High-weldability anti-warping thick film conductor paste for stainless steel base material and preparation method of high-weldability anti-warping thick film conductor paste
A technology of conductive paste and stainless steel, applied in the direction of conductive materials dispersed in non-conductive inorganic materials, cable/conductor manufacturing, electrical components, etc., can solve the problem of incomplete contact between thick-film conductors and electronic parts, and reduce the reliability of thick-film conductors Solderability, incomplete contact and other problems, to achieve the effect of inhibiting corrosion, excellent compatibility, and improving adhesion
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Embodiment 1
[0031] This stainless steel substrate is made of highly weldable and anti-warping thick film conductor paste, including 78% by weight of composite conductive powder, 4% of composite lead-free glass powder, and 18% of organic carrier; the composite conductive powder is spherical Mixed powder of silver powder and spherical palladium powder; composite lead-free glass powder is CaO-Al 2 o 3 -SiO 2 -B 2 o 3 -Li 2 O series lead-free glass powder and Bi 2 o 3 -CuO-MnO 2 -Al 2 o 3 -SiO 2 It is a composite powder of lead-free glass powder.
[0032] Further, the weight ratio of silver powder to palladium powder is 95:5.
[0033] Further, the average particle size of the silver powder is 2.0 μm, and the specific surface area is 3~5m 2 / g; the average particle size of palladium powder is 300nm, and the specific surface area is 20~40m 2 / g.
[0034] Further, CaO-Al 2 o 3 -SiO 2 -B 2 o 3 -Li 2 O-based lead-free glass powder includes 22% CaO and 10% Al by weight 2 o 3 ,...
Embodiment 2
[0046] The thick film conductor paste involved in this embodiment is different from the first embodiment in that: the thick film conductor paste includes 80% by weight of composite conductive powder, 1% of composite lead-free glass powder, and 19% of organic Carrier; the composite conductive powder is a mixed powder of spherical silver powder and spherical palladium powder; the composite lead-free glass powder is CaO-Al 2 o 3 -SiO 2 -B 2 o 3 -Li 2 O series lead-free glass powder and Bi 2 o 3 -CuO-MnO 2 -Al 2 o 3 -SiO 2 It is a composite powder of lead-free glass powder.
[0047] Further, the weight ratio of silver powder to palladium powder is 98:2.
[0048] Further, the average particle size of the silver powder is 2.0 μm, and the specific surface area is 3~5m 2 / g; the average particle size of palladium powder is 300nm, and the specific surface area is 20~40m 2 / g.
[0049] Further, CaO-Al 2 o 3 -SiO2 -B 2 o 3 -Li 2 O-based lead-free glass powder includes ...
Embodiment 3
[0055] The thick film conductor paste involved in this embodiment is different from the first embodiment in that: the thick film conductor paste includes 81% by weight of composite conductive powder, 3% of composite lead-free glass powder, and 16% of organic Carrier; the composite conductive powder is a mixed powder of spherical silver powder and spherical platinum powder; the composite lead-free glass powder is CaO-Al 2 o 3 -SiO 2 -B 2 o 3 -Li 2 O series lead-free glass powder and Bi 2 o 3 -CuO-MnO 2 -Al 2 o 3 -SiO 2 It is a composite powder of lead-free glass powder.
[0056] Further, the weight ratio of silver powder to platinum powder is 96:4.
[0057] Further, the average particle size of the silver powder is 2.0 μm, and the specific surface area is 3~5m 2 / g; the average particle size of platinum powder is 300nm, and the specific surface area is 20~40m 2 / g.
[0058] Further, CaO-Al 2 o 3 -SiO 2 -B 2 o 3 -Li 2 O-based lead-free glass powder includes 2...
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Abstract
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