Organic light emitting diode and organic light emitting device including same
A light-emitting diode and organic technology, applied in the direction of light-emitting materials, chemical instruments and methods, electric solid-state devices, etc., can solve the problems of inapplicability, short light-emitting life of metal complexes, etc.
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Embodiment 1
[0236] Embodiment 1 (Ex.1): Manufacturing OLED
[0237] An OLED was produced comprising introducing mCBP (LUMO-2.5eV; HOMO-6.0eV) as a host, Compound 1-1 in Chemical Formula 2 (LUMO-3.0eV; HOMO-5.7eV) as a delayed fluorescence material (DF) and Compound 2-1 (LUMO-3.6eV; HOMO-5.8eV) in Chemical Formula 4 as a fluorescent material (FD). The ITO substrate was cleaned by UV-ozone treatment before use, and then transferred to a vacuum chamber to deposit the emissive layer . Subsequently, at 10 -7 Under the condition of Torr vacuum, and set the deposition rate as The anode, emissive layer and cathode were deposited by evaporation from a heated boat in the following order:
[0238] Anode (ITO, 50nm); HIL (HAT-CN, 7nm); HTL (NPB, 78nm); EBL (TAPC, 15nm); EML (mCBP: Compound 1-1: Compound 2-1=64:35:1( weight ratio), 35nm); HBL (B3PYMPM, 10nm); ETL (TPBi, 25nm); EIL (LiF);
[0239] Then, a cover layer (CPL) is deposited on the cathode and the device is encapsulated with glass. A...
Embodiment 2
[0240] Embodiment 2 (Ex.2): Manufacturing OLED
[0241] OLEDs were fabricated using the same materials as in Example 1, except that Compound 1-2 (LUMO-3.1eV; HOMO-5.7eV) in Chemical Formula 2 was used instead of Compound 1-1 as a delayed fluorescence material in EML. LUMO FD –LUMO DF =-0.5eV; HOMO FD –HOMO DF = -0.1eV.
Embodiment 3
[0242] Embodiment 3 (Ex.3): manufacture OLED
[0243] OLEDs were fabricated using the same materials as in Example 1, except that Compound 1-17 (LUMO-3.1eV; HOMO-5.9eV) in Chemical Formula 2 was used instead of Compound 1-1 as a delayed fluorescence material in EML. LUMO FD –LUMO DF =-0.5eV; HOMO FD –HOMO DF = -0.1eV.
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