Hydroiodic acid electrolysis modeling and process simulation method for sulfur-iodine cycle hydrogen production
A modeling method, the technology of hydroiodic acid, applied in the direction of electrical digital data processing, special data processing applications, chemical process analysis/design, etc., can solve problems such as complex processes, and achieve the effect of improving the thermal efficiency of the system
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[0067] Set the hydroiodic acid electrolysis parameter t + is 0.95, β is 3, and the effective area of the membrane is 0.0025m 2 , the current density is 1.01A / cm 2 . Design and introduce the sulfur-iodide cycle hydrogen production process after the introduction of hydroiodic acid electrolysis, as shown in the attached figure 2 Shown, including the Bunsen reaction unit, sulfuric acid decomposition unit and hydroiodic acid electrolysis unit. The feed to the Bunsen reaction consists of H 2 O, HI, SO 2 , I 2 , and its corresponding feed ratio is n(H 2 O):n(HI):n(SO 2 ):n(I 2 )=58.96:4.16:32.67:4.21. With the goal of hydrogen production of 10L / h, the ELECNTRL method is used globally. The calculated material balance results of the above three units are shown in Table 6-8.
[0068] Table 6 Information of each material flow in the Bunsen reaction unit
[0069]
[0070]
[0071] Information of each material flow in the sulfuric acid decomposition unit in table 7
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