Imide organic silica gel and preparation method thereof

A technology of organic silica gel and imide, applied in the field of imide organic silica gel and its preparation, can solve the problems of high price, unfavorable large-scale popularization and application, high cost of polyetherimide resin, and achieve convenient operation and good market. Application prospect and effect of industrialized production

Active Publication Date: 2019-05-10
福建省海钛智能科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0017] (2) 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane (BAHPFP) and other monomers are expensive, resulting in high cost of polyetherimide resin (HPEI) and adhesives, which is not conducive to Large-scale promotion and application can only be limited to some special fields

Method used

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  • Imide organic silica gel and preparation method thereof
  • Imide organic silica gel and preparation method thereof
  • Imide organic silica gel and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Put 32.2 grams (0.1 mole) of 1,4-bis(2,4-diaminophenoxy)benzene (14BDAPB), 500 grams of methyl tetrahydrofuran and 900 grams of N,N dimethylformamide into the reaction kettle , after stirring and dissolving at room temperature, add 19.6 grams (0.2 moles) of maleic anhydride, stir and dissolve at room temperature and react for 15 minutes, then add 10.62 grams (0.01 moles) of double-ended aminopropyl polydimethylsiloxane (YASI, The average value of m is 12), after stirring and dissolving completely, add 20.0 grams (0.1 moles) of 3,4'-diaminodiphenyl ether, 73.2 grams (0.2 moles) of 2,2-bis(3-amino-4-hydroxybenzene base) hexafluoropropane and 80.0 grams (0.2 moles) of 4,4'-bis(4-aminophenoxy) diphenyl sulfide, after stirring and dissolving, add 209.3 grams (0.65 moles) of 3,3',4,4 '-Tetracarboxybenzophenone dianhydride was stirred and dissolved at room temperature. After stirring for 1.0 hour, 22.1 grams (0.1 mole) of 3-aminopropyltriethoxysilane was added, and stirred for...

Embodiment 2

[0041] 32.2 grams (0.1 moles) of 1,4-bis(2,4-diaminophenoxy)benzene (14BDAPB), 1000 grams of tetrahydrofuran, 1000 grams of N,N dimethylacetamide and 1000 grams of N-ethyl -2-Pyrrolidone was put into the reaction kettle, stirred and dissolved at room temperature, 19.6 grams (0.2 moles) of maleic anhydride was added, stirred and dissolved at room temperature, reacted for 30 minutes, and then added 15.32 grams (0.02 moles) of double-ended aminopropyl polymer Dimethylsiloxane (YASI, the average value of m is 8), after stirring and dissolving completely, add 22.4 grams (0.1 moles) of 2-(4-aminophenyl)-5-aminobenzimidazole, 58.0 grams (0.2 moles ) 4,4'-diamino-4"-hydroxytriphenylmethane, 80.0 grams (0.4 moles) of 3,4'-diaminodiphenyl ether and 120.0 grams (0.3 moles) of 4,4'-bis(4-amino Phenoxy) diphenyl sulfide, after stirring and dissolving, add 186.0 grams (0.6 moles) of 3,3',4,4'-tetracarboxy diphenyl ether dianhydride and 193.2 grams (0.6 moles) of 3,3',4 , 4'-tetracarboxyben...

Embodiment 3

[0043] 32.2 grams (0.1 moles) of 1,4-bis(2,4-diaminophenoxy)benzene (14BDAPB), 1000 grams of tetrahydrofuran, 3000 grams of N,N dimethylformamide and 1700 grams of N-ethyl -Put the organic solvent of 2-pyrrolidone into the reaction kettle, stir and dissolve at room temperature, add 19.6 grams (0.2 moles) of maleic anhydride, stir and dissolve at room temperature, and react for 20 minutes, then add 16.1 grams (0.05 moles) of double-ended aminopropyl Based polydimethylsiloxane (YASI, the average value of m is 2), after stirring and dissolving completely, add 20.0 g (0.1 mole) of 3,4'-diaminodiphenyl ether, 160.0 g (0.4 mole) of 4, 4'-bis(4-aminophenoxy) diphenyl sulfide and 43.2 grams (0.2 moles) of 3,3'-diamino-4,4'-dihydroxybiphenyl, after stirring and dissolving, add 225.4 grams (0.7 mol) 3,3',4,4'-tetracarboxybenzophenone dianhydride, 78.0 g (0.15 mol) 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane Dianhydride, stirring and dissolving at room temperature, after stirring for...

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Abstract

The invention relates to imide organic silica gel and a preparation method thereof. The imide organic silica gel is composed of a reaction product of 1, 4-di(2, 4-aminophenoxy)benzene 14BDAPB, double-terminated aminopropyl polydimethylsiloxane YASI, maleic anhydride, aromatic diamine, aromatic binary anhydride and 3-aminopropyl trialkoxysilane and an organic solvent. Raw material source is convenient, process is simple, operation is convenient, and the imide organic silica gel is good in comprehensive performance, can be applied in bonding of glass, ceramic, composite materials, special-polarity textile prepreg and composite material base materials thereof and has good market application prospect.

Description

technical field [0001] The invention belongs to the field of adhesives, in particular to an imide organic silica gel and a preparation method thereof. Background technique [0002] Adhesive systems are widely used in various fields of the national economy: whether it is high-tech or general-purpose technology, whether it is national defense or civilian industry, or even people's daily life. [0003] There have been many research reports on adhesive systems or silicone resin systems, and there are also many invention patents: [0004] Chinese invention patent CN102786902A discloses a silicone organic fluorine epoxy adhesive and a preparation method thereof. [0005] Yan Rui, Yu Xinhai et al [Research on Preparation and Properties of New Epoxy Adhesives, Insulating Materials, 2012, 45(2): 12-14,18] disclosed a new type of epoxy resin adhesive and its preparation method, and its performance has been systematically studied. [0006] Chinese invention patent CN106220851A discl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J179/08C08G73/12
Inventor 虞鑫海黄朝希
Owner 福建省海钛智能科技有限公司
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