Method for recovering copper from copper-containing materials using direct electrowinning

Abstract

A method for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent extraction techniques or apparatus. A method for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution, without subjecting the copper-containing solution to solvent extraction.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application is a continuation of U.S. patent application Ser. No. 10 / 737,420, which was filed on Dec. 15, 2003 and issued as U.S. Pat. No. 6,972,107 on Dec. 6, 2005, which application is a continuation of U.S. patent application Ser. No. 10 / 238,399, which was filed on Sep. 9, 2002 and issued as U.S. Pat. No. 6,663,689 on Dec. 16, 2003, which application is a continuation of U.S. patent application Ser. No. 09 / 912,921, which was filed on Jul. 25, 2001 and issued as U.S. Pat. No. 6,451,089 on Sep. 17, 2002, the disclosures of which are incorporated by reference herein.FIELD OF INVENTION [0002] The present invention relates generally to a process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material, and more specifically, to a process for producing cathode copper without the use of solvent / solution extraction, ion exchange of copper, or related processes to refine and concentrate the copper...

AI Technical Summary

Benefits of technology

[0012] In an aspect of another embodiment of the invention, a recycle circuit is used intermediate to the leaching and electrowinning steps to facilitate control of the composition of copper-containing solution entering the electrowinning stage, and to thus enhance the quality of the copper recovered therefrom.

[0013] In accordance with various preferred aspects of the present invention, by providing for the electrowinning of copper directly from a copper-containing solution without first subjecting the copper-containing solution to solvent extraction, the present invention enables lower-cost recovery of copper and eliminates the expenses associated with solvent extraction, such as specialized reagents, process apparatus and equipment, and energy resources. Furthermore, in accordance with one preferred aspect of the invention, careful control of the composition of the copper-containing solution entering the electrowinning circuit enables production of high quality, uniformly-plated cathode copper.

Problems solved by technology

However, the copper recovered by such so-called direct electrowinning processes often is too impure for sale or use as is, and thus, generally must be further refined at an additional cost, or may be sold at a discount.

More specifically, prior art techniques have shown the ability for direct electrowinning of copper to produce a relatively low-quality copper product.

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