Unlock instant, AI-driven research and patent intelligence for your innovation.

Dephosphorization method of phosphorus-containing iron ore

A technology for dephosphorization of iron ore, applied in the direction of improving process efficiency, etc., can solve problems such as poor dephosphorization effect, and achieve low dephosphorization cost and good dephosphorization effect

Inactive Publication Date: 2008-10-08
CENT SOUTH UNIV
View PDF2 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the dephosphorization effect of this method is relatively poor, and the dephosphorization rate only reaches about 42% under the synergistic effect of the phosphorus-dissolving agent.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Dephosphorization method of phosphorus-containing iron ore

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Example 1, referring to the attached drawings, the iron ore with a phosphorus content of 1.12% was crushed to a particle size less than 0.074mm, and 10% of the pyrite with a particle size less than 0.074mm was added to the phosphorus-containing iron ore by mass percentage. The 9K medium solution adjusts the mass concentration of the pulp to 10%, and adds 5% of Thiobacillus ferrooxidans (Tf bacteria) broth according to the mass percentage. The initial pulp pH is 2.2. Under the condition of leaching for 35 days, the dephosphorization rate reaches 68.81%. ; When the pyrite content is increased to 20%, the dephosphorization rate is 78.84%.

Embodiment 2

[0014] Example 2, referring to the attached drawings, the iron ore with a phosphorus content of 1.12% was crushed to a particle size less than 0.074mm, and 20% of the pyrite with a particle size less than 0.074mm was added to the phosphorus-containing iron ore as a percentage by mass. The 9K medium solution adjusts the mass concentration of the pulp to 15%, and adds 5% Tf bacteria liquid according to the mass percentage. When the initial pulp pH is 1.7 and 2.0, the dephosphorization rate reaches 86.68% and 86.63 after 45 days of leaching. %; When the pH is lower than 1.5, it is difficult for bacteria to survive; when the pH is 3.5, the dephosphorization rate drops to 78%.

Embodiment 3

[0015] Example 3, referring to the attached drawings, the iron ore containing 1.12% phosphorus was crushed to a particle size less than 0.074mm, and 20% of the pyrite with a particle size less than 0.074mm was added to the phosphorus-containing iron ore by mass percentage. The 9K medium solution adjusts the pulp mass concentration to 20%, the initial pulp pH is 2.2, and under the condition of 45 days of leaching, when the Tf bacterial liquid inoculum is increased from 2% to 5% by mass percentage, the dephosphorization rate will be 67.70 % Increased to 78.84%; and when the Tf bacterial solution inoculation amount increased from 5% to 10%, the dephosphorization rate of ore only increased from 78.84% to 79.95%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
Login to View More

Abstract

A method for dephosphorizing from phosphor-containing iron ore is disclosed, wherein phosphor-containing iron ore is broken to the granularity of less than 0.074mm and mixed with iron pyrite prebroken to the granularity of less than 0.074mm based on mass percent of 5%-20%, the mass concentration of ore slurry is adjusted to 10%-20% by the aphosphorosis 9K culture and pH of original ore slurry is in the range of 1.5 to 3.5, then noculating ferrous and sulfur oxide bacilli lysate of 2% -10% mass percent in which bacteria is cultrued by 9K culture beforehand ro reach exponential phase of growth in ore slurry, extracting dephosphorization, solid-liquid separation after 30 -45 days, and the solid is iron ore concentrate. The invention is suitable for direct-extracting dephosphorizing from each phosphor-containing iron ore microbe, the ore dephosphorizing yield can be exceeded 80%, The content of phosphorus satisfies the requirement of blast furnace ironmaking materials, and having comprehensive utilization of iron pyrite. The process provides a reliable technical support for developing rich high phosphorus iron ore in our country with low cost and good dephosphorization.

Description

Technical field [0001] The invention relates to a method for dephosphorizing phosphorus-containing iron ore, in particular to a method for directly leaching phosphorus-containing iron ore to dephosphorize it by using Thiobacillus ferrooxidans (T.f bacteria). Background technique [0002] With the development of the iron and steel industry, my country's limited rich ore and easy-to-dress iron ore resources have gradually been exhausted, and the available iron ore resources have become increasingly poor, fine and miscellaneous. Large amounts of phosphorus-containing iron ore are stored in my country's Hunan, Hubei and Yangtze River basins. Since phosphorus can cause "cold brittleness" in steel, low phosphorus content is an important quality indicator of iron ore. Cleveland Cleffs Inc proposes that the phosphorus content of iron ore concentrates should be less than 0.024%, and the domestic basic requirement for phosphorus content of iron ore concentrates is 0.05% to 0.30%, which is ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C22B3/18C22B1/14
CPCY02P10/20
Inventor 姜涛邱冠周杨永斌李光辉李骞郭宇峰金勇士范晓慧黄柱成许斌朱忠平张元波刘牡丹董海刚
Owner CENT SOUTH UNIV