34results about How to "Little environmental hazard" patented technology

A method and apparatus for generating energy from a composition containing guanidine and a method for providing the composition containing guanidine. The apparatus includes a container such as tank (1) for providing the composition, and a container such as tank (2) for providing water. The composition is delivered from tank (1) to a container such as reactor (3) for reacting the guadinine composition with water, supplied from tank (2), to form ammonia. The apparatus may also include buffer tank (4) for storing the ammonia produced by the reactor. The ammonia produced from the reactor of the guadinine composition with water is delivered from the buffer tank (4) to a container such as chamber (5) for oxidizing ammonia to form water and nitrogen generating energy

The invention relates to a catalyst for removing nitrogen oxide through selective catalytic reduction for an automobile diesel engine adopting Ce2O3 and V2O5 double active compositions. The catalyst adopts scordierite honeycomb ceramics as a framework material, the Ce2O3 and the V2O5 as main active compositions, WO3 or MoO3 as an auxiliary catalyst composition, and TiO2 as a coating substrate, wherein the mass fraction of the main active compositions, namely the Ce2O3 and the V2O5, to the auxiliary catalyst composition WO3 or MoO3 to the coating substrate TiO2 is 1-3:6:12:85-93. The specific process comprises the following steps: preparing a TiO2 precursor solution; coating a TiO2 coating; coating an auxiliary catalyst; determining the loading of active compositions of oxides; and coating the main active compositions, namely the Ce2O3 and the V2O5. The catalyst replaces the V2O5 with high toxicity with the Ce2O3 with low toxicity, and reduces the environmental hazards of the catalyst, and the replaced catalyst has wider active temperature range, particularly greatly improves the low-temperature activity, and is particularly suitable for the traffic conditions of urban highways of China.

The invention discloses a preparation method for synthesizing an aniline catalyst by undergoing a hydrogenation reaction on nitrobenzene. The method comprises the following steps of: reducing a PdCl2 aqueous solution under the protection of sodium citrate by taking a NaBH4 aqueous solution as a reducing agent to obtain Pd nanoparticle sol; and mixing and stirring an ultrasonically-treated carbon nanotube in the aqueous solution with the Pd nanoparticle sol to form a Pd-carbon nanotube catalyst. The aniline catalyst shows very high activity in a reaction for synthesizing aniline through hydrogenation of nitrobenzene, and has long cycle life.

The invention provides stainless steel washed white solution, which uses water as solvent, every one liter of the solution comprises 4-10 percent of nitric acid, 10-40g phosphoric acid, 2.5g boric acid, 5-30g acetic acid, 10-30g ammonium sulfate, 10-30g trisodium phosphate and 15-35g ammonium bifluoride. The method of using the stainless steel washed white solution to do the washed white process of the surface of stainless steel has the technological processes of pretreatment, degreasing, pickling, washing white, washing and baking, wherein after the stainless steel which is needed to be washed white is pretreated, degreased and pickled, the stainless steel which is pickled is put into the stainless steel washed white solution for 10-35 minutes in 55-85 DEG C, at last through washing and baking, the surface of the stainless steel is formed with an uniform silvery film layer which has a sand surface effect.

The invention relates to an auxiliary agent for a pigment, which is particularly suitable for dispersing the pigment, has good dispersion performance and high stability, and belongs to the field of application of a fine chemistry industry. A dispersant is prepared from fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether monoester, fatty alcohol-polyoxyethylene ether diester, carboxylated fatty alcohol-polyoxyethylene ether, carboxylated fatty alcohol-polyoxyethylene ether monoester and carboxylated fatty alcohol-polyoxyethylene ether diester. The dispersant is easily and biologically degraded and meets ecological and green and environment-friendly requirements; and a unique molecular chain structure can better disperse the pigment and can keep the pigment stable.

