Laser imaged printing plates comprising multi-layer slip film
A laser imaging, printing plate technology, applied in the printing plate field, can solve the problems of unstable optical components, easy damage, expensive lasers, etc.
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Embodiment 1
[0063] Preparation of UV absorber-modified polyamide sliding films for flexographic printing plates
[0064] Conventional sliding films are modified with UV absorbers to make films opaque to actinic radiation. Nitrocellulose, an autoxidizing adhesive, is also added to enhance the mask's sensitivity to laser ablation. The masks used had the approximate composition of the dried films in Table 3.
[0065] Material
% by weight (solution)
% by weight (dry)
Uvinul3050 (5% ethanol)
39.5
19.6
RS Nitrocellulose (10% solvent mix)
49.4
49.1
Versamid744 (30% nBuOH)
8.90
26.4
Ingrasperse Black R-U (23%)
2.11
4.9
total
100
100
[0066] The above ingredients were hand poured onto a clean PET cover slip such as Melinex 453, available from Du Pont PET (Hopewell, VA) to obtain a thickness of approximately 2-4 μm (dry). membrane. A regular Flex-Light KOR 0.067" plate (Polyester Technolog...
Embodiment 2
[0069] Polyamide slip modified with UV absorbers and IR absorbers for flexographic printing plates Preparation of moving membrane
[0070] An IR absorbing dye, ADS 830A, available from American Dye Source (Montreal, Canada), was added to the UV absorber modified mask of Example 1. The mask absorbs 99.9% of actinic radiation. Through the addition of an IR absorbing dye, the mask is made sensitive to an IR laser operating at a wavelength of 830nm, which is typically used in flexo plate setters. The mask used had the approximate composition of the dried film in Table 4:
[0071] Material
% by weight (solution)
% by weight (dry)
ADS 830 A (2% solvent)
30.34
7.0
Uvinul 3050 (5% ethanol)
31.55
18.2
RS Nitrocellulose (10% solvent mix)
24.27
45.6
Versamid 744 (30% nBuOH)
12.13
24.6
Ingrasperse Black R-U dye (23%)
1.71
4.6
total
100
100
[0072] The solutions o...
Embodiment 3
[0076] Preparation of Multilayer Mask Coatings for Flexographic Printing Plates
[0077] In order to overcome the drawbacks described in Example 2, a multilayer coating was used as the sliding film. see Figure 1-2 , the multilayer sliding film 12 includes an ultraviolet absorbing layer 14 and an infrared absorbing layer 16 . The UV absorbing layer 14 absorbs 99.9% of actinic UV radiation. The ultraviolet absorbing layer 14 had the approximate composition of the dry film in Table 5 and a thickness of about 1-1.5 µm. The infrared absorbing layer 16 is located below the ultraviolet absorbing layer 14 and adjacent to the photocurable layer 18 . The infrared absorbing layer 16 is designed to be sensitive to IR laser light operating at a wavelength of 830nm, which is typically employed in flexo plate setters. The presence of a contrast dye in the UV absorbing layer 14 allows for image contrast in the final laser imaged plate. The infrared absorbing layer 16 had the approximate...
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