Developer for use with carbonless copy paper and photo imaging system
a technology of carbonless copy paper and developer, applied in the field of color developer composition, can solve the problems of fading of the image, discoloration is a very undesirable attribute, and resins are somewhat colored materials,
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example 2
[0027] Molecular Sieve
[0028] 20.0 g of a C.sub.16H.sub.33(CH.sub.3).sub.3NCl / OH solution (prepared as in Example #1) was mixed with 0.42 g of NaAlO.sub.2. Then 10.0 g of a 25% tetramethylammoniumsilicate solution (Aldrich) was added to the mixture. This addition was followed by 2.5 g of fumed silica (Aldrich). The resulting mixture was placed in a 125 mL closed Parr Reactor and heated for 24 hours at 120.degree. C. The mixture was then filtered and washed with water. The solid was dried at 120 .degree. C. The dried solid was then treated with a 10% HNO.sub.3 solution over night. Following the acid treatment the sample was filtered and washed with water and dried at 120.degree. C. A heat treatment of the material was then carried out by heating the sample in a tube furnace under N.sub.2 flow at 450.degree. C. followed by heating in air for 3 hours. The sample was then transferred to an oven and was heated at 500.degree. C. in air for 8 hrs. The sample was tested via the spot method a...
example 3
[0029] Molecular Sieve
[0030] 20.0 g of a C16H.sub.33(CH.sub.3).sub.3NCl / OH solution (prepared as in Example #1) was mixed with 0.68 g of ZnCl.sub.2, 10.0 g of a 25% tetramethylammoniumsilicate solution (Aldrich), 2.5 g of fumed silica (Aldrich) and 0.42 g LiOH.H.sub.2O. This mixture was then placed in a closed 125 ml Parr reactor and heated at 120.degree. C. for 24 hours. The mixture was filtered and the white solid obtained was washed with water and ethanol. The product was then dried at 120.degree. C. The sample was then added to 100 ml of a 10% HNO.sub.3 solution and stirred at room temperature over night. The mixture was filtered and the solid washed with water. Drying at 120.degree. C. was the next process step. Finally the sample was heated under N.sub.2 flow in a tube furnace at 500.degree. C. for one hour, followed by heating in air at 500.degree. C. for 10 hours. The sample was tested via the spot method and exhibited color development.
example 4
[0031] Molecular Sieve
[0032] 60.0 g of a C.sub.16H.sub.33(CH.sub.3).sub.3NCl / OH solution (prepared as in Example #1) was mixed with 3.30 g Na.sub.2SnO.sub.3, 30.0 g of a 25% tetramethylammoniumsilicate solution (Aldrich) and 7.5 g of fumed silica (Aldrich). The mixture was placed in a closed 300 mL Parr reactor and heated at 120.degree. C. for 39 hours. The resulting mixture was filtered and the solid was washed with water and ethanol. The solid was dried at 120.degree. C. and then treated with 400ml of a 20% HNO.sub.3 solution for 20 hours. The mixture was filtered and the solid was washed with water and ethanol. The sample was dried at 120.degree. C. A heat treatment consisting of heating under N.sub.2 at 500.degree. C. for 3 hours followed by heating in air at 500.degree. C. for 14 hours completed the material preparation. The sample was tested via the spot method and exhibited color development.
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