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Processes for forming dental materials and device

a technology of dental materials and composites, applied in dental surgery, dental tools, impression caps, etc., can solve the problems of material shrinkage upon hardening, fractures within the tooth and/or the composite, physical gap and subsequent microleakage into the tooth cavity, etc., and achieve the effect of reducing tooth strain

Inactive Publication Date: 2007-03-08
3M INNOVATIVE PROPERTIES CO +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides processes for hardening dental materials involving a sequential hardening of the compositions. These processes can reduce stress placed on the dental material and surrounding environment during and after hardening. The processes involve a first step of initiating hardening of a second composition that is in contact with a first composition that is in contact with a dental surface. The second composition is then irradiated to selectively harden it, while the first composition remains substantially unhardened. The first composition can be a dental adhesive and the second composition can be a dental composite. The processes can be carried out using blue light or other suitable radiation. The invention also provides dental materials that are adhered to a dental surface using these processes.

Problems solved by technology

Often, such materials shrink upon hardening.
This is particularly problematic when the material is in a constrained environment, as in a dental filling or restorative, for example.
Such forces can result in interfacial failures between the tooth and the polymeric material resulting in a physical gap and subsequent microleakage into the tooth cavity.
Alternatively, such forces can lead to fractures within the tooth and / or the composite.

Method used

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  • Processes for forming dental materials and device
  • Processes for forming dental materials and device
  • Processes for forming dental materials and device

Examples

Experimental program
Comparison scheme
Effect test

example 1

Selective Curing of Compositions Having Different Photoinitiator Systems

[0108] The objective of this example was to demonstrate that compositions having different photoinitiator systems could be selectively cured (i.e., polymerized to a hardened material) with applied light having different effective wavelength ranges. An additional objective was to measure shear bond strength of sequentially irradiated tooth samples coated with various adhesive compositions and filled with a dental restorative.

[0109] Enamel and dentin tooth samples were prepared in a conventional manner by grinding with standard 120 grit / 600 grit, etching with SCOTCHBOND phosphoric acid etchant (3M Company), and priming with SCOTCHBOND multi-purpose primer (3M Company). A thin coating of Adhesive A or Adhesive B was then applied to separately prepared tooth samples and left uncured. A Teflon mold 2.5-mm thick and having a cylindrical 4-mm diameter hole was placed over each adhesive-coated tooth sample and filled ...

example 2

Selective Curing of Compositions Having Different Photoinitiator Systems

[0115] A layer of Adhesive A or Adhesive B was coated on separate glass slides followed by the addition of a Z100 restorative layer to each adhesive layer. Following irradiation of the coated slides with an ACCUCURE 3000 Laser as described in Example 1 (Curing Method 1), the Z100 layer could be moved readily on the Adhesive B-coated slide; whereas, the Z100 layer was firmly adhered to the Adhesive A-coated slide. Subsequent irradiation with a VISILUX 2500 halogen light as described in Example 1 (Curing Method 2) caused the Z100 layer to become firmly adhered to the Adhesive B-coated slide.

example 3

Selective Curing of Compositions Having Different Photoinitiator Systems

[0116] An aliquot of Adhesive A or Adhesive B was added to separate glass vials followed by the addition of an aliquot of P-60 restorative to each vial. Following irradiation of the filled vials for 15 seconds with the ACCUCURE 3000 Laser, the P-60 restorative cured to a solid polymer in a solidified Adhesive A; whereas in the other vial, the P-60 solid polymer was surrounded by a still fluid Adhesive B. Subsequent irradiation with a VISILUX 2500 halogen light as described in Example 1 (Curing Method 2) would be expected to solidify Adhesive B.

[0117] It is concluded from the results of Examples 2 and 3 that irradiation at a wavelength range of 460-500 cured Adhesive A and Z100 restorative (both with CPQ-based photoinitiator systems), but not Adhesive B (with IRGACURE 819); and that subsequent irradiation at a wavelength range of 400-500 cured or would cure Adhesive B.

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Abstract

Processes for forming dental materials that include applying a first hardenable dental composition (e.g., a dental adhesive) to a surface followed by applying a second hardenable dental composition (e.g., a dental composite) to the first hardenable dental composition on the surface. The first and second hardenable dental compositions are hardened such that the second hardenable composition is substantially completely hardened prior to complete hardening of the first hardenable composition.

Description

CROSS REFERENCE TO RELATED APPLICATIONS [0001] This application is a divisional of U.S. Ser. No. 10 / 185,431, filed Jun. 28, 2002, now U.S. Pat. No. 7,134,875, the disclosure of which is incorporated by reference in its entirety herein.TECHNICAL FIELD [0002] This invention relates to processes for forming dental materials from hardenable dental compositions involving generally sequential hardening. BACKGROUND [0003] Hardenable polymeric materials are used in a wide variety of dental applications, including composites, filling materials, restoratives, cements, adhesives, and the like. Often, such materials shrink upon hardening. This is particularly problematic when the material is in a constrained environment, as in a dental filling or restorative, for example. Dimensional changes upon shrinkage while in a constrained environment can generate a strain within the material that is typically converted into a stress on the surrounding environment (e.g., tooth). Such forces can result in ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A61C3/00A61C13/00A61C13/15A61K6/00A61K6/083
CPCA61C19/003A61K6/0017A61K6/0023A61K6/0047A61K6/083A61K6/087A61K6/0835C08L33/00C08L63/00A61K6/20A61K6/30A61K6/60A61K6/887A61K6/889A61K6/891
Inventor OXMAN, JOEL D.CRAIG, BRADLEY D.KALGUTKAR, RAJDEEP S.PEUKER, MARCBISSINGER, PETER
Owner 3M INNOVATIVE PROPERTIES CO
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