A kind of organic compound and its preparation method and application
An organic compound and compound technology, applied in the fields of organic chemistry, chemical instruments and methods, semiconductor/solid-state device manufacturing, etc., can solve the problem of OLED device performance and luminous efficiency decrease, low CBP glass transition temperature, unsatisfactory light-emitting area, etc. To avoid the generation of high-energy excitons, improve the efficiency of energy transfer, and avoid the effect of energy transfer
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[0147] Concrete synthesis method comprises the following steps:
[0148] Synthesis of C'-1: In a 250 ml three-necked flask, A'-1 (28.6 grams, 0.1mol), B'-1 (12.2 grams, 0.1mol), potassium carbonate (16.6 grams, 0.12 mol), toluene (100 ml), water (25 ml), tetrakis(triphenylphosphine)palladium (5.8 g, 0.005 mol), stirred at 100° C. for 10 hours, cooled to room temperature after reaction. The reaction system was added with water, extracted with dichloromethane, and the obtained extract was sequentially added to magnesium sulfate to dry, filtered and spin-dried; the crude product was purified by chromatography (the volume ratio of ethyl acetate / hexane was 1:10) to obtain C'-1 (22 g, 78% yield).
[0149] Synthesis of D'-1: In a 100 ml three-necked flask, add C'-1 (14.1 g, 0.05 mol), cuprous iodide (0.5 g, 2.5 mmol), cesium carbonate (19.6 g, 0.06 mol), 1,4-dioxane (60 milliliters), PAC (5mmol), nitrogen protection, heating and reflux for 20 hours, after the completion of the reac...
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