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High nickel electrode sheet with reduced moisture reactivity and method of making same

A technology of electrode sheet and positive electrode mixture, applied in the field of high-nickel electrode sheet with reduced moisture reactivity and its manufacturing, can solve the problems of insufficient battery life and difficulty in achieving energy density, and achieve improved life characteristics and increased capacity The effect of the characteristic

Pending Publication Date: 2022-03-01
LG ENERGY SOLUTION LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the conventional technology has the effect of inhibiting lithium precipitation, but it is not enough to improve the life of the battery, and the nickel content of the second positive electrode active material coated on both ends is only 20 to 40%, so it is difficult to achieve the required energy density

Method used

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  • High nickel electrode sheet with reduced moisture reactivity and method of making same
  • High nickel electrode sheet with reduced moisture reactivity and method of making same
  • High nickel electrode sheet with reduced moisture reactivity and method of making same

Examples

Experimental program
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Effect test

no. 1 approach

[0065] In the electrode sheet according to the first embodiment of the present invention, the second positive electrode mixture layer includes the first positive electrode active material and the second positive electrode active material, and the first positive electrode mixture layer can be made of the same average particle diameter D 50 positive electrode active material.

[0066] At this time, the average particle diameter D of the positive electrode active material of the first positive electrode mixture layer 50 It may be 9 to 30 μm, preferably 9 to 25 μm, more preferably 10 to 20 μm. In addition, it may be the same as the average particle diameter of the first positive electrode active material of the second positive electrode mixture layer.

no. 2 approach

[0068] In the electrode sheet according to the second embodiment of the present invention, the second positive electrode mixture layer may include the first positive electrode active material and the second positive electrode active material, and the first positive electrode mixture layer may include large particles like the second positive electrode mixture layer. A mixture of a first positive electrode active material with a small particle size and a second positive electrode active material with a small particle size.

[0069] At this time, in order to make the second positive electrode mixture layer stronger than the first positive electrode mixture layer in roll pressing, the weight (b) of the second positive electrode active material in the second positive electrode mixture layer is equal to the weight of the first positive electrode active material. The ratio (b / a) of the weight (a) is greater than the ratio (b' / a') of the weight (b') of the second positive electrode act...

Embodiment 1

[0102] (Preparation of the first positive electrode slurry for forming the first positive electrode mixture layer)

[0103] Prepare the first positive electrode active material (D 50 11 μm) as lithium-nickel-cobalt-manganese transition metal oxide, which is then mixed with carbon black conductive material and PVDF binder at a weight ratio of 96.5:1.5:2 in N-methylpyrrolidone solvent to manufacture The first positive electrode slurry (viscosity: 7000 Pa·s).

[0104] (Preparation of the second positive electrode slurry for forming the second positive electrode mixture layer)

[0105] The first positive electrode active material (D 50 is 11 μm) and the second positive electrode active material (D 50 6 μm) in a ratio of 8:2 to prepare a positive electrode active material, which is mixed with carbon black conductive material and PVDF binder in a ratio of 96.5:1.5:2 in N-methylpyrrolidone solvent to form The second positive electrode slurry (viscosity: 7000 Pa·s).

[0106] (Pre...

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Abstract

In the present invention, during the storage of a high-nickel-content electrode sheet, a second positive electrode mixture slurry is applied to both edge regions of an electrode sheet holding part, in which the edge regions are easily permeated by moisture and have a high rate of roll-in reduction. The positive electrode active material contained in the slurry is more resistant to rolling than the positive electrode active material applied to the central region of the holding part, thereby suppressing reactivity of nickel and moisture as much as possible, thereby improving life characteristics of the battery.

Description

technical field [0001] This application claims priority based on Korean Patent Application No. 10-2020-0054235 filed on May 7, 2020 and Korean Patent Application No. 10-2021-0049862 filed on April 16, 2021, the contents of which are not incorporated herein as a part of this specification. [0002] The present invention relates to a positive electrode sheet containing a positive electrode active material with a high nickel content and a manufacturing method thereof, and more particularly, relates to a slurry capable of coating a second positive electrode mixture by coating the two edge regions of the electrode sheet coating part. An electrode sheet for suppressing reactivity with moisture and a method for manufacturing the electrode sheet, wherein the second positive electrode mixture slurry includes a positive electrode active material having a rolling-resistant particle strength, compared with the central portion of the coating portion , the edge region is easily penetrated ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/13H01M4/139H01M4/505H01M4/525
CPCH01M4/13H01M4/139H01M4/525H01M4/505H01M4/131H01M4/1391Y02E60/10H01M10/0404H01M10/0525H01M4/0404H01M4/0435H01M4/0471H01M2004/021H01M2004/028
Inventor 韩松伊柳志勋
Owner LG ENERGY SOLUTION LTD