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Treatment method and treatment system for spent electroless nickel solution

A treatment system and treatment method technology, applied in the field of purification and treatment of chemical nickel waste liquid, can solve the problems of harsh reaction conditions, poor treatment effect of chemical nickel waste mother liquid, high disposal cost and economic pressure on enterprises, and achieve the effect of mild treatment conditions

Pending Publication Date: 2019-11-19
DONGGUAN KEDA ENVIRONMENTAL PROTECTION ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Chemical nickel wastewater is mainly divided into chemical nickel waste mother liquor and chemical nickel plating cleaning wastewater. The existing chemical nickel wastewater treatment mainly focuses on the treatment of chemical nickel plating cleaning wastewater, but the treatment effect of chemical nickel waste mother liquor is not good. The mixed treatment of waste mother liquor and electroless nickel plating cleaning wastewater will eventually lead to the inability to guarantee the stability of total nickel and total phosphorus in the overall effluent, etc.
The existing technology cannot form a complete process flow for the chemical nickel wastewater discharged from chemical nickel plating. When disposing of part of the cleaning wastewater, the enterprise also needs to outsource some of the high-concentration chemical nickel waste mother liquor. great economic pressure
[0003] In addition, the existing chemical nickel wastewater treatment technology does not clearly classify the sludge after disposal, which is not conducive to the subsequent resource utilization; there is a large amount of ammonia water as a pH buffer in the waste mother liquor of chemical nickel and chemical nickel plating cleaning wastewater. The Fenton reaction method, the reaction conditions are relatively harsh, which not only brings great difficulties to the pH adjustment of the subsequent purification treatment, but also consumes a lot of acid and alkali, and also converts the ammonium ions into ammonia gas and spills into the operating space , the operating environment is relatively harsh, causing certain hazards to the health of operators

Method used

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  • Treatment method and treatment system for spent electroless nickel solution
  • Treatment method and treatment system for spent electroless nickel solution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Such as figure 1 As shown, a treatment system for chemical nickel wastewater includes sequentially connected waste mother liquor pretreatment devices and mixed waste liquid purification devices. The waste mother liquor pretreatment device includes sequentially connected nickel removal electrolytic cells 1, nickel removal reaction precipitation tank 2, nickel removal filter press 3, phosphorus removal reaction precipitation tank 4 and phosphorus removal filter press 5, the liquid outlet of described nickel removal filter press 3 communicates with the liquid inlet of phosphorus removal reaction precipitation tank 4; The mixed waste liquid purification device comprises a waste liquid collection tank 6, a pH adjustment tank 7, a sand filter tank 8, a nickel removal chelating resin tank 9, a phosphorus removal reaction precipitation tank 10 and a phosphorus removal sedimentation tank 11 connected in sequence, and the phosphorus removal The liquid outlet of the filter press 5...

Embodiment 2

[0075] The difference between this embodiment and embodiment 1 is:

[0076] In the step (S1), the waste chemical nickel mother liquor is electrolyzed under the action of 400A current.

Embodiment 3

[0078] The difference between this embodiment and embodiment 1 is:

[0079] In the step (S1), the waste chemical nickel mother liquor is electrolyzed under the action of 550A current.

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Abstract

The invention specifically relates to a treatment method and treatment system for a spent electroless nickel solution, belonging to the technical field of purification and treatment of spent electroless nickel solutions. According to the treatment method, the mother liquid of a spent electroless nickel solution is subjected to pretreatment so as to realize removal and sorted collection of a greatamount of nickel ions and phosphorus ions in the mother liquid of the spent electroless nickel solution, so the concentrations of nickel and phosphorus in the mother liquid of the spent electroless nickel solution are reduced; and then the mother liquid of the spent electroless nickel solution is mixed with cleaning wastewater produced in chemical nickel-plating so as to realize further removal and sorted collection of mixed waste liquid with low nickel ion and phosphorus ion concentrations, so the treatment load of a mixed waste liquid treatment device is reduced, and the stable operation ofthe whole treatment system is guaranteed.

Description

technical field [0001] The invention relates to the technical field of purification and treatment of chemical nickel waste liquid, in particular to a treatment method and system for chemical nickel waste water. Background technique [0002] Chemical nickel wastewater is mainly divided into chemical nickel waste mother liquor and chemical nickel plating cleaning wastewater. The existing chemical nickel wastewater treatment mainly focuses on the treatment of chemical nickel plating cleaning wastewater, but the treatment effect of chemical nickel waste mother liquor is not good. The mixed treatment of waste mother liquor and electroless nickel plating cleaning wastewater eventually leads to the disadvantages that the total nickel and total phosphorus in the overall effluent cannot be stably guaranteed. The existing technology cannot form a complete process flow for the chemical nickel wastewater discharged from chemical nickel plating. When disposing of part of the cleaning was...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/06C02F11/122C02F11/125C25C1/08C22B7/00
CPCC02F9/00C02F11/122C02F11/125C01B25/003C25C1/08C22B7/006C22B23/0461C02F1/461C02F1/66C02F1/5245C02F1/722C02F1/28C02F1/001C02F2303/16Y02P10/20
Inventor 郑方元戴锁堂黄国俭张建华
Owner DONGGUAN KEDA ENVIRONMENTAL PROTECTION ENG
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