Water-based steel drum coating as well as preparation process and application thereof
A water-based, steel drum technology, applied in epoxy resin coatings, coatings, and devices for coating liquid on the surface, can solve problems such as long drying time, poor flatness and bonding force, and high energy consumption, and achieve high Abrasion resistance and retort resistance, rapid baking improvement, high surface flatness effect
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[0055] The invention discloses a preparation process of water-based steel drum paint, comprising the following steps:
[0056] S1: Preparation of epoxy-modified acrylic resin;
[0057] Specifically, the preparation process of self-made epoxy-modified acrylic resin described in step S1 is as follows:
[0058] S11: Preparation of primer: prepare 15-20 parts of ethylene glycol butyl ether, dissolve 35-45 parts of Nantong Xingchen 901 solid epoxy resin into an epoxy solution, then add 18-30 parts of acrylic acid monomer, mix it as a primer spare;
[0059] S12: Preparation of monomer mixed solution: 17-30 parts of styrene, 45-65 parts of butyl acrylate, 5-15 parts of methyl methacrylate, 1-5 parts of hydroxypropyl acrylate, 3-5 parts of peroxide 2 - tert-butyl ethylhexanoate (TBPO) initiator and 10-20 parts of propylene glycol methyl ether solvent are mixed to form a mixed solution;
[0060] S13: Prepare other materials: 0.2-1.0 parts of tert-butyl peroxide 2-ethylhexanoate (TBP...
Embodiment 1
[0068] Including the following processes:
[0069] S11: Preparation of primer: prepare 18 parts of ethylene glycol butyl ether, dissolve 42 parts of Nantong Xingchen 901 solid epoxy resin into an epoxy solution, add 25 parts of acrylic acid monomer, mix and use as a primer for later use;
[0070] S12: Preparation of monomer mixed solution: 24 parts of styrene, 55 parts of butyl acrylate, 10 parts of methyl methacrylate, 3 parts of hydroxypropyl acrylate, 4.2 parts of tert-butyl peroxide 2-ethylhexanoate initiator And 12 parts of propylene glycol methyl ether solvents are mixed to make mixed solution;
[0071] S13: Prepare other materials: 0.4 parts of tert-butyl peroxide 2-ethylhexanoate initiator, 0.8 parts of propylene glycol methyl ether solution as supplementary initiator, 10 parts of n-butanol, and 32.4 parts of ethylene glycol butyl ether as diluent , 2.6 parts of dimethylethanolamine as a neutralizing agent;
[0072] S14: stirring and mixing:
[0073] S141: heat up t...
Embodiment 2
[0098] S21: Preparation of epoxy solution: heat 4.6 parts of ethylene glycol butyl ether and 8.6 parts of Nantong Xingchen 850S epoxy resin to 45°C under stirring, and dissolve to make an epoxy solution;
[0099] S22: Pre-dissolving: 0.87 parts of 85% phosphoric acid, 0.4 parts of deionized water and 0.8 parts of ethylene glycol butyl ether are pre-dissolved at room temperature;
[0100] S23: Prepare other materials: prepare 3.7 parts of ethylene glycol butyl ether and 1 part of dimethylethanolamine;
[0101] S24: Phosphating:
[0102] S241: Add the epoxy solution prepared in step S22 to the pre-dissolved material in step S21, raise the temperature to 60°C for 1 hour, then raise the temperature to 100°C-110°C within 1 hour, and keep the temperature for 3 hours;
[0103] S242: Cool to 50°C after adding 3.3 parts of ethylene glycol butyl ether;
[0104] S243: Add 1 part of dimethylethanolamine and 0.4 part of ethylene glycol butyl ether, and stir evenly to prepare water-solubl...
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