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Method for dephosphorization of molten iron, and refining agent

A technology of refining agent and molten iron, which is applied in the dephosphorization method of molten iron and the field of refining agent, can solve the problems that the refining agent is difficult to melt, the dephosphorization reaction cannot be carried out efficiently, and the reaction time is short, so as to improve the efficiency of dephosphorization treatment Effect

Active Publication Date: 2019-08-23
JFE STEEL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, there is a problem that the refining agent is difficult to melt (slagging) and the reaction time is short.
That is, compared with the case of using a converter, there is a problem that the dephosphorization reaction cannot be efficiently carried out in the case of using a mixed iron car or a molten iron tank.

Method used

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  • Method for dephosphorization of molten iron, and refining agent
  • Method for dephosphorization of molten iron, and refining agent
  • Method for dephosphorization of molten iron, and refining agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0083] Next, Example 1 performed by the inventors of the present application will be described. In Example 1, with respect to the dephosphorization method related to the above-mentioned embodiment, the dephosphorization treatment was performed by changing the Ig-loss value of the lime source as the refining agent 7, and the relationship between the Ig-loss value and the dephosphorization rate (dephosphorization rate) was investigated. coming impact.

[0084] In Example 1, first, the molten iron 2 that has been tapped from the blast furnace and desiliconized in the blast furnace sand bed is transferred and injected into a molten iron tank with a capacity of 250 tons as the molten iron holding container 1, and transported to figure 1 The dephosphorization treatment equipment shown. Next, in the dephosphorization treatment equipment, the refining agent lime source is blown in from the injection lance 3, the gaseous oxygen source 9 and the dephosphorization agent 11 are injected ...

Embodiment 2

[0091] Next, Example 2 performed by the inventors of the present application will be described. In Example 2, the stirring power (ε g +ε p ) to carry out dephosphorization treatment, and investigate the effect of stirring power on the dephosphorization rate.

[0092] In Example 2, the dephosphorization treatment was performed by changing the stirring power (gg+εP) from 265 W / t to 1392 W / t under the same conditions as in Examples 1-11. It should be noted that the phosphorus concentration before the dephosphorization treatment of the molten iron 2 is 0.121% by mass to 0.125% by mass. About other conditions, it is the same as Example 1-14.

[0093] Table 2 shows the stirring power and refining agent conditions in Example 2, and the phosphorus concentration and dephosphorization rate in the molten iron 2 before and after the treatment as the investigation results.

[0094] As shown in Table 2, it was confirmed that under any conditions, although the dephosphorization rate was ...

Embodiment 3

[0098] Next, Example 3 performed by the inventors of the present application will be described. In Example 3, regarding the dephosphorization method according to the above-mentioned embodiment, the dephosphorization treatment was performed by changing the specific surface area of ​​the refining agent 7, and the influence of the specific surface area of ​​the refining agent 7 on the dephosphorization rate was investigated.

[0099] In Example 3, for the same conditions as in Example 2-3, the specific surface area of ​​the refining agent 7 was changed to 0.41m 2 / g~5.13m 2 / g to carry out dephosphorization treatment respectively. It should be noted that the phosphorus concentration before the dephosphorization treatment of the molten iron 2 is 0.121% by mass to 0.125% by mass. About other conditions, it is the same as Example 2-3.

[0100] Table 3 shows the stirring power and refining agent conditions in Example 3, and the phosphorus concentration and dephosphorization rate i...

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Abstract

During dephosphorization processing of molten iron (2) by adding an oxygen source (dephosphorization agent (11, 12) or a gaseous oxygen source (9)) and a refining agent (7) as a lime source to the molten iron (2) accommodated in a molten-iron holding container (1), a refining agent having an Ig-loss value of 4.0% by mass to 35.0% by mass and including 60% by mass of quicklime is used as the refining agent (7).

Description

technical field [0001] The invention relates to a method for dephosphorizing molten iron and a refining agent. Background technique [0002] In recent years, the quality requirements for steel have become increasingly stringent, requiring the reduction of impurity elements represented by phosphorus and sulfur. To meet such demands, in the steelmaking process, dephosphorization is usually performed at the molten iron stage. This dephosphorization treatment is carried out by supplying an oxygen source such as gaseous oxygen (oxygen) or solid iron oxide as a dephosphorization agent to molten iron, and oxidizing phosphorus in the molten iron with oxygen in the dephosphorization agent to form phosphorus oxides. (P 2 o 5 ) to absorb the generated phosphorus oxides into the slag for dephosphorization and refining. [0003] As a refining agent for forming slag for dephosphorization refining, a lime-based refining agent is generally used. In addition, in recent years, from the v...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C1/02
CPCC21C1/02C21C1/025C21C7/064C21C7/0037C21C7/076C21C2200/00C21C7/072C21C7/0075Y02P10/20C21C5/4606C21C7/00C21C7/0645
Inventor 藤井勇辅中井由枝森干洋前田孝彦菊池直树西口范孝
Owner JFE STEEL CORP