Activated carbon capping disposal method for heavy metal pollution dredged materials
A disposal method, heavy metal technology, applied in the field of marine pollution control, to achieve the effect of simple operation, reduced consumption, and improved disposal effect
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Embodiment 1
[0038] Preparation of heavy metal polluted dredged materials.
[0039] Three typical heavy metals, Cu, Pb and Cd, were selected as target pollutants for capping disposal research. In order to meet the experimental requirements, using Cd(NO 3 ) 2 4H 2O, Pb(NO 3 ) 2 and Cu(NO 3 ) 2 ·3H 2 O dissolved in deionized water to make a concentration of 10mg L -1 , 500mg L -1 and 400mg L -1 A mixed solution of Cd, Pb and Cu was used to prepare polluted dredging. Put the dry dredged material (about 700g) in the device, then slowly pour the above heavy metal mixture until the dredged material is completely soaked, and let it stand for 3 days.
Embodiment 2
[0041] The construction of cap experiment apparatus.
[0042] Build a small cap experiment setup, such as image 3 As shown, activated carbon is used as the capping material to simulate the in-situ capping disposal of polluted dredged materials. The construction situation is as follows:
[0043] 1) The experimental device is an acrylic cylindrical device with an inner diameter of 8 cm and a height of about 47 cm. The device is provided with an overlying water sampling port for collecting overlying water samples during the capping experiment;
[0044] 2) The construction process of the capping experimental device is as follows: firstly, a certain thickness of polluted dredging material (about 17 cm in thickness) is placed in the capping device, and then activated carbon with a thickness of 2 cm is placed on the device. Ionized water reaches the height of the device at about 43cm;
[0045] 3) Set a group of exposure groups without restoration materials as the control group;
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Embodiment 3
[0049] To test the effect of activated carbon in situ capping on the release of heavy metals from polluted dredged materials.
[0050] The capping experiment lasted for 50 days, and samples were collected regularly through the overlying water sampling port. The collected samples were filtered through a 0.45 μm filter membrane and the content of heavy metals was determined using an atomic absorption spectrophotometer. The retardation was analyzed by comparing the difference in the concentration of heavy metals in the overlying water between the exposure group and the activated carbon capping group.
[0051] Such as Figure 4~6 Shown are the changes in the concentration of Cu, Pb and Cd in the overlying water of the exposure group and the activated carbon capping device group during the capping experiment.
[0052] according to Figure 4 , for Cu, during the capping experiment, the Cu concentration in the overlying water of the exposure group rose slowly and fluctuated, and t...
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