The invention discloses a surface sizing agent and a preparation method thereof. The preparation method comprises the following steps: 1, adding an aqueous solution of a cationic etherifying agent to a mixture of guar gum raw powder and an aqueous solution of a low carbon alcohol under an inert atmosphere, such as a nitrogen atmosphere, adding an alkali catalyst, and reacting to obtain a cationic guar gum product; 2, adjusting the pH value of a system of the product obtained in step 1 to 1-4 by an acidic neutralizer, adding a superacidic chemical, and reacting; and 3, adding a viscosity stabilizing agent, and simultaneously adjusting the PH value to 6-9, reacting, and collecting the surface sizing agent from reaction products. The surface sizing agent of the invention, which has the characteristics of very good fluidity, easy dispersion and usage, exquisite and stable gum solution, and rapid hydration swelling, is an ideal surface sizing agent, and simultaneously is a multifunctional wet-end additive. The surface sizing agent is suitable for sizing various surfaces of cultural paper, newspaper, art paper and special paper.

The invention discloses a technology of using asbestos tailings to produce a silicon-calcium-magnesium-potassium fertilizer. The technology comprises following steps: at first, grinding serpentine bya cone crusher to a size of 3 cm or so; then adding grinded serpentine into a ball milling machine, carrying out ball milling for 30 to 40 minutes, controlling the granularity of serpentine to be 250meshes or so; adding KCl particles into the ball milling machine, wherein the ratio of KCl particles to serpentine is 1:9, carrying out ball milling for 30 minutes, when the granularity of particles in the ball milling machine is greater than 300 meshes, discharging the powder to a winnowing machine, winnowing the powder under a pressure of 6 kg; after winnowing, directly packaging the powder, orusing the powder to product a fertilizer, discharging materials which are not winnowed from the rotating cylinder, and taking non-winnowed materials as a metallurgy raw material. The asbestos tailingsare processed harmlessly, the wastes are converted into valuable resources, and the environmental pollution is reduced.

The invention discloses a purifying method for spherical graphite. The automatic purifying method for the spherical graphite comprises the following steps: adding the spherical graphite, fluoride, a complexing agent and water into a primary reaction tank, uniformly stirring, introducing steam, heating for 3h, and carrying out reaction for 8-12h at the temperature of 80-120 DEG C; after reaction, pumping a material into a primary filter press through a pipeline at the bottom by virtue of a material conveying pump, carrying out filtration and deacidification, collecting waste acid liquid into an acid storage tank for secondary reserve, introducing soft water, and cleaning the material to be neutral; sending the material discharged by the primary filter press into a middle pulping tank by virtue of a spiral material conveying device; adding aqua regia and water into the middle pulping tank according to a certain ratio, and stirring until the material is in a gruel shape, and pumping the material into a secondary reaction tank by virtue of the material conveying pump; introducing the steam, heating, and carrying out reaction for 4-8h at the temperature of 80-120 DEG C; after reaction, discharging the material, enabling the material to enter a secondary filter press by virtue of the material conveying pump, carrying out filtration and deacidification, collecting concentrated acid liquid into an acid storage tank, introducing deionized water, cleaning the material to be neutral, and drying the discharged material to obtain the high-purity spherical graphite, wherein the purity of the spherical graphite can achieve 99.99-99.995 percent.

The invention relates to a flyash tamping plug and a preparation method thereof and belongs to the field of water pressure blasting technology. The flyash tamping plug is prepared from the following raw materials in parts by weight: 90-110 parts of low liquid limit clay (liquid limit (50%)), 5-7 parts of coarse sand, 6-8 parts of flyash and 14-17 parts of water. The preparation method comprises the following steps of: weighing the low liquid limit clay, the coarse sand, the flyash and the water as required and uniformly mixing to form primary material; hardening the primary material for 1-2h and fianlly processing the hardened into a tamping plug rolls. According to the novel tamping plug, flyash and clay powder are used as core materials, local materials are used, and the cost is saved. The corresponding preparation method is simple, the water-retaining property of the obtained product is good, the flyash tamping plug can be stored for 12 hours after being processed into the tamping plug rolls; if coated with a plastic film, the storage time can be further prolonged, and the existing common loess tamping plug only can be stored for 5 hours under no protection.

