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Methanol liquid phase reforming hydrogen production device and method and power supply system

A liquid phase reforming and hydrogen production device technology, applied in chemical instruments and methods, solar heating systems, hydrogen, etc., can solve the problems of increased risk, complex internal structure and processing technology, and high risk, so as to improve safety , Simple structure, good load-bearing effect

Active Publication Date: 2022-05-27
河北氢联新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the built-in solar vacuum heat collector is filled with Cu@C catalyst as a hydrogen production reaction tube. The internal structure and processing technology are very complicated, which is not conducive to later maintenance and replacement of the catalyst, and the service life is short.
Moreover, the glass used in the solar vacuum heat collecting tube is easy to be damaged due to changes in cold and hot temperatures or impact, which is more dangerous.
In addition, due to the use of the gravity of the closed high-level tank to ensure the automatic feeding of methanol water, in order to maintain this gravity, the high-level tank needs to be fixed at a higher position, so the requirements for the size and installation location of the entire hydrogen production device are higher. , and increased risk

Method used

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  • Methanol liquid phase reforming hydrogen production device and method and power supply system
  • Methanol liquid phase reforming hydrogen production device and method and power supply system
  • Methanol liquid phase reforming hydrogen production device and method and power supply system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0075] use figure 1 In the methanol liquid-phase reforming hydrogen production device of the embodiment shown, the coil P is serpentine, and the coils P of the first solar flat panel heat collector 20 and the second solar flat panel heat collector 30 are connected in series. The methanol aqueous storage tank 10 stores a mixed solution of methanol and deionized water prepared in advance, and the concentration of the solution is 45 wt%. Provide methanol aqueous solution with a predetermined pressure of 2.0MPa, the first solar flat panel heat collector 20 is set to heat the methanol aqueous solution to 40°C, the second solar flat panel heat collector 30 is set to heat the methanol aqueous solution to 150°C, and the catalyst is Pt / α-MoC. The gas produced by the liquid phase reforming is hydrogen with a CO content of 91ppm, and the gas pressure is 2.0MPa.

Embodiment 2

[0077] use figure 2 In the methanol liquid-phase reforming hydrogen production device of the embodiment shown, the coil P is serpentine. The concentration of the solution stored in the aqueous methanol storage tank 10 is 50 wt%, and the aqueous methanol solution is supplied at a predetermined pressure of 5.0 MPa. The two first solar flat panel heat collectors 20 are set to heat methanol aqueous solution to 80°C and 150°C, the second solar flat panel heat collector 30 is set to heat methanol aqueous solution to 190°C, and the catalyst is Cu@C. The gas produced by the liquid phase reforming is hydrogen with a CO content of 79ppm, and the gas pressure is 5.0MPa.

Embodiment 3

[0079] use image 3 In the methanol liquid-phase reforming hydrogen production device of the embodiment shown, the coil P is in a spiral shape. The concentration of the solution stored in the aqueous methanol storage tank 10 is 55 wt%, and the aqueous methanol solution is supplied at a predetermined pressure of 7.0 MPa. The first solar flat panel heat collector 20 is set to heat the aqueous methanol solution to 130°C, the second solar flat panel heat collector 30 is set to heat the aqueous methanol solution to 210°C, and the catalyst is Cu / ZnO / Al 2 o 3 . The gas produced by the liquid phase reforming is hydrogen with a CO content of 77ppm, and the gas pressure is 7.0MPa.

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Abstract

The invention discloses a methanol liquid phase reforming hydrogen production device and method and a power supply system, the methanol liquid phase reforming hydrogen production device comprises a methanol aqueous solution providing part, a preheating part and a reaction part, the preheating part comprises a first solar flat plate collector (20), and the reaction part comprises a second solar flat plate collector (30). The first solar flat plate collector comprises a first working medium flow channel (21), the methanol aqueous solution supply part is used for conveying a methanol aqueous solution with preset pressure to the first working medium flow channel, the second solar flat plate collector comprises a second working medium flow channel (31), an inlet of the second working medium flow channel is communicated with the first working medium flow channel, and an outlet of the second working medium flow channel is communicated with the second working medium flow channel. And the second working medium flow channel (31) is suitable for being filled with a catalyst for methanol liquid phase reforming hydrogen production. The methanol liquid phase reforming hydrogen production device is simple in structure and low in cost, and a head tank or an installation site does not need to be arranged or considered.

Description

technical field [0001] The present application relates to the field of methanol hydrogen production, and more specifically, relates to a methanol liquid-phase reforming hydrogen production device and method and a power supply system. Background technique [0002] The utilization and development of renewable energy is an important way to deal with the depletion of fossil energy and environmental pollution. Among them, solar energy is widely distributed, with unlimited reserves, clean and pollution-free during the mining and utilization process, hydrogen energy has high quality and energy density, high energy storage efficiency, and almost zero carbon emissions during use. Therefore, the comprehensive utilization of both solar energy and hydrogen energy is of great significance. [0003] In recent years, the use of solar heat collection for methanol reforming to produce hydrogen has been more in-depth research. Currently known methanol reforming hydrogen production is mainly...

Claims

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Application Information

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IPC IPC(8): C01B3/32H01M8/0612F24S70/20F24S10/75
CPCC01B3/323H01M8/0618F24S10/755F24S70/20C01B2203/0233C01B2203/0866C01B2203/0838C01B2203/1064C01B2203/1041C01B2203/1047C01B2203/1058C01B2203/1076C01B2203/1082C01B2203/1223C01B2203/84Y02E10/44Y02P20/133
Inventor 李孟赫刘社田
Owner 河北氢联新能源科技有限公司
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