soil remediation agent. The use method includes: mixing the heavy metal polluted soil remediation agent with compound polluted soil, adjusting the water content of the compound polluted soil, and performing soil maintenance and restoration. The heavy metal-contaminated soil remediation agent reduces the leaching concentration of heavy metals in the soil, thereby reducing their mobility and bioavailability, and realizes the stabilization of various heavy metals. It has the advantages of low cost, short remediation period, good remediation effect, wide application range and unique Secondary pollution and other advantages.

Description

Technical field [0001] The present invention belongs to the field of contaminated soil repair technology, and it is related to a heavy metal contamination soil repair agent and a preparation method and method of use. Background technique [0002] Heavy metal stabilization techniques are used in the field of soil restoration, and the soil repair agents involved are diverse, but the mechanism of action is similar. Pollution soil characteristics determine the choice of repairing agents to a certain extent. However, the current heavy metal pollution soil repair pharmaceutical industry has no fixed repair plan, "the local system", "the disease" has become an important principle of conventional in the field of soil restoration. [0003] The development of soil repair pharmacy has been early in foreign countries. At the time, the research of related materials R & D and supporting facilities has been perfect; in the country, it is still in its infancy, most of the pollution venue is stil...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K17/40B09C1/08C09K109/00
CPCB09C1/08C09K17/40C09K2109/00
Inventor 毕学张琢王志新
Owner 北京润鸣环境科技有限公司
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