The invention discloses a novel environment-friendly gold ore beneficiation process under simulated natural conditions, and relates to the fields of beneficiation and environmental protection. It is characterized in that the particle size distribution of gold particles in the gold ore and the components and forms of the associated ore are accurately measured, and then the gold ore is crushed, finely ground, step-by-step screened, blown, magnetized water treatment, heating, cooling , ultrasound, microwave, gravity separation and other technological procedures, simulated the geological weathering process that would take millions of years to complete under natural conditions, and quickly realized the process of gold ore transformation into alluvial gold and gold concentration, so that the grade of gold concentrate produced It can be increased from less than 100 grams/ton to 300-1000 grams/ton. This treatment process is suitable for refractory original ecological gold mines, and can effectively recycle various tailings produced in the process. Compared with traditional processes, it can greatly reduce production costs and reduce environmental pollution. It is a low-cost And environment-friendly gold ore beneficiation process.

The invention discloses an exhaust system and method of a vacuum drying chamber. The exhaust system of the vacuum drying chamber comprises a plurality of exhaust openings and an exhaust pump, wherein the exhaust openings are formed outside the vacuum drying chamber; the exhaust pump is connected with the exhaust openings through exhaust pipes. The exhaust method of the vacuum drying chamber includes the steps that when a base plate to be dried is placed in the vacuum drying cavity, exhausting is conducted through the exhaust pump; when the vacuum drying chamber is closed, the exhaust pump is stopped from conducting exhausting; when the dried base plate is taken out of the vacuum drying chamber, exhausting is conducted through the exhaust pump. In conclusion, the multiple exhaust openings are formed outside the vacuum drying cavity, so that when the base plate is stored in and taken out of the cavity, the volatile gas of the dissolved matter of high concentration in the cavity can be discharged through the multiple exhaust openings formed outside the vacuum drying cavity, and the harm to the environment generated in the storing and taking process of the base plate is reduced.

The invention discloses an egg yolk-egg shell structure type microsphere and a preparation method thereof. The preparation method comprises the following steps: preparing a mixed dispersion material of powder and molten naphthalene, wherein a mass ratio of the powder to the naphthalene in the mixed dispersion material is 1 : (2-5); treating the mixed dispersion material by adopting a melt granulation device to obtain a powder/naphthalene spherical mixture; preparing a mixed material of a nano-graphite flake and an organic binder, and wrapping the surface of the powder/naphthalene spherical mixture with the mixed material to obtain a powder/naphthalene/mixed material microsphere, wherein a mixed material and a powder body wherein a mass ratio of the mixed material to the powder/naphthalenespherical mixture is 1 : (10-70); and carrying out low-temperature heating treatment on the powder/naphthalene/mixed material microsphere to remove a naphthalene layer to obtain an egg yolk-egg shellstructure type powder@mixed material microsphere, and carrying out high-temperature carbonization treatment on the powder@mixed material microsphere to obtain an egg yolk-egg shell structure type powder@graphite microsphere. The invention provides a preparation method of an egg yolk-egg shell structure type nuclear@graphite microsphere which is corrosion-free, simple, cheap and environment-friendly, and can be prepared on a large scale.

The invention discloses a corrosion-preventing treating agent for the surface of an alloy casting. The corrosion-preventing treating agent comprises, by weight, 100 parts of oxalic acid, 20-25 parts of silane coupling agent, 20-30 parts of isopropanol, 10-15 parts of soluble aluminum salt, 6-8 parts of corrosion inhibitor and 80-120 parts of distilled water. At the room temperature, the oxalic acid and the soluble aluminum salt are sequentially added into a mixed solution of the isopropanol and the distilled water to be evenly stirred, and then the silane coupling agent and the corrosion inhibitor are added to the solution. According to the corrosion-preventing treating agent, a very good corrosion-prevention and rust-prevention protection effect can be better achieved on the metal pressure casting, cleaning of the surface of the casting can be strengthened through the adding of the oxalic acid and the soluble aluminum salt, the dispersing effect of the treating agent can be enhanced under the synergistic effect of the silane coupling agent and other components, the binding force of a corrosion-prevention film layer is improved, and coating adhesive force is improved.

The invention discloses a method of utilizing zinc hydro-metallurgy oxygen pressure acid leaching slag to prepare a demercuration adsorbent. The method comprises following steps: (1) evenly mixing oxidized zinc ores with oxygen pressure acid leaching slag to obtain a premixed material, and dissolving soluble sulfides into an organic solution to obtain a sulfide solution; (2) mixing the premixed material and the sulfide solution obtained in the step (1), stirring the mixture under the assistance of ultrasonic waves to obtain a turbid liquid, heating the turbid liquid to carry out hydrothermal reactions, and collecting the product namely a zinc polysulfide compound; and (3) mixing the zinc polysulfide compound obtained in the step (2) with iron salts, and evenly mixing to obtain the demercuration adsorbent. The zinc hydro-metallurgy oxygen pressure acid leaching slag is taken as the raw material to prepare the demercuration adsorbent; the damage to the environment is reduced; the oxygenpressure acid leaching slag is completely converted into valuable resources; moreover, the prepared adsorbent has a high mercury removal rate, and at least 90% of mercury in various forms in flue gasand waste liquid is removed.

An optical recording medium 10 on which recording/reproducing or reproducing is performed by irradiating a light by means of an objective lens 4 having a numerical aperture equal to or more than 1 wherein an optical recording portion 2 is provided at least at the outer most surface at the irradiation side of the optical recording medium 10 and a relation n≧NA is selected when the refractive index of the recording portion 2 is n and the numerical aperture of the objective lens 4 is NA. Accordingly, it can propose an optical recording medium and an optical recording/reproducing method suitable for a near-field optical recording method which uses an objective lens having a numerical aperture equal to or more than 1.

The invention discloses a preparation method of a Fe monatomic catalyst Fe-PANI. The preparation method comprises the following steps: 1) pretreating a polyaniline carrier; polyaniline in a complete oxidation state or an intermediate oxidation state is directly used as a carrier; the polyaniline in the acid-doped state is used as a carrier after being subjected to alkali washing; (2) dipping the polyaniline carrier in a ferric salt solution or a ferrous salt solution or a mixed solution of ferric salt and ferrous salt, so that Fe atoms are coordinated with imine nitrogen atoms in polyaniline to be loaded on the surface of polyaniline; and 3) separating out the polyaniline carrier loaded with Fe atoms, washing the polyaniline carrier with deionized water, and drying to obtain the Fe monatomic catalyst Fe-PANI. The invention further relates to the Fe monatomic catalyst Fe-PANI prepared through the method, polyaniline serves as a carrier of the Fe monatomic catalyst Fe-PANI, and Fe monatomic atoms are stably loaded on the surface of the polyaniline carrier in a highly dispersed mode through coordination.

The invention discloses an environment-friendly type dyeing assistant for natural blended fabric. The environment-friendly type dyeing assistant is mainly prepared from the following main raw materials: a rare earth compound, organic acid, borax, chitosan, a leveling agent, a dispersant, zinc oxide and sodium hexametaphosphate. In the environment-friendly type dyeing assistant, the main raw materials are the borax and the sodium hexametaphosphate, and a trace of the rare earth compound and a small amount of the zinc oxide are supplemented, so that the content of inorganic salt is reduced to be less than 1 percent, and environmental hazard is remarkably reduced; meanwhile, during a preparation process, compounds, such as halogens and heavy metal, which are harmful to a human body and the environment are not added. The environment-friendly type dyeing assistant disclosed by the invention is matched with active dye for use, and dyed natural blended fabric is uniform in color, has no chromatic aberration, is bright in color and good in color fixing effect.

The invention relates to the field of oil field chemistry, and belongs to a polymer gel crosslinking agent capable of realizing the controllable gelling time. The polymer gel crosslinking agent mainlysolves the problems of gelling time uncontrollability and environment pollution of the frequently-used polymer gel crosslinking agents in an oil field. The polymer gel crosslinking agent is preparedfrom the following ingredients in percentage by weight: 0.2 to 0.3 percent of trivalent metal chromium ion salt, 0.01 to 0.03 percent of low-carbon mixed organic acid, 0.02 to 0.05 percent of organicacid, 0.03 to 0.06 percent of melamine, 0.01 to 0.04 percent of sodium sulfite and the balance of water. The polymer gel crosslinking agent has the advantages that the gelling time is controllable; the harm to the environment is small; good long-period thermal stability is realized, and the like.

The invention belongs to the technical field of treatment of rural ditch sludge, and discloses a treatment method and a treatment system for rural ditch sludge. The treatment system for the rural ditch sludge comprises a water quality detection device, a sludge image collection device, a main control device, a sludge extracting device, a dewatering device, a drying device, a carbonization device and a display device. Lysozyme is used to hydrolyze the cell walls of microorganisms in the sludge through the dewatering device, so the system can achieve a good sludge dewatering effect and has few harms to the environment. The carbonization device utilizes the deodorizing function of the microorganisms and the filtering function of carbonized sludge to effectively remove the odor of the sludge after long-time sludge before drying the sludge, so the health of the worker is prevented from being damaged.

The invention discloses the technical field of agricultural chemical engineering, and particular to an aphid repellent based on multi-component linear chain unsaturated aldehydes. A preparation methodof 1L of repellent includes the steps: S1 weighing 1g of purified purple-leaf plum, adding the purple-leaf plum into 1L of deionized water, standing and soaking mixture for 12hours, and completely dissolving the purple-leaf plum in water to form homogeneous solution to obtain purple-leaf plum water solution; S2 adding 5g of 4-oxo-2-hexenoic aldehyde, 1g of trans-2-hexenoic aldehyde and 1g of trans-2-octenal into 1L of purple-leaf plum water solution, and mechanically stirring mixture for 15 minutes to obtain mixed solution; S3 adding 1mL of nonionic surface active agent polyethylene glycol 400 into the mixed solution, and continuing to mechanically stir mixture for 30 at the indoor temperature to obtain the repellent. The prepared aphid repellent cannot kill aphids and effectively repelsthe aphids. Compared with a pesticide for killing the aphids, the prepared aphid repellent is free from toxicity and harm, less in environmental harm and more suitable for outdoor viewing and gardening flowers.

The invention relates to the technical field of neodymium-iron-boron magnets, in particular to a neodymium-iron-boron magnet surface coating process which comprises the following steps: S1, polishing; s2, removing oil and cleaning; s3, acid pickling; s4, performing surface conditioning processing; s5, activating treatment; s6, nickel electroplating treatment, wherein an electroplating solution comprises the following components: 100-110 g/L of nickel sulfate, 60-80 g/L of nickel chloride, 20-50 g/L of sodium sulfate, 40-60 g/L of boric acid and 0.05-0.1 g/L of lauryl sodium sulfate; the pH value of the electroplating solution is 4.0-5.0, the electroplating treatment time is 30-60 minutes, the temperature is 60-65 DEG C, the current density is 0.5-0.6 A/dm < 2 >, and the thickness of a plating layer is 2-6 microns; s7, chemical nickel-tungsten-phosphorus alloy plating treatment; according to the coating technology, operation is easy and convenient, in the coating process, used reagents have little harm to the environment, the composite coating almost has no influence on the thermal demagnetization rate of the magnet, the binding force between the composite coating and a base body is very good, the composite coating is not prone to falling off, and the corrosion resistance of the neodymium-iron-boron magnet is greatly improved.