Preparation method for anti-wear reagent at extreme pressure and application in full synthetic water-based molding liquid
An anti-wear agent and molding fluid technology, applied in additives, lubricating compositions, petroleum industry and other directions, can solve the problems of anti-oxidation, anti-detergency, weak repair function and poor multi-functionality, and achieve good biodegradability, Good abrasion resistance, excellent anti-corrosion effect
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Embodiment 1
[0033] A preparation method of an antiwear agent, comprising the following steps,
[0034] (1) Preparation of DMF homogeneous dispersion of carboxylated graphene oxide:
[0035] Take 1mg / mL graphene oxide uniform dispersion, add hydrobromic acid, stir vigorously at room temperature for 8h, add oxalic acid, continue to react for 3h, wash with deionized water until neutral, and then use DMF to make the solution concentration 1mg / mL, continuous ultrasonic dispersion for 20h, to obtain a homogeneous dispersion of carboxylated graphene oxide in DMF.
[0036] (2) Graphene oxide composite modified by lanthanum phthalocyanine
[0037] Take the DMF homogeneous dispersion of carboxylated graphene oxide, tetraaminolanthanum phthalocyanine EDC, and DMAP, heat at 80°C under vacuum nitrogen protection, react for 45h, cool and centrifuge and wash to obtain the graphene oxide compound modified by lanthanum phthalocyanine , that is, the antiwear agent.
[0038] The EDC is 1-(3-dimethylamino...
Embodiment 2
[0040] A preparation method of an antiwear agent, comprising the following steps,
[0041] (1) Preparation of DMF homogeneous dispersion of carboxylated graphene oxide:
[0042] Take 1mg / mL graphene oxide uniform dispersion, add hydrobromic acid, stir vigorously at room temperature for 15h, add oxalic acid, continue to react for 5h, wash with deionized water until neutral, and then use DMF to make the solution concentration 1mg / mL, continuous ultrasonic dispersion for 30h, to obtain a homogeneous dispersion of carboxylated graphene oxide in DMF.
[0043] (2) Graphene oxide composite modified by lanthanum phthalocyanine
[0044] Take the DMF homogeneous dispersion of carboxylated graphene oxide, tetraaminolanthanum phthalocyanine EDC, and DMAP, heat at 99°C under vacuum nitrogen protection, react for 55h, cool and centrifuge and wash to obtain the graphene oxide compound modified by lanthanum phthalocyanine , that is, the antiwear agent.
[0045] The EDC is 1-(3-dimethylamin...
Embodiment 3
[0047] A preparation method of an antiwear agent, comprising the following steps,
[0048] (1) Preparation of DMF homogeneous dispersion of carboxylated graphene oxide:
[0049] Take 1mg / mL graphene oxide uniform dispersion, add hydrobromic acid, stir vigorously at room temperature for 12h, add oxalic acid, continue to react for 4h, wash with deionized water until neutral, and then use DMF to make the solution concentration 1 mg / mL, continuous ultrasonic dispersion for 24 hours, to obtain a homogeneous dispersion of carboxylated graphene oxide in DMF.
[0050] (2) Graphene oxide composite modified by lanthanum phthalocyanine
[0051] Take the DMF homogeneous dispersion of carboxylated graphene oxide, tetraaminolanthanum phthalocyanine EDC, DMAP, heat at 90°C under vacuum nitrogen protection, react for 48h, cool and centrifuge and wash to obtain the graphene oxide compound modified by lanthanum phthalocyanine , that is, the antiwear agent.
[0052] The EDC is 1-(3-dimethylam...
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