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Device for producing composite active material powder and method for producing composite active material powder

a technology of active materials and composite materials, which is applied in the direction of cell components, final product manufacturing, sustainable manufacturing/processing, etc., can solve the problems of inability to maintain, change the composition of sulfide-based solid electrolyte, and low production efficiency. achieve the effect of reducing the internal resistance of the battery

Inactive Publication Date: 2016-12-01
TOYOTA JIDOSHA KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent aims to provide a device and method for producing a composite active material powder that can reduce the internal resistance of a battery. The technical effect of the invention is the production of a more efficient and effective material that can improve the performance of batteries.

Problems solved by technology

However, the PLD method is generally slow in film-forming rate, so that it is remarkably low in productivity and is not practical.
At this time, the composition of the sulfide-based solid electrolyte may be changed and may not be maintained.
However, in such mixing / kneading methods using the medium, mechanical damage is applied in collision with the medium and, as a result, the surfaces of the active material-containing particles may be damaged.
However, the use of the conventional composite active material powder production device as disclosed in Patent Literature 1, is problematic in that the internal resistance of a battery using the thus-obtained composite active material powder is large.

Method used

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  • Device for producing composite active material powder and method for producing composite active material powder
  • Device for producing composite active material powder and method for producing composite active material powder
  • Device for producing composite active material powder and method for producing composite active material powder

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0090]First, composite particles in which LiNi1 / 3Co1 / 3Mn1 / 3O2 particles (active material particles) are coated with LiNbO3 (oxide-based solid electrolyte) were prepared (average particle diameter 6 μm).

[0091]Next, 20 g of the composite particles and 4 g of 60Li2S-2OP2S5-20LiI particles (sulfide-based solid electrolyte, average particle diameter 0.8 μm) were put into a dry mixing / kneading machine (product name: NOB-MINI; manufactured by: Hosokawa Micron Corporation) and mixed and kneaded for 10 minutes under the following conditions, thereby producing a composite active material powder.

[0092]Thickness of each blade: 6 mm

[0093]Width of the end surface of the end part of each blade: 1 mm

[0094]Length of the end part of each blade: 5.0 mm

[0095]Total length of each blade: 18.9 mm

[0096]Diameter of the rotating shaft of a rotating body: 50 mm

[0097]Clearance: 1 mm

[0098]Inclined angle: 45°

[0099]Peripheral speed: 18.5 m / s

example 2

[0100]A composite active material powder was produced in the same manner as Example 1, except that the width of the end surface of the end part of each blade was changed to 2.5 mm, and the thickness of each blade was changed to 7.5 mm.

example 3

[0101]A composite active material powder was produced in the same manner as Example 1, except that the width of the end surface of the end part of each blade was changed to 5 mm, and the thickness of each blade was changed to 10 mm.

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Abstract

A device produces a composite active material powder by coating active material or composite particle surfaces, which are obtained by coating the active material particle surfaces with an oxide-based solid electrolyte, with a sulfide-based solid electrolyte. The device includes: a storage body having a cylindrical inner wall surface, and a rotating body disposed in an internal space surrounded by the storage body inner wall surface, having a rotating shaft aligned with the internal space central axis, and which includes blades. Each blade end part has such a tapered section on a front side in the rotating body rotation / movement direction, that a thickness of the blade gradually tapers toward a blade end side, and each blade end part has such a curved end surface on a back side in the rotating body rotation / movement direction, that the curved end surface faces the storage body inner wall surface and is generally parallel thereto.

Description

BACKGROUND OF THE INVENTION[0001]Technical Field[0002]The present invention relates to a device for producing a composite active material powder and a method for producing a composite active material powder.[0003]Background Art[0004]In the field of all-solid-state batteries, there is an attempt to improve the performance of all-solid-state batteries, focusing on an interface between the electrode active material and the solid electrolyte material.[0005]Examples of conventional methods for coating the surfaces of active material-containing particles with a sulfide-based solid electrolyte, include gas phase methods such as pulsed laser deposition (hereinafter may be referred to as PLD). However, the PLD method is generally slow in film-forming rate, so that it is remarkably low in productivity and is not practical. Also in the PLD method, the target of the sulfide-based solid electrolyte is turned into a plasma by laser irradiation. At this time, the composition of the sulfide-based s...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01M4/36H01M4/525H01M4/505H01M4/58
CPCH01M4/366H01M4/505H01M4/525H01M4/5815H01M4/04H01M4/362H01M4/1391H01M4/587H01M4/62H01M10/052H01M10/0562Y02E60/10C01G51/00C01G51/44H01M4/139Y02P70/50B01F27/70B01F27/112B01F27/0721
Inventor IWASAKI, MASAHIRO
Owner TOYOTA JIDOSHA KK