Method for improving foam cell retraction behavior of thermoplastic elastomer microcellular foam material

A technology for thermoplastic elastomers and microcellular foaming materials, which is applied in the field of improving the shrinkage behavior of thermoplastic elastomers such as thermoplastic polyurethane microcellular foaming materials. To achieve the effect of maintaining shock absorption and rebound performance, convenient test method, and increased cell density

Pending Publication Date: 2020-09-18
SICHUAN UNIV
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, during the molding process of TPU microcellular foamed materials, we found that there is an obvious phenomenon of unstable cell structure in the process of cell setting: the foaming ratio of the material drops sharply in a short time after the pressure relief is completed, and the cell setting Difficult, the cell shrinkage is serious; resulting in the increase of the density of the TPU foam material and the decrease of the expansion ratio, which greatly limits the performance and application fields of the TPU microcellular foam material
[0003] In response to this problem, most manufacturers of TPU microcellular foaming materials now use secondary foaming techno...

Method used

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  • Method for improving foam cell retraction behavior of thermoplastic elastomer microcellular foam material
  • Method for improving foam cell retraction behavior of thermoplastic elastomer microcellular foam material
  • Method for improving foam cell retraction behavior of thermoplastic elastomer microcellular foam material

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Effect test

Embodiment 1-4

[0036] Experimental raw materials: polyether TPU, brand: DESMOPAN DP.9385AU DPS650; hardness value 86A; provided by Covestro Polymers (China) Co., Ltd.; organically modified nano-montmorillonite (O-MMT), brand: I.44P, modified by dioctadecyl dimethyl ammonium bromide, provided by NANOCOR Co., Ltd. of the United States; CO 2 The gas, with a purity of 99.5%, was provided by Linde Gas (Chengdu) Co., Ltd.

[0037] Sample preparation process:

[0038] First, to remove the influence of moisture, place TPU and O-MMT in a vacuum oven at 80°C for 8 hours to vacuum dry; then, use a twin-screw extruder (machine model: NOE 02213, Nanjing Coperion Technology Co., Ltd. ) extruding the O-MMT masterbatch with a mass fraction of O-MMT of 10wt%, the temperature of the second to tenth sections of the extruder is 175°C, 180°C, 183°C, 185°C, 188°C, 190°C, 193°C, 195°C and 195°C were set sequentially; the die temperature was set to 195°C, and the twin-screw speed was set to 85rpm; then, the mass ...

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Abstract

The invention relates to a method for improving the cell retraction behavior of a thermoplastic elastomer microcellular foam material, and belongs to the field of thermoplastic elastomer microcellularfoaming. The method for inhibiting the cell retraction of the thermoplastic elastomer microcellular foam material is characterized in that nanoparticles are introduced in the process of preparing thethermoplastic elastomer microcellular foam material, and the nanoparticles and the thermoplastic elastomer have a physical bonding or chemical crosslinking effect, thereby inhibiting cell retractionafter foaming of the foam material. The invention aims to provide the method for conveniently and efficiently improving the cell retraction behavior of the thermoplastic elastomer from the perspectiveof a molecular chain, and the problem of cell retraction of the thermoplastic elastomer is fundamentally solved.

Description

technical field [0001] The invention relates to a method for improving the cell retraction behavior of thermoplastic elastomers such as thermoplastic polyurethane microcellular foaming materials, and belongs to the field of thermoplastic elastomer microcellular foaming. Background technique [0002] Thermoplastic elastomers such as thermoplastic polyurethane (TPU) use carbon dioxide (CO 2 ) foaming method to prepare the microporous foam material, which has excellent shock absorption and resilience performance and wear resistance, and is widely used in shoe material production and tire preparation; the most representative ones are German Adidas and BASF companies The jointly developed Boost series of running shoes, for the first time, applied the infinergy of TPU foam particles in the production and preparation of the midsole of running shoes; the sole of this kind of running shoes not only has excellent shock absorption and resilience performance and wear resistance, but als...

Claims

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Application Information

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IPC IPC(8): C08L75/08C08K9/04C08K3/34C08J9/12
CPCC08J9/008C08J9/122C08J2203/06C08J2203/08C08J2375/08C08K3/346C08K9/04C08K2201/011
Inventor 杨其龚鹏剑蓝滨
Owner SICHUAN UNIV
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