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Hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production

A modeling method, the technology of hydroiodic acid, applied in the direction of electrical digital data processing, special data processing applications, chemical process analysis/design, etc., can solve problems such as complex processes, and achieve the effect of improving the thermal efficiency of the system

Active Publication Date: 2019-10-18
UNIV OF SHANGHAI FOR SCI & TECH
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Problems solved by technology

[0006] The technical problem to be solved by the present invention is: to overcome the shortcomings of the current sulfur-iodine cycle hydrogen production system with complicated flow

Method used

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  • Hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production
  • Hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production
  • Hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production

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specific Embodiment

[0067] Set the hydroiodic acid electrolysis parameter t + is 0.95, β is 3, and the effective area of ​​the membrane is 0.0025m 2 , the current density is 1.01A / cm 2 . Design and introduce the sulfur-iodide cycle hydrogen production process after the introduction of hydroiodic acid electrolysis, as shown in the attached figure 2 Shown, including the Bunsen reaction unit, sulfuric acid decomposition unit and hydroiodic acid electrolysis unit. The feed to the Bunsen reaction consists of H 2 O, HI, SO 2 , I 2 , and its corresponding feed ratio is n(H 2 O):n(HI):n(SO 2 ):n(I 2 )=58.96:4.16:32.67:4.21. With the goal of hydrogen production of 10L / h, the ELECNTRL method is used globally. The calculated material balance results of the above three units are shown in Table 6-8.

[0068] Table 6 Information of each material flow in the Bunsen reaction unit

[0069]

[0070]

[0071] Information of each material flow in the sulfuric acid decomposition unit in table 7

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Abstract

The invention provides a hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production, and solves the problems of complex sulfur-iodine cycle hydrogen production process and high energy consumption. The method comprises the following steps: establishing a hydroiodic acid electrolysis mathematical model according to a Faraday second law and a massconservation relationship; inputting the model into an EXCEL file to achieve EXCEL modeling; building a hydroiodic acid electrolysis USER2 custom module by means of simulation software Aspen Plus, andassociating the hydroiodic acid electrolysis USER2 custom module with an EXCEL file to realize data interaction; setting relevant parametersreasonably according to an experiment result, and completing debugging through simulation operation of the custom module. Further, the USER2 custom module is connected with a Bunsen reaction unit, a sulfuric acid decomposition unit and other modules; the sulfur-iodine cycle hydrogen production whole process is designed, related material and energy balance calculation and thermal efficiency analysis are carried out according to design requirements, and a guidance scheme is provided for designing and simplifying the whole sulfur-iodine cycle hydrogen production system and improving the thermal efficiency of the system.

Description

technical field [0001] The invention belongs to the technical field of hydrogen production, and relates to a hydroiodic acid electrolytic modeling and process simulation method for sulfur-iodine cycle hydrogen production. Background technique [0002] Hydrogen is a clean and efficient energy source. It is not only widely used in chemical, electronic, and fuel cell industries, but also can be used as an energy storage medium to couple solar energy and wind energy to achieve sustainable supply of renewable energy. my country strongly supports the development of hydrogen energy and fuel cell technology. The current large-scale, renewable and efficient hydrogen production technology has been a research hotspot. [0003] Among many thermochemical cycles to split water to produce hydrogen, sulfur-iodine cycle stands out, which can be coupled with solar energy or nuclear energy, and has outstanding application prospects in the future. The sulfur-iodide circulation system mainly i...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G06F17/50G16C20/10
CPCG16C20/10G06F30/20Y02E60/36
Inventor 应芝郑晓园豆斌林崔国民
Owner UNIV OF SHANGHAI FOR SCI & TECH
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