"Multilayer Film"

a technology of multi-layer film and adhesive property, applied in the field of multi-layer film, can solve the problem of difficult use as a single film, and achieve the effect of improving physical properties and superior adhesive properties of respective resins

Inactive Publication Date: 2014-02-06
SK INNOVATION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The multilayer film achieves excellent adhesive properties, reduces material costs, and enhances oxygen barrier and low-temperature heat seal capabilities, while allowing for cost-effective production and use as a shrinking film in packaging applications.

Problems solved by technology

Aliphatic polycarbonate is excellent in oxygen-barrier property, transparency, and the like, but is difficult to use as a single film due to a low Tg, which needs to be, in most cases, laminated with other resin at the time of use.
The polylactic acid-based polymer may be variously used as films, sheets, fibers, or the like, due to biodegradability and inherent physical properties thereof, but is limited in a packaging field requiring prevention of acidification due to large oxygen permeability thereof.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 2

[0070]A multilayer film was produced by the same method as Example 1, except that thicknesses of respective layers were regulated to 50 μm / 80 μm / 60 μm at the time of coextrusion, and the produced sheet was stretched in the mechanical direction and the transverse direction with a stretch ratio of 3×3 times, respectively, by using a biaxial stretcher at 85° C. Physical properties of the produced film were measured and the results were tabulated in Table 1.

example 3

[0071]A multilayer film was produced by the same method as Example 2, except that stretching is performed with a stretch ratio of 3×4 times.

[0072]Physical properties of the produced film were measured and the results were tabulated in Table 1.

TABLE 1UnitExample 1Example 2Example 3DelaminationNot de-Not de-Not de-laminatedlaminatedlaminatedFilm thicknessμm68.12015TensileKg / cm254811001050strength (MD)TensileKg / cm257712201100strength (TD)Elongation (MD)%9.480100Elongation (TD)%1.95040Haze%2.41.01.0Oxygencc / m2day63197250permeability(23° C., RH 0%)Water vaporg / m2day187350376permeability(38° C., 100% RH)

[0073]As shown in Table 1, it can be seen that mechanical properties were improved and haze was lowered to increase transparency in the biaxially stretched film, as compared with the non-stretched film, and oxygen permeability and water vapor permeability were inversely proportional to the thickness of the stretched film.

example 4

[0074]A multilayer film was produced by preparing a sheet having the same thickness as Example 2 and then regulating a stretch ratio and a stretch temperature as shown in Table 2 below. The film thus produced was submerged within a warm water bath at 70 to 100° C. for 30 seconds, and a shrinkage ratio of each film was measured.

[0075]The results were tabulated in Table 2.

TABLE 2StretchStretchWater bathMDTDratiotemperaturetemperatureShrinkageShrinkage(MD × TD)(° C.)(° C.)ratio(%)ratio(%)1 × 370701.751 × 370801.751 × 370903.311.71 × 3701003.38.31 × 3807001.71 × 3808001.71 × 380901.751 × 3801001.7101 × 3907001.71 × 3908001.71 × 390901.71.71 × 3901001.73.33 × 170708.04.03 × 1708016.08.03 × 170906.04.03 × 4707023303 × 4708037283 × 4709038433 × 47010047453 × 4807023293 × 4808030383 × 4809035433 × 48010040473 × 4907020273 × 4908015293 × 4909021333 × 4901002538

[0076]As shown in Table 2, it can be seen that biaxial stretching further increases the shrinkage ratio as compared with uniaxial str...

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Abstract

The present invention relates to a multilayer film coextruded from an aliphatic polycarbonate and polylactic acid-based polymer and a method for producing the same. According to the present invention, a multilayer film having excellent adhesive property can be manufactured even without a separate adhesive layer.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a division of U.S. patent application Ser. No. 13 / 218,220, filed Aug. 25, 2011, which claims priority to Korean Patent Application No. 10-2011-0077928, filed Aug. 4, 2011, and Korean Patent Application No. 10-2010-0086276, filed Sep. 3, 2010, which are incorporated herein by reference in their entirety.TECHNICAL FIELD[0002]The present invention relates to a multilayer film coextruded from an aliphatic polycarbonate and polylactic acid-based polymer and a method for producing the same.BACKGROUND ART[0003]Aliphatic polycarbonate is excellent in oxygen-barrier property, transparency, and the like, but is difficult to use as a single film due to a low Tg, which needs to be, in most cases, laminated with other resin at the time of use. However, in order to make the aliphatic polycarbonate be laminated with other kinds of resins such as PE, PP, or the like, when an appropriate adhesive capable of adhering two kinds of resins...

Claims

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Application Information

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Patent Type & AuthorityApplications(United States)
IPC IPC(8): B32B27/36B32B27/08B29C48/08B29C48/10
CPCB32B27/08B32B27/365B29L2007/00B32B27/36B29L2009/00B32B2250/02B32B2250/03B32B2250/244B32B2250/40B32B2307/516B32B2307/518B32B2307/7163B32B2307/736B29C48/08B29C48/10B29C48/0018B29C48/21B29C48/305B29C48/32B29C48/832Y10T428/31507Y02W90/10B32B37/02B32B5/18
InventorJEON, MIN HOYOO, JI EUNCHOI, MOON JUNGCHUNG, KWANG JINOK, MYUNG AHN
OwnerSK INNOVATION CO LTD