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Polyvinyl chloride fiber, process for producing the same, and use thereof

A polyvinyl chloride fiber and vinyl chloride technology, applied in the field of polyvinyl chloride production, can solve the problems of increased heat shrinkage and no selection of resin compositions, and achieve the effect of small heat shrinkage

Active Publication Date: 2007-09-12
DENKA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, since the thermal shrinkage of the ethylene-vinyl acetate / vinyl chloride graft polymer itself is equal to that of the vinyl chloride resin, even if the compatibility between the vinyl chloride resin and the chlorinated vinyl chloride resin is improved, the resin composition Self-heat shrinkage will also increase, therefore, this method is not preferred
While improving the compatibility between vinyl chloride resins and chlorinated vinyl chloride resins, it is necessary to select a resin that itself has a certain degree of heat resistance, but still no satisfactory resin has been selected.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] The polyvinyl chloride fibers used in Example 1 were obtained by melt-spinning a resin composition having the following composition using a melt extruder: 100 parts by weight of vinyl chloride resin (TH-1000, produced by Taiyo Vinyl Corp.) , 5 parts by weight of compatibility chlorinated vinyl chloride resin (customized, produced by Sekisui Chemical Co., Ltd), 11 parts by weight of heat-resistant chlorinated vinyl chloride resin (customized, produced by Sekisui Chemical Co., Ltd . Production) and 0.5 parts by weight of a heat stabilizer (CP-234A, produced by Nissan Chemical Industries, Ltd.), and then subjected to a stretching step and a thermal relaxation treatment step, to be molded into an average fineness of 60 denier. The chlorine content, degree of polymerization and fluidity of each of the compatible chlorinated vinyl chloride resin and heat-resistant chlorinated vinyl chloride resin used are shown in Table 1.

[0070] Melt spinning of polyvinyl chloride fibers w...

Embodiment 2~4

[0072] Polyvinyl chloride fibers were obtained in the same manner as in Example 1, except that the mixing amount, chlorine content, degree of polymerization, and fluidity of each resin used, and the mixing amount of heat stabilizers were changed to the values ​​shown in Table 1 , and then evaluated in the same way.

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Abstract

Polyvinyl chloride fibers which are reduced in heat shrinkage even in an atmosphere of 100 DEG C or higher and are obtained from a composition retaining the spinnability possessed by conventional compositions. The fibers are suitable for use in applications such as artificial hair. The polyvinyl chloride fibers are characterized by being obtained by forming a resin composition comprising 100 parts by mass of a polyvinyl chloride resin, 3 to 20 parts by mass of a compatible chlorinated polyvinyl chloride resin, 10 to 30 parts by mass of a heat-resistant chlorinated polyvinyl chloride resin, and 0.1 to 10 parts by mass of a heat stabilizer into fibers, the compatible chlorinated polyvinyl chloride resin having a chlorine content of 57 to 64 wt.% and an average degree of polymerization of 450 to 800 and the heat-resistant chlorinated polyvinyl chloride resin having a chlorine content of 65 to 71 wt.% and an average degree of polymerization of 450 to 1,100.

Description

technical field [0001] The present invention relates to polyvinyl chloride fibers, especially polyvinyl chloride having small heat shrinkage and maintaining conventional spinning characteristics even in an atmosphere of 100°C or higher, and to a method for producing the polyvinyl chloride and to the production of the polyvinyl chloride application. Background technique [0002] Vinyl chloride resin is used in various applications as a typical general-purpose plastic because of its excellent transparency, flame retardancy, chemical resistance, and low price. Among them, polyvinyl chloride fibers are close to natural hair in strength, ductility, etc., and therefore, are generally used as fibers for artificial hair instead of hair. PVC shrinks more than necessary due to heat in secondary processing. As a method of solving such a problem, a method of producing a polyvinyl chloride fiber made of a composition of a vinyl chloride-containing resin and a heat-resistant chlorinated...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/48C08L27/06C08K5/00C08K3/00
Inventor 樱井晓金冈正道茂吕居昭
Owner DENKA CO LTD