Difficult-flammble polycarbonate composition and preparation method thereof

A polycarbonate and polycarbonate resin technology, applied in the field of engineering plastics, can solve the problems affecting the toughness and heat resistance of PC resins, the limitation of the use of aromatic phosphate ester flame retardants, and the decline of the mechanical properties of resins, so as to improve the toughness. The effect of retention, flame retardant performance improvement, and impact reduction

Inactive Publication Date: 2019-03-29
TIANJIN KINGFA NEW MATERIAL
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

The mechanical properties of the hydrolyzed resin decrease, which seriously affects its use in some specific fields
[0003] In addition, in the application fields that require flame retardancy, the commonly used phosphate ester flame retardant for PC has the advantages of environmental protection, flame retardancy and high efficiency, but its addition usually produces plasticizing effect on PC, which affects the toughness and heat resistance of PC resin.
In addition, in high-temperature and high-humidity environments, the use of phosphate ester flame retardants is more likely to cause PC degradation. Therefore, the use of aromatic phosphate ester flame retardants in high-temperature and high-humidity environments is limited.

Method used

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  • Difficult-flammble polycarbonate composition and preparation method thereof
  • Difficult-flammble polycarbonate composition and preparation method thereof
  • Difficult-flammble polycarbonate composition and preparation method thereof

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Embodiment Construction

[0027] Unless otherwise defined, the technical terms used in the following embodiments have the same meaning as commonly understood by those skilled in the art to which the present invention belongs. The test reagents used in the following examples, unless otherwise specified, are conventional biochemical reagents; the experimental methods, unless otherwise specified, are conventional methods.

[0028] The present invention will be described in detail below in conjunction with examples.

[0029] In embodiment 1-3 of the present invention and comparative example 1-5: polycarbonate resin (PC resin) selects the PC S-3000F (Mitsubishi of Japan) that viscosity-average molecular weight is 22000 for use; Toughener selects the SX- 005, the other toughening agent is S-2001 from Mitsubishi Rayon; the flame retardant is EF-42 (Mitsubishi), and the other flame retardant is PhireGuard BDP (Jiangsu Yake); the anti-hydrolysis agent is Stabaxol P (Rheinland Chemical ). The lubricant in othe...

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Abstract

The invention provides a difficult-flammble polycarbonate composition and a preparation method thereof. The difficult-flammble polycarbonate composition comprises the following components in parts byweight: 96.0-99.8 parts of polycarbonate resin, 0.1-3.0 parts of a toughening agent, 0. 01-6.0 parts of a flame retardant, 0.1-5.0 parts of an anti-hydrolysis agent, 0.01-2.0 parts of an antioxidant,and 0.01-1.2 parts of other additives; wherein the anti-hydrolysis agent is one of carbodiimide, isocyanate, oxazoline, and an epoxy compound. The difficult-flammble polycarbonate composition has goodflame retardation performance, toughness and anti-hydrolysis performance, the heat resistance temperature is higher than 120 DEG C, and the difficult-flammble polycarbonate composition is especiallysuitable for occasion with high usage environment requirements.

Description

technical field [0001] The invention belongs to the technical field of engineering plastics, and in particular relates to a flame-retardant polycarbonate composition and a preparation method thereof. Background technique [0002] Polycarbonate resin is a kind of general-purpose engineering plastic, which has the advantages of transparency, impact resistance, heat resistance, dimensional stability, etc., and because of its excellent characteristics mentioned above, it is widely used in industry as automotive, Materials in the field of office equipment such as printers, and in the electrical and electronic fields such as mobile phones. The polycarbonate commonly used in the market is prepared by the interfacial polycondensation method, which contains a large number of ester groups. When the temperature is high or the relative humidity is high, water easily reacts with polycarbonate and degrades with the help of heat and oxygen, and the hydrogen free radicals generated by the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L79/00C08K5/134C08K5/526
CPCC08L69/00C08L2201/02C08L79/00C08K5/1345C08K5/526
Inventor 艾军伟陈勇文董相茂王中林佟伟岑茵李明昆张现军丁超陶四平
Owner TIANJIN KINGFA NEW MATERIAL
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