Process for producing sand alumina by Bayer precipitation process

A technology of alumina and Bayer method, applied in the preparation of alumina/hydroxide, alkali metal aluminate/alumina/aluminum hydroxide, etc., can solve the problems of large amount of production, low product strength, and large flying loss

Inactive Publication Date: 2005-03-16
GUIZHOU BRANCH CHINA ALUMINUM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When dealing with diaspore type bauxite, higher alkali concentration and dissolution temperature are required. At the same time, in order to reduce energy consumption and improve decomposition rate, it is also required to have a higher concentration of alumina in the decomposed raw solution and a larger caustic ratio of the mother liquor; in order to To achieve the required decomposition rate, the required decomposition time is prolonged, so that the particle size and strength of the product are difficult to guarantee
Using diaspore as raw material to produce alumina, the existing production process adopts the Bayer method semen to add aluminum hydroxide as a seed crystal, maintain a relatively low initial decomposition temperature for natural decomposition, and the final decomposition temperature is low, and the produced Alumina has poor strength and fine particle size. After roasting, most of its products are powdery and intermediate alumina.
Compared with sandy alumina, powdery or intermediate alumina has a small specific surface area, poor dissolution rate in electrolytes and poor ability to absorb hydrogen fluoride, high fine particle content, low product strength, and particle breakage during transportation Seriously, a large amount of fine particles are produced, resulting in large flying losses

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] The alumina concentration of the Bayer process semen is 140g / l, and the caustic ratio is 1.45. Under the condition that 400g / l aluminum hydroxide is added as the seed crystal in the first tank of the agglomeration, the agglomeration temperature is 76°C. After 10 hours of agglomeration, after a rapid cooling in the middle The temperature is 65°C, and then after 50 hours of natural cooling and decomposition to the final temperature of 48°C, after the aluminum hydroxide product is roasted, the physical properties of the alumina are: the wear index is 16, and the particle content of -45μm is 10%.

Embodiment 2

[0014] The alumina concentration of the Bayer process semen is 160g / l, the caustic ratio is 1.45, under the condition of adding 300g / l aluminum hydroxide as the seed crystal in the first tank of the agglomeration, the initial decomposition temperature is kept at 65°C, and after 6 hours of agglomeration, the temperature is dropped rapidly in the middle The final temperature is 55°C, and then after 50 hours of natural cooling and decomposition to the final temperature of 48°C, after the aluminum hydroxide product is roasted, the physical properties of alumina are: wear index 17, -45μm particle content is 6%.

Embodiment 3

[0016] The alumina concentration of the Bayer process semen is 155g / l, and the caustic ratio is 1.45. Under the conditions of adding 100g / l aluminum hydroxide as a seed crystal in the first tank of the agglomeration, the initial temperature of the agglomeration is 80°C, the agglomeration time is 10 hours, and after the intermediate cooling, The initial temperature of the long section is 65°C, the amount of seed crystals added in the first groove of the long section is 500g / l, and then after 50 hours of natural cooling and decomposition to the final temperature of 50°C, after the aluminum hydroxide product is roasted, the physical properties of alumina are : Wear index 16, -45μm particle content 8%.

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Abstract

The invention discloses a pocess for producing sand alumina by Bayer precipitation process which consists of, charging seed crystal into refined aluminum oxide solution in one or two times for decomposition, separating the obtained decomposition product by grades, returning the seed crystal back to decomposition process, subjecting the aluminum hydroxide product to filtering, scouring, drying, and sintering to obtain the sand form aluminum oxide product.

Description

technical field [0001] The invention discloses a method for producing sandy alumina by seed separation by the Bayer method, which involves using diaspore-type bauxite as a raw material, and performing Bayer method seed decomposition to produce sandy alumina by using a hybrid process or a pure Bayer process method. Background technique [0002] The production of alumina in my country mainly uses insoluble diaspore bauxite as raw material. Compared with the easy-to-handle gibbsite bauxite widely used abroad, the process conditions and technologies There are large differences in indicators and so on. When dealing with diaspore type bauxite, higher alkali concentration and dissolution temperature are required. At the same time, in order to reduce energy consumption and improve decomposition rate, it is also required to have a higher concentration of alumina in the decomposed raw solution and a larger caustic ratio of the mother liquor; in order to To achieve the required decomp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/04C01F7/30
Inventor 郭声琨熊维平孙兆学顾松青丁安平马达卡李旺兴李少康梁春来张吉龙李光柱赵培生赵清杰孟杰李文化郭晋梅王天庆康智明董保才于斌娄士斌张学超
Owner GUIZHOU BRANCH CHINA ALUMINUM IND
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