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Color-changing ink and preparation method and application thereof

A color-changing ink, space technology, applied in the field of ink, can solve the problems of low-cost batch printing and high cost, and achieve the effect of low cost and low price

Active Publication Date: 2019-05-24
SHENZHEN NINE STARS PRINTING & PACKAGING GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The ink has some disadvantages. First, the use of precious metals as raw materials is expensive; second, in order for the reaction to continue, the material must remain in a gel state, which cannot be mass-printed at low cost by a printing machine

Method used

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  • Color-changing ink and preparation method and application thereof
  • Color-changing ink and preparation method and application thereof

Examples

Experimental program
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preparation example Construction

[0036] Such as figure 1 Shown, the preparation method of the color-changing ink of an embodiment, comprises the following steps:

[0037] The color-changing ink is obtained by dissolving 20-50 parts of space-forming materials and 1-10 parts of guest molecules in 20-60 parts of solvent.

[0038] Specifically, the above steps include step S110 and step S130:

[0039] Step S110: Dissolving 20-50 parts of space-forming materials in 20-60 parts of solvent to obtain the first mixture;

[0040] Step S130: adding 1-10 parts of guest molecules into the first mixture, mixing and dissolving to obtain the color-changing ink.

[0041] In some embodiments, in the above step of obtaining the color-changing ink, that is, after step S110 and before step S130, it also includes step S120: adding 5 parts to 30 parts of filler material to the first mixture dissolved step. It should be noted that, in some embodiments, the above-mentioned fillers can be generated internally by the addition and e...

Embodiment 1

[0052] The preparation steps of the color-changing ink of the present embodiment are as follows:

[0053] (1) Take 20 parts of polyvinyl butyral, add it into 30 parts of isopropanol and dissolve it to obtain the first mixture.

[0054] (2) Get 5 parts of stearic acid and dissolve in the above-mentioned first mixture.

[0055] (3) Finally, add 1 part of iodine simple substance to the above-mentioned first mixture for mixing and dissolving to obtain the color-changing ink.

[0056] The initial state of the color-changing ink prepared in Example 1 is orange. After the ink solvent is dried, polyvinyl butyral, stearic acid and iodine element together form an inclusion compound, which is green. With the escape of iodine element, the ink gradually changes from Green changes to blue and finally to transparent color. Experiments have shown that when the ink layer thickness of the above-mentioned color-changing ink is 0.01 mm, the color-changing cycle of the color-changing ink layer i...

Embodiment 2

[0058] The preparation steps of the color-changing ink of the present embodiment are as follows:

[0059] (1) Take 30 parts of polyvinyl butyral and dissolve it in 30 parts of isopropanol to obtain the first mixture.

[0060] (2) Take 10 parts of oleic acid and dissolve in the above-mentioned first mixture.

[0061] (3) Finally, add 3 parts of simple iodine to the above-mentioned first mixture for mixing and dissolving to obtain the color-changing ink.

[0062] The initial state of the color-changing ink prepared in Example 2 is orange. After the ink solvent is dried, polyvinyl butyral, oleic acid and iodine element together form an inclusion compound, which is green. With the escape of iodine element, the ink gradually changes from green to green. turns blue and eventually becomes transparent. Experiments have shown that when the ink layer thickness of the above-mentioned color-changing ink is 0.05mm, the color-changing cycle of the color-changing ink layer is 15 days in an...

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PUM

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Abstract

The invention relates to color-changing ink and a preparation method and application thereof. The color-changing ink comprises, by mass, the following raw materials: 20-50 parts of space constitutingmaterial, 1-10 parts of guest molecules and 20-60 parts of a solvent; wherein the space constituting material is a linear polymer material with a average molecular weight of more than 10,000 and a chain structure, and the guest molecules are an iodine simple substance. The price of each raw material for forming the color-changing ink is low, and the cost for preparing the color-changing ink is obviously lower than that of a prior temperature-sensitive color-changing ink prepared from nano gold particles, silver ions and reducing agents which are used as core components; various raw materials and ink finished products do not need the prior low-temperature storage and transportation conditions required by the temperature-sensitive color-changing ink mainly prepared from a substituted dialkyne monomer.

Description

technical field [0001] The invention relates to the field of inks, in particular to color-changing inks, a preparation method and applications thereof. Background technique [0002] The quality of food is lost in the time of food transportation and storage. The time-temperature indicator (TTI, time-temperature indicator) is a new type of indicator device used to monitor the safety of food and other products in real time. It produces a cumulative effect of time and temperature through physical or chemical changes, which is used to record the temperature change history of the product and indicate the remaining shelf information of the product, that is, through the change of the ink color of the device, it can be visually distinguished whether the product is expired. [0003] There are two main types of traditional temperature-sensitive color-changing inks: temperature-sensitive color-changing inks with substituted diacetylene monomers as core materials and temperature-sensitiv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/50C09D11/03C09D11/106C09D11/08C09D11/14C09D11/102
Inventor 刘永生周世兵李冬玲蒋建彪
Owner SHENZHEN NINE STARS PRINTING & PACKAGING GRP