Preparation method of aquaculture bactericide

A technology for aquaculture and fungicides, applied in botany equipment and methods, biocides, chemical instruments and methods, etc., can solve the problem that the sterilization effect is easily affected by water hardness, light, temperature, toxicity and Corrosiveness and other problems, to achieve the effect of large unit sterilization treatment capacity, wide application range and easy operation control

Inactive Publication Date: 2019-09-06
金华市呗力水产养殖技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the development of the aquaculture industry, people are constantly screening new disinfectants. At present, there are still many shortcomings in existing disinfectants, such as chlorine-containing disinfectants, which are easily affected by changes in organic matter and pH in water, and have harmful effects on utensils. Corrosive effect, also highly toxic to fish, the effective chlorine contained in the chlorine preparation reacts with the water body to form various halides, and produces a variety of non-volatile halogenated organic compounds such as trihalomethanes, etc. At the same time, the chlorine preparation reacts with ammonia in the water to form Chloramine, not only has no killing effect on pathogens in water, but also has side effects on aquatic organisms after reaching a certain concentration; the bactericidal effect of quaternary ammonium salts is easily affected by water hardness, and the bactericidal effect is poor under acidic conditions; Although iodine preparations have good bactericidal effect, they are easily affected by light and temperature, and are easy to evaporate and fail; although phenolic disinfectants are less affected by organic matter, they have poor bactericidal effect, pollute the environment, and are toxic and corrosive

Method used

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  • Preparation method of aquaculture bactericide
  • Preparation method of aquaculture bactericide
  • Preparation method of aquaculture bactericide

Examples

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Embodiment 1

[0026] A preparation method of aquaculture bactericide, comprising mixing the dispersion of chitosan quaternary ammonium salt in a dispersion medium with activated carbon; the modifier for the preparation of the above-mentioned chitosan quaternary ammonium salt is 2,3-epoxypropyl Trimethylammonium chloride, activator is glycolic acid and zinc L-lactate. Chitosan quaternary ammonium salt is the product of chitosan modified by alkylation, and the quaternary ammonium group of quaternary ammonium salt is substituted to the amino group of chitosan to form a stronger polycationic compound. The quaternization modification of chitosan greatly improves the solubility of chitosan, and it has more positive charges than chitosan, which interacts with the negative charges on the surface of the bacteria, thereby changing the penetration of the cell membrane of the bacteria, so that The transport of extracellular substances is blocked, thereby achieving better antibacterial and bactericidal ...

Embodiment 2

[0037] A kind of preparation method of aquaculture fungicide, its concrete steps are as follows:

[0038] 1) dissolving the crude chitosan in glacial acetic acid with a concentration of 5%, adding alkali to adjust the pH to 10, soaking for 10 hours, then centrifuging, and washing the obtained precipitate with water to neutrality to obtain pure chitosan;

[0039] 2) Place the pure chitosan in a water bath at 80°C, and dissolve it in isopropanol with magnetic stirring, then add a modifier and an activator, react at 60°C for 5.5h, then wash with absolute ethanol, and then Place in a dialysis bag for dialysis for 24 hours, concentrate the dialysate and vacuum freeze-dry to obtain chitosan quaternary ammonium salt, the addition of modifier is 38.5% of the weight of pure chitosan, and the addition of activator is pure chitosan. Product chitosan weight 0.45%, wherein the weight ratio of glycolic acid and L-zinc lactate is 1:2;

[0040] 3) Boil the activated carbon in a 5% hydrochlor...

Embodiment 3

[0044] A kind of preparation method of aquaculture fungicide, its concrete steps are as follows:

[0045] 1) dissolving the crude chitosan in glacial acetic acid with a concentration of 3.5%, adding alkali to adjust the pH to 9, soaking for 8.5 hours, then centrifuging, and washing the obtained precipitate with water until neutral to obtain pure chitosan;

[0046] 2) Place the pure chitosan in a water bath at 70°C, and dissolve it in isopropanol with magnetic stirring, then add modifier and activator, react at 75°C for 6.5h, then wash with absolute ethanol, and then Place in a dialysis bag for dialysis for 18 hours, concentrate the dialysate and vacuum freeze-dry to obtain chitosan quaternary ammonium salt, the addition of modifier is 34.5% of the weight of pure chitosan, and the addition of activator is pure chitosan. Product chitosan weight 0.15%, wherein the weight ratio of glycolic acid and L-zinc lactate is 1:1.5;

[0047] 3) Put the activated carbon in a hydrochloric ac...

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Abstract

The invention provides a preparation method of an aquaculture bactericide, and belongs to the technical field of aquaculture. The preparation method includes mixing dispersions of chitosan quaternaryammonium salt in a dispersion medium with activated carbon. A modifier for preparation of the chitosan quaternary ammonium salt is 2,3-epoxypropyltrimethylammonium chloride. Activators are glycolic acid and L-zinc lactate. The bactericide comprises the chitosan quaternary ammonium salt, sodium percarbonate, citric acid, soda ash and modified activated carbon. The preparation method of the aquaculture bactericide provided by the invention is easy in control of operation and less in energy consumption and system operation loss, and the activity of biological raw materials is not destroyed. The prepared bactericide integrates the effects of water quality improvement, disinfection, anti-inflammation and sterilization, has the advantages of no toxic effects, strong ability of catching bacteria,wide application range in acid-alkali environment, good adsorption effect and large amount of bacteria removal per unit, and obviously reduces the amount of the drug and the treatment cost.

Description

technical field [0001] The invention belongs to the technical field of aquaculture, and in particular relates to a preparation method of an aquaculture fungicide. Background technique [0002] With the continuous improvement of the degree of intensification of aquaculture in my country and the sharp increase in the species and density of aquaculture, there are quality problems in aquatic product aquaculture, such as serious pesticide residues, ammonium nitrogen, nitrite, coliform bacteria, pathogenic bacteria and Toxic elements exceed the standard. The widespread use of chemicals such as disinfectants, water quality improvers and algaecides has caused pesticide residues in aquatic products to exceed the standard; a large amount of fertilizer has caused ammonium nitrogen and nitrite in the aquaculture water to exceed the standard. Although chemicals have made great contributions to the development of aquaculture, their long-term use has brought about problems such as environm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N43/16A01N33/12A01N59/00A01N37/36A01P1/00C02F1/28C08B37/08
CPCA01N33/12A01N37/36A01N43/16A01N59/00C02F1/283C08B37/003
Inventor 孙弋博
Owner 金华市呗力水产养殖技术有限公司
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