Polypropylene composite material and preparation method

A technology of composite materials and polypropylene, which is applied in the field of polypropylene composite materials and its preparation, can solve the problem of ghost image appearance, the difficulty of effectively solving the injection molding process, and no good solutions have been found.

Active Publication Date: 2021-04-27
CHENGDU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ghost appearance defect is a relatively common appearance defect of injection molded parts. Ghost appearance defect is the appearance difference caused by the temperature, pressure or shrinkage mutation of the material during the molding process. In the injection molding process, it is often used to reduce the holding pressure and time. , reduce the pressure at the injection end or increase the injection speed, and increase the mold temperature or reduce the material temperature to reduce the degree of ghosting as much as possible, but the actual effect is very limited, especially now that the automotive interior grains have changed from ordinary rough grains to fine grains. There is a tendency for the grains (usually texture depth ≤ 100 μm) to develop towards the direction of geometric grains (usually the depth of grain textures > 100 μm). The deeper the grains, the greater the possibility of ghost appearance defects on the surface of injection molded parts. Therefore, Deep geometric leather parts often encounter ghost appearance problems during injection molding and cannot be effectively solved
[0003] Ghost defect is a nightmare for the appearance of injection molded parts. Not only is it difficult to effectively solve it in the injection molding process, but also in the material formula, there has been no good solution before, and there are almost no relevant reports in the literature.

Method used

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  • Polypropylene composite material and preparation method
  • Polypropylene composite material and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A preparation method of polypropylene composite material, comprising the following steps:

[0040] By weight, 60 parts of polypropylene PP-1, 20 parts of talcum powder, 20 parts of POE 8137, 0.3 parts of A-C540; 0.3 parts of TR451; 0.2 parts of antioxidant 1010, 0.2 parts of antioxidant 168, 0.2 parts of LA- 402AF and 0.2 parts of BS-3818 are mixed evenly in the mixing equipment, mixed evenly in the high mixer, and then added to the twin-screw extruder with a length-to-diameter ratio of 40:1, and there are 12 sections in the twin-screw extruder Screw barrel, the first section of the screw barrel is the feeding port, and an independent vacuum device is installed in multiple places at the rear end of the screw barrel. The vacuum degree is required to be below -0.08MPa. ℃, 180℃, 185℃, 190℃, 195℃, 200℃, 205℃, 210℃, 215℃, 220℃, 225℃, 230℃, 235℃, 240℃. After melting and kneading, extrude, granulate, cool and dry to obtain a polypropylene composition.

Embodiment 2

[0042] A preparation method of polypropylene composite material, comprising the following steps:

[0043] By weight, 50 parts of polypropylene PP-1, 25 parts of talcum powder, 25 parts of POE 7447, 0.4 part of erucamide; 0.2 part of TR451; 0.2 part of antioxidant 1010, 0.2 part of antioxidant 168, 0.2 part of LA- 402AF and 0.2 parts of BS-3818 are mixed evenly in the mixing equipment, mixed evenly in the high mixer, and then added to the twin-screw extruder with a length-to-diameter ratio of 40:1, and there are 12 sections in the twin-screw extruder Screw barrel, the first section of the screw barrel is the feeding port, and an independent vacuum device is installed in multiple places at the rear end of the screw barrel. The vacuum degree is required to be below -0.08MPa. ℃, 180℃, 185℃, 190℃, 195℃, 200℃, 205℃, 210℃, 215℃, 220℃, 225℃, 230℃, 235℃, 240℃. After melting and kneading, extrude, granulate, cool and dry to obtain a polypropylene composition.

Embodiment 3

[0045] A preparation method of polypropylene composite material, comprising the following steps:

[0046] By weight, 60 parts of polypropylene PP-1, 15 parts of talcum powder, 25 parts of POE 8137; 0.2 parts of antioxidant 1010, 0.2 parts of antioxidant 168, 0.2 parts of LA-402AF and 0.2 parts of BS-3818 in the mixing equipment Mix evenly in the high mixer, and then add it to the twin-screw extruder with the aspect ratio of 40:1. There are 12 screw barrels in the twin-screw extruder, and the first screw barrel is the following At the feed port, independent vacuuming devices are installed in multiple screw barrels at the rear end, and the vacuum degree is required to be below -0.08MPa. The temperatures of the first section to the 12th section are 170°C, 180°C, 185°C, and 190°C respectively. , 195°C, 200°C, 205°C, 210°C, 215°C, 220°C, 225°C, 230°C, 235°C, 240°C. After melting and kneading, extrude, granulate, cool and dry to obtain a polypropylene composition.

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Abstract

The invention belongs to the field of polypropylene composite material modification, and particularly relates to a polypropylene composite material and a preparation method thereof. The composite material comprises the following components in parts by weight: 30-80 parts of high molecular weight co-polypropylene; 5-40 parts of a filler; 10-30 parts of an elastomer; and 0.4-1 part of a lubricant. The preparation method comprises the following steps of: uniformly mixing the high molecular weight polypropylene, the filler, the elastomer, the lubricant and a processing aid in a mixing device, adding the mixture into an extruder, carrying out melt mixing at 170-240 DEG C, granulating, cooling and drying to obtain the polypropylene composition. The obtained composition has a good appearance effect, and particularly, meets the use requirements of deep geometric dermatoglyph automobile parts.

Description

technical field [0001] The invention belongs to the technical field of modification of polypropylene composite materials. More specifically, it relates to a polypropylene composite material and a preparation method. Background technique [0002] In recent years, with the development of the automobile industry, more and more plastic materials have been used in the interior and exterior parts of automobiles. Among them, polypropylene materials occupy the leading position in automobiles due to their excellent comprehensive performance, wide range of sources, high quality and low price. Use larger proportions of plastics. With the improvement of people's living standards, consumers are paying more and more attention to details such as the appearance of interior and exterior parts of automobiles. Ghost appearance defect is a relatively common appearance defect of injection molded parts. Ghost appearance defect is the appearance difference caused by the temperature, pressure or ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L23/08C08L23/06C08K13/02C08K3/34C08K5/20C08K5/098C08K5/134C08K5/526
CPCC08L23/14C08L2205/02C08L2205/03C08K2201/014C08L23/0815C08K13/02C08K3/34C08K5/20C08K5/1345C08K5/526C08K5/098C08L23/06
Inventor 陈锐黄险波叶南飚陈延安吴国峰
Owner CHENGDU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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