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Copper and titanium enhanced anti-corrosion austenitic stainless steel and preparation method thereof

A technology of austenitic stainless steel and stainless steel, applied in the field of austenitic stainless steel, can solve problems such as damage to components or equipment, and affect the safe operation of nuclear power plants, and achieve the effects of reduced corrosion rate, excellent corrosion resistance, high hardness and strength

Inactive Publication Date: 2019-03-22
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When corrosion reaches a certain level, it will cause damage to components or equipment, and in severe cases, it will affect the safe operation of the entire nuclear power plant.

Method used

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  • Copper and titanium enhanced anti-corrosion austenitic stainless steel and preparation method thereof
  • Copper and titanium enhanced anti-corrosion austenitic stainless steel and preparation method thereof
  • Copper and titanium enhanced anti-corrosion austenitic stainless steel and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, 316 stainless steel scrap, pure copper plate, and metal titanium as raw materials. The stainless steel composition is as follows: C=0.03, Ni=12, Cr=16.0, Mo=2.4, Ti=0.12, Cu=0.2, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=balance. After weighing the corresponding raw materials according to the composition requirements, argon shielded arc melting, the temperature of the molten pool is kept at 1720°C during melting; the molten steel is calmed for 10 minutes before pouring, and the molten steel is poured under argon shielding at 1650°C. Cast into round ingots.

[0052] The ingot can be opened by hot forging, and the billet after hot forging is then cross-rolled and pierced to obtain a pipe billet; hot forging and cross-rolled piercing are heated to 1260 ° C, kept for 5 hours and then released for forging, the initial forging temperature is 1170 ° C, and the final forging temperature is 1170 ...

Embodiment 2

[0057] 316L stainless steel waste, metal molybdenum, pure copper plate, and ferro-titanium are selected as raw materials, and the stainless steel components configured are as follows: C=0.015, Ni=12.0, Cr=18.0, Mo=3.0, Ti=0.16, Cu=0.3, Mn=1.2, Si=0.7, P≤0.035, S≤0.030, Fe=balance.

[0058] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is maintained at 1680°C during melting; the molten steel is calmed for 5 minutes before pouring, and the molten steel is vacuum poured at 1550°C. Cast into square ingots.

[0059] The billet is heated to 1270°C, and after 3 hours of heat preservation, the billet is opened by pass rolling. The initial rolling temperature is 1160°C, the final rolling temperature is 980°C, and the total area reduction rate of rolling is 62%. Bars were obtained, and the total rolling deformation was calculated as 82% according to the reduction ...

Embodiment 3

[0062] Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, pure copper plate, titanium iron, graphite block as raw materials, and configure the stainless steel composition as follows: C=0.025, Ni=15.0, Cr=18.0, Mo=2.5, Ti =0.34, Cu=0.4, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=balance.

[0063] After weighing the corresponding raw materials according to the composition requirements, they are induction smelted under the protection of argon, and the temperature of the molten pool is kept at 1700°C during smelting. Cast into round ingots.

[0064] The cast ingot can be rolled by a universal rolling mill with two pairs of parallel rolls. The cast billet is heated to 1280°C, held for 4 hours and rolled out of the furnace. The rate is calculated as 65%;

[0065] The T-shaped profile is prepared by universal rolling, and the total rolling deformation is calculated as 85% according to the reduction of area;

[0066] After cold rolling, annealing is ...

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Abstract

The invention discloses copper and titanium enhanced anti-corrosion austenitic stainless steel and a preparation method thereof. Alloy elements include 0.03 or less of C, 12.0-15.0 of Ni, 16.0-18.0 ofCr, 2.0-3.0 of Mo, 0.42 or less of Ti, 0.2-0.8 of Cu, 2.0 or less of Mn, 1.0 or less of Si, 0.035 or less of P, 0.030 or less of S and the balance Fe, wherein 3.98 x C<=Ti<=3.98 x C + 0.3. After an alloy is smelted, through thermal deformation cogging and cold deformation, TiC is sufficiently broken and dispersed and distributed, and through high-temperature solution treatment, thick and large austenite grains are obtained. Under the hydrogen feeding condition, the alloy corrosion current in a 0.5 mol / L H2SO4 electrolyte containing 5 x 10<-6>F<-> at the temperature of 80 DEG C is 5.9 mu A / cm<2>-7.9 mu A / cm<2>, compared with stainless steel 316L, the corrosion rate is greatly reduced, and the mechanical performance is slightly superior to that of the stainless steel 316L.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to composition design, processing and heat treatment method of high corrosion resistance austenitic stainless steel, and can be widely used in energy, electric power, chemical industry and daily life. technical background [0002] Due to its excellent mechanical and corrosion resistance, stainless steel is widely used in energy, electric power, chemical and other fields. Austenitic stainless steel is widely used in the nuclear power industry because of its good mechanical properties, machinability, corrosion resistance and neutron radiation resistance. 304L and 316LN austenitic stainless steel are used as structural materials for the main pipeline of the PWR primary circuit, reactor internals, drive mechanism, main pump and pump shaft and other key equipment. These materials have served in harsh water chemical environments such as high temperature, high pressure and radiation fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21D1/18C21D1/26C21D1/74C21D1/773C21D8/02C21D8/06C21D8/10C22C33/06C22C38/02C22C38/04C22C38/42C22C38/44C22C38/50C22C38/58
CPCC21D1/18C21D1/26C21D1/74C21D1/773C21D8/0226C21D8/0236C21D8/065C21D8/105C21D2211/001C22C33/06C22C38/002C22C38/02C22C38/04C22C38/42C22C38/44C22C38/50C22C38/58Y02P10/20
Inventor 罗丰华杜帅刘笑高翔向剑波李国平
Owner CENT SOUTH UNIV