Method of activating two-dimensional materials for multivalent/polyatomic-ion intercalation battery electrodes
a multivalent/polyatomicion intercalation and battery electrode technology, applied in the field of multivalent/polyatomicion batteries, can solve the problems of unfavorable insertion and diffusion, sluggish insertion/diffusion of these cations, and intrinsic difficulty in electrochemical storage of multivalent cations in insertion compounds, and achieve enhanced specific capacity and rate performance.
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[0046]The following examples are included to demonstrate particular aspects of the present disclosure. It should be appreciated by those of ordinary skill in the art that the methods described in the examples that follow merely represent illustrative embodiments of the disclosure. Those of ordinary skill in the art should, in light of the present disclosure, appreciate that many changes can be made in the specific embodiments described and still obtain a like or similar result without departing from the spirit and scope of the present disclosure.
[0047]Electrochemical Activation of 1T-TiS2 for MgCl-Ion Storage
[0048]It is known that intercalating organic molecules or bulky ions can expand the layered materials by 10-60 Å. 1-butyl-1-methylpyrrolidinium ion (PY14+) was chosen as the pillaring material to expand TiS2 because of the bulky size and electrochemical stability of PY14+. 0.2 M PY14Cl is dissolved into a standard all-phenyl complex (APC) electrolyte. Cyclic voltammetry characte...
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