Systems and methods for plasma-less de-halogenation
A plasma and processing system technology, applied in the field of substrate processing systems, which can solve problems such as atomic diffusion, film performance change, dopant profile shift, etc.
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[0028] Systems and methods according to the present invention are used to remove residual halogen species from substrates. The systems and methods described herein use steam at high pressure and temperature to remove residual halogen species, including F, Cl, Br, and / or I. In some examples, deionized water (DIW) is used to generate water vapor. The systems and methods expose the substrate to water vapor at a pressure greater than 10 Torr and elevated temperature (eg, greater than 300° C.) for a predetermined time to enable the water vapor to react with residual halogen species on the surface of the substrate.
[0029] The water vapor is then evacuated from the chamber. After cooling the substrate to a temperature above 100 °C to prevent potential residual water condensation, it was removed from the chamber. Systems and methods according to the present disclosure provide high levels (>90%) of fluorine removal, comparable to wet cleaning methods, while resulting in little mate...
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