High-speed hot-stamping gloss oil type tipping paper electrochemical aluminum foil hot melt adhesive and preparation method thereof

A technology of electrochemical aluminum foil and tipping paper, applied in the directions of adhesives, adhesive types, polymer adhesive additives, etc., can solve the problems of inability to wet the substrate, the hot stamping layer is difficult to adhere, and the bonding cannot be achieved. To achieve the effect of stable and controllable quality, lower surface energy and stable performance

Active Publication Date: 2019-04-09
云南玉溪东魅包装材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The hot-melt adhesive layer in the prior art is incompatible with waxy materials with low surface energy, and the surface energy under melting conditions is higher than that of varnish-type tipping paper, which cannot wet the substrate and fail to achieve the purpose of bonding, resulting in scalding The printing layer is difficult to attach or the adhesion is not strong, and it is easy to cause powder removal and other phenomena

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A high-speed hot stamping varnish type electrochemical aluminum foil hot melt adhesive for tipping paper, the specific formula is calculated by weight: 8 parts of vinyl chloride-vinyl acetate-maleic anhydride terpolymer, 3 parts of aldehyde and ketone resin, butyl acetate 2 parts of acid cellulose, 4 parts of rosin pentaerythritol ester, 0.2 parts of polyether modified polydimethylsiloxane, 2 parts of fumed silica, 75.8 parts of ethyl acetate, 5 parts of n-propyl acetate.

[0026] Follow the steps below for production:

[0027] a. Add ethyl acetate and n-propyl acetate weighed according to the proportion to the container and stir at room temperature for 3 to 5 minutes at a stirring speed of 60-100r / min to obtain mixed solution A;

[0028] b. Under the condition of stirring at a low speed of 60-100r / min, add vinyl chloride-vinyl acetate-maleic anhydride terpolymer, aldehyde and ketone resin, cellulose acetate butyrate, Rosin pentaerythritol ester, after feeding, clean u...

Embodiment 2

[0033] A high-speed hot stamping varnish type electrochemical aluminum foil hot melt adhesive for tipping paper, the specific formula is calculated by weight: 9 parts of vinyl chloride-vinyl acetate-maleic anhydride terpolymer, 4 parts of aldehyde and ketone resin, butyl acetate 3 parts of acid cellulose, 3 parts of rosin pentaerythritol ester, 0.3 parts of polyether modified polydimethylsiloxane, 2.5 parts of fumed silica, 74.2 parts of ethyl acetate, 4 parts of n-propyl acetate.

[0034] Follow the steps below for production:

[0035] a. Add ethyl acetate and n-propyl acetate weighed according to the proportion into the container at room temperature and stir for 3 to 5 minutes at a stirring speed of 60-100r / min to obtain a mixed solution A;

[0036] b. Under the condition of stirring at a low speed of 60-100r / min, add vinyl chloride-vinyl acetate-maleic anhydride terpolymer, aldehyde and ketone resin, cellulose acetate butyrate, Rosin pentaerythritol ester, after feeding, c...

Embodiment 3

[0041] A high-speed hot stamping varnish type electrochemical aluminum foil hot melt adhesive for tipping paper, the specific formula is calculated by weight parts: 10 parts of vinyl chloride-vinyl acetate-maleic anhydride terpolymer, 2 parts of aldehyde and ketone resin, butyl acetate 4 parts of acid cellulose, 5 parts of rosin pentaerythritol ester, 0.5 parts of polyether modified polydimethylsiloxane, 3 parts of fumed silica, 70.5 parts of ethyl acetate, 5 parts of n-propyl acetate.

[0042] Follow the steps below for production:

[0043] a. Add ethyl acetate and n-propyl acetate weighed according to the proportion into the container at room temperature and stir for 3 to 5 minutes at a stirring speed of 60-100r / min to obtain a mixed solution A;

[0044] b. Under the condition of stirring at a low speed of 60-100r / min, add vinyl chloride-vinyl acetate-maleic anhydride terpolymer, aldehyde and ketone resin, cellulose acetate butyrate, Rosin pentaerythritol ester, after feedi...

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PUM

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Abstract

The invention provides a high-speed hot-stamping gloss oil type tipping paper electrochemical aluminum foil hot melt adhesive and a preparation method thereof, and aims to solve the phenomena that anexisting hot melt adhesive is not compatible with a wax material with low surface energy and easily shelled. The hot melt adhesive is prepared from the following raw materials in parts by weight: 5-10parts of vinyl chloride-vinyl acetate-maleic anhydride terpolymer, 1-5 parts of aldehyde ketone resin, 1-5 parts of cellulose acetate butyrate, 1-5 parts of rosin modified resin, 0.1-0.5 part of a wetting agent, 1-5 parts of fumed silica, 50-80 parts of ethyl acetate and 1-5 parts of n-propyl acetate. According to the hot melt adhesive, the surface energy of hot melt adhesive can be greatly reduced under a melting condition, and the wetting and penetrating performance of hot melt adhesive on the low-surface-energy tipping paper base material can be effectively improved; resin is reasonably matched in the formula for mixing and modifying preparation, and initial adhesion and persistent adhesion of the hot melt adhesive can be taken into consideration, and the aim of firm adhesion and high-speed hot stamping can be achieved.

Description

technical field [0001] The invention relates to the field of hot-melt adhesives, in particular to a hot-melt adhesive for high-speed stamping varnish type tipping paper anodized aluminum foil and a preparation method thereof. Background technique [0002] Anodized aluminum hot stamping foil is a hot stamping material, mainly composed of base film layer, release layer, coloring layer, vacuum aluminized layer and hot melt adhesive layer. Among them, the base film layer is the carrier and support of other layers; the release layer is to provide the transferability of the base film layer and other layers; the coloring layer is a protective layer for displaying color and vacuum aluminized layer; It is to provide adhesion with the substrate, and different hot-melt adhesive layers can be used to achieve hot stamping of different substrates. Anodized aluminum hot stamping foil is transferred to the surface of the substrate by the principle of hot pressing, which has the functions o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J127/06C09J161/02C09J101/14C09J11/04C09J11/08
CPCC08L2205/035C09J11/04C09J11/08C09J127/06C08L61/02C08L1/14C08L93/04C08L83/12C08K3/36
Inventor 何宗修龚麟杨正德
Owner 云南玉溪东魅包装材料有限公司
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