The present invention belongs to the technical field of
polymer materials, relates to the modification of waterborne
polyurea, and particularly relates to a preparation method of an internally crosslinked modified waterborne
polyurea with terminal carboxyl hyperbranched
polyamide, comprising: dissolving polyisocyanate in a
solvent, heating to 90-140°C, adding a catalyst and a coreless terminal carboxyl hyperbranched
polyamide, and keeping warm for 1-4 h; adjusting the temperature to 105-160°C, adding a waterborne chain
extender and a
polyol, and keeping warm for 2-6 h; cooling to 60-90°C, adjusting the pH to 7.0-7.3 with a neutralizing agent, increasing the stirring rate and quickly adding deionized water for dispersion to obtain the product. The
solid content of the modified waterborne
polyurea prepared by the present invention is 40.3-42.7%, and it can be applied to roll
coating, knife
coating or spraying such as intaglio printing,
relief printing, flexographic printing, etc. Since the hyperbranched
polyamide molecule has cavities and more branched chain gaps, the modified waterborne polyurea can further bond / chelate
small molecule compounds or be used as a
drug carrier, and its application value in the medical field cannot be underestimated.