Coke quality improvement synergist and its preparation and use method

A quality-enhancing synergist and coke technology, which is applied in the new field of coking, can solve the problems of increasing coke ash content, high passivation agent price, and viscous solution, so as to improve fragmentation and wear resistance, reduce coal blending costs, The effect of increasing the thermal strength

Active Publication Date: 2020-09-01
CHONGQING LUNIU TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The Chinese invention patent with the publication number CN101082008A introduces "a coke passivator containing rare earth elements of the lanthanum series and its use method", which uses borax, wollastonite, rare earth co-abrasives of the lanthanum series and 60% to 90% boric acid Mix, add water and stir, and finally blend and stir with carboxymethyl cellulose. The passivator is expensive and the solution is viscous, which is not conducive to industrial implementation
The Chinese invention patent with the publication number CN102041129 introduces "a coke passivator containing trace additives and its preparation and use method", using 20-80% boric acid, 15-70% inorganic additives, and 0% active additives. ~15%, trace additive 0.1~5%, then mix and ball mill for 1~3 hours, then dissolve into water to make emulsion; this process is too complicated, not only increases the ash content of coke, but also increases the production cost, It is also not conducive to industrial promotion and application
There are also some patented technologies about coke passivators, which have different defects and limitations in terms of preparation process, raw material cost and implementation methods.

Method used

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  • Coke quality improvement synergist and its preparation and use method
  • Coke quality improvement synergist and its preparation and use method
  • Coke quality improvement synergist and its preparation and use method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of coke quality improving synergist (with 100kg as quantitative unit), its component and mass percent content are: succinic acid 0.1%, suberic acid 5.0%, N-acylglutamate (C 12 h 15 NO 6 S) 10.0%, cationic cellulose (cationic cellulose is a low irritation cationic polymer with excellent water solubility, conditioning, adsorption and repairing properties) 14.9%, titanium concentrate powder 10.0%, instant boron 10.0 %, boron trioxide 50.0%.

[0023] Prepare the coke quality-improving synergist according to the following steps: add the weighed components into a dry blender and mix evenly, the speed of the blender is controlled at 15 rpm, and the mixing time is controlled at 45 minutes. During the mixing process, the mixing tank is heated with electricity, and the temperature of the mixing tank is controlled at 100°C; the mixing material is dehumidified so that the moisture content of the quality-enhancing synergist is ≤1.0%. Then weigh and bag.

[0024] Dissolve ...

Embodiment 2

[0029] A preparation of a coke quality-improving synergist (with 100kg as the quantitative unit), its components and mass percent content are: 2.0% succinic acid, 3.0% suberic acid, 10.0% N-acyl glutamate, cationic Cellulose 8.0%, titanium concentrate powder 7.0%, instant boron 25.0%, boron trioxide 45.0%.

[0030] Prepare the coke quality-improving synergist according to the following steps: add various substances weighed into a dry blender and mix evenly, the speed of the blender is controlled at 20 rpm, and the mixing time is controlled at 40 minutes. During the mixing process, the mixing tank is heated with electricity, and the temperature of the mixing tank is controlled at 75° C., and the mixing material is dehumidified so that the moisture content of the quality-enhancing synergist is ≤1.0%. Then weigh and bag.

[0031] Dissolve the above-mentioned coke upgrading synergist with water into a solution with a mass concentration of 7.0%, spray the prepared solution three-d...

Embodiment 3

[0035] A preparation of a coke quality-improving synergist (with 100kg as the quantitative unit), its components and mass percent content are: 3.0% succinic acid, 0.1% suberic acid, 5.0% N-acyl glutamate, cationic Cellulose 6.9%, titanium concentrate powder 15.0%, instant boron 25.0%, boron trioxide 45.0%;

[0036] Prepare the coke quality-improving synergist according to the following steps: add various substances weighed into a dry blender and mix evenly, the speed of the blender is controlled at 30 rpm, and the mixing time is controlled at 30 minutes. During the mixing process, the mixing tank is heated with electricity, and the temperature of the mixing tank is controlled at 65° C., and the mixing material is dehumidified so that the moisture content of the quality-enhancing synergist is ≤1.0%. Then weigh and bag.

[0037] Dissolve the above-mentioned coke quality-improving synergist with water into a solution with a mass concentration of 1.0%, and spray the prepared solu...

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PUM

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Abstract

The invention discloses a coke quality-improving synergist, whose components and mass percentages are: 0.1-3.0% of succinic acid, 0.1-5.0% of suberic acid, 0.1-10.0% of N-acyl glutamate, cationic 0.1-15% cellulose, 0.1-20.0% titanium concentrate powder, 10.0-35.0% instant boron, 30.0-55.0% boron trioxide. It also discloses its preparation method: (1) weighing each component according to the mass percentage of each component; (2) mixing, heating and dehumidifying each weighed component to obtain the product. Also disclosed is a method for using the aforementioned coke quality-enhancing synergist: the quality-enhancing synergist is formulated into an aqueous solution with a mass concentration of 1.0-12.0%, and the aqueous solution is sprayed on the coke at an injection rate of 1.0-5.0% of the coke weight . The synergist of the invention can not only save a large amount of coke quenching water resources, but also can significantly improve coke fragmentation and enhance the hot strength of coke.

Description

technical field [0001] The invention belongs to the field of coking new technologies, and in particular relates to a coke quality-improving synergist and a preparation and use method thereof. Background technique [0002] Since 2000, Shougang Jingtang 5500m 3 A batch of large-scale blast furnaces represented by blast furnaces have been put into operation one after another in China, with 4000m2 3 The above-mentioned large-scale blast furnaces have reached 22, and the large-scale blast furnace has become a future development trend. With the large-scale blast furnace and the intensification of smelting, the load on coke in the blast furnace has increased from below 4.0 to 6.0, and the working conditions of coke have deteriorated significantly. After the coke reaches the lower part of the furnace shaft, due to the high temperature thermal stress, gasification corrosion, alkali metal, etc., the thermal strength decreases, the particle size becomes smaller, and the powder increa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10B57/06
Inventor 朱慧强
Owner CHONGQING LUNIU TECH